Korean Journal of Chemical Engineering, Vol.29, No.9, 1203-1210, 2012
Electro-Fenton treatment of synthetic organic dyes: Influence of operational parameters and kinetic study
This work investigates oxidative decolorization of two different dyes, Methylene blue and Titan yellow in aqueous solution using an environmentally friendly advanced electro-chemical oxidation (electro-Fenton) process. The effect of operating conditions like H2O2 concentration, current density, initial dye concentration was studied in a batch stirred cell. Individual decolorization decay kinetics for both dyes was investigated. The second-order absolute rate constants (L mol.1 s.1) between hydroxyl radical and dye have been calculated from experimental data by fitting it to the decolorization model. The apparent kinetic constants, kapp (s.1) for Methylene blue and Titan yellow dye decolorization were also determined. The experimental data showed a good fit to the theoretical model, which can predict data in a wide range of % dye decolorization. This process also reduces COD of the dye solution, and the unit energy demand (UED) in kWh/kg COD removed for different electrical current has been reported.
[References]
Gupta AK, Pal A, Sahoo C, Dyes Pigm. , 69 , 224, 2006
Dai QZ, Zhou MH, Lei LC, J. Hazard. Mater. , 137 (3), 1870, 2006
Lata H, Garg VK, Gupta RK, Dyes Pigm. , 74 , 653, 2007
Wang XS, Zhou Y, Jiang Y, Sun C, J. Hazard. Mater. , 157 (2-3), 374, 2008
Garg VK, Amita M, Kumar R, Gupta R, Dyes Pigm. , 63 , 243, 2004
Robinson T, Chandran B, Nigam P, Environ. Int. , 28 , 29, 2002
Wang S, Boyjoo Y, Choueib A, Chemosphere. , 60 , 1401, 2005
Hamdaoui O, J. Hazard. Mater. , 135 (1-3), 264, 2006
Poon CS, Huang QP, Fung C, Chemosphere. , 38 , 1005, 1999
Xie YB, Li XZ, Mater. Chem. Phys. , 95 (1), 39, 2006
Kumar KV, Kumaran A, J. Biochem. Eng. , 27 , 83, 2005
Ozer D, Dursun G, Ozer A, J. Hazard. Mater. , 144 (1-2), 171, 2007
Papic S, Vujevic D, Koprivanac N, Sinko D, J. Hazard. Mater. , 164 (2-3), 1137, 2009
Huang YH, Chou S, Perng MG, Huang GH, Cheng SS, Water Sci. Technol. , 39 , 145, 1999
Brillas E, Calpe JC, Casado J, Water Res. , 34 , 2253, 2000
Lin SH., Chang CC, Water Res. , 34 , 4243, 2000
Cruz-Gonzalez K, Torres-Lopez O, Garcia-Leon A, Guzman-Mar JL, Reyes LH, Hernandez-Ramirez A, Peralta-Hernandez JM, Chem. Eng. J. , 160 (1), 199, 2010
Juttner K, Galla U, Schmieder H, Electrochim. Acta , 45 (15-16), 2575, 2000
Ruiz EJ, Arias C, Brillas E, Hernandez-Ramirez A, Peralta-Hernandez JM, Chemosphere. , 82 , 495, 2011
Martinez-Huitle CA, Brillas E, Appl. Catal. B: Environ. , 87 (3-4), 105, 2009
Zhang GQ, Yang FL, Gao MM, Fang XH, Liu LF, Electrochim. Acta , 53 (16), 5155, 2008
Pletcher D, Walsh FC,, Industrial Electrochemistry, 2nd Ed., Chapman and Hall, London, UK, 1990
Lin SH, Chen ML, Environ. Technol. , 16 , 693, 1995
Gau SH, Chang FS, Wat. Sci. Technol. , 34 , 455, 1996
Brillas E, Casado J, Chemosphere. , 47 , 241, 2002
Oturan MA, Peiroten J, Chartrin P, Acher AJ, Environ. Sci.Technol. , 34 , 3474, 2000
Panizza M, Cerisola G, Water Res. , 35 , 3987, 2001
Lahkimi A, Oturan MA, Oturan N, Environ. Chem. Lett. , 5 , 35, 2007
Guivarch E, Trevin S, Lahitte C, Oturan MA, Environ. Chem.Lett. , 1 , 38, 2003
Rosales E, Pazos M, Longo MA, Sanroman MA, Chem. Eng. J. , 155 (1-2), 62, 2009
Bensalah N, Alfaro MAQ, Martinez-Huitle CA, Chem. Eng. J. , 149 (1-3), 348, 2009
Panizza M, Cerisola G, Water Res. , 43 , 339, 2009
Clesceri LS, Greenberg AE, Andrew D, Standard methods for the Examination of water and wastewater, 20th Ed., APHA, Washington, DC, 1998
Talini I, Anderson GK, Water Res. , 26 , 107, 1992
Kuo WG, Water Res. , 26 , 881, 1992
Ghosh P, Samanta AN, Ray S, Can. J. Chem. Eng. , 88 (6), 1021, 2010
Zhou MH, Yu QH, Lei LC, Barton G, Sep. Purif. Technol. , 57 (2), 380, 2007
Zhou M, Yu Q, Lei L, Dyes Pigm. , 77 , 129, 2008
Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ. , 47 (4), 219, 2004
Kwon BG, Lee DS, Kang N, Yoon J, Water Res. , 33 , 2110, 1999
El-Dein AM, Libra JA, Wiesmann U, Water Sci. Technol. , 44 , 295, 2001
Ramirez JH, Duarte FM, Martins FG, Costa CA, Madeira LM, Chem. Eng. J. , 148 (2-3), 394, 2009
Khataee AR, Vatanpour V, Ghadim ARA, J. Hazard. Mater. , 161 (2-3), 1225, 2009
Altin S, Int. J. Chem. Reactor Eng. , 9 , A33, 2011
Altin A, Sep. Purif. Technol. , 61 (3), 391, 2008
Wang CT, Hu JL, Chou WL, Kuo YM, J. Hazard. Mater. , 152 (2), 601, 2008
Brillas E, Sires I, Oturan MA, Chem. Rev. , 109 (12), 6570, 2009
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