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Korean Journal of Chemical Engineering, Vol.29, No.9, 1115-1118, 2012
A study of the palladium size effect on the direct synthesis of hydrogen peroxide from hydrogen and oxygen using highly uniform palladium nanoparticles supported on carbon
Highly monodisperse carbon-supported palladium nanoparticles with controllable size (3 nm, 6.5 nm, 9.5 nm) were prepared using a simple colloidal method, and the size dependence of the catalytic performance for the direct synthesis of hydrogen peroxide from hydrogen and oxygen was studied. Smaller-sized supported palladium nanoparticles showed both higher conversion of hydrogen and selectivity for hydrogen peroxide, compared to larger-sized supported particles. Among the catalysts tested, 3-nm Pd nanoparticles supported on carbon showed the highest yield for hydrogen peroxide because of the small size and high crystallinity.
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[Cited By]
- Guo L, Bai J, Liang H, Xu T, Li C, Meng Q, Liu H, Huang Y, Korean Journal of Chemical Engineering, 30(12), 2142, 2013
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- Hang VTT, Chung YM, Korean Journal of Chemical Engineering, 37(1), 65, 2020
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