Issue
Korean Journal of Chemical Engineering,
Vol.28, No.12, 2282-2286, 2011
Co-methanation of CO and CO2 on the NiX-Fe1-X/Al2O3 catalysts; effect of Fe contents
The co-methanation of carbon dioxide containing syngas was carried out on Al2O3 supported NixFe1-x (x is 0.1, 0.3, 0.5, 0.7 and 0.9) catalysts for synthetic natural gas (SNG) production. The catalysts were prepared by wetimpregnation method taking 20 weight percent of the metallic component over the support, and its characteristics were analyzed by BET surface area, XRD and H2-TPR. The maximum carbon conversion and CH4 selectivity are achieved on Ni0.7Fe0.3/Al2O3 catalyst. Further, increase of Fe content led to enhancing the water gas shift reaction and hydrocarbon formation.
[References]
  1. Bresler SA, Ireland JD, Chem. Eng., 1, 94, 1972
  2. Harms A, Hohlein B, Jørn E, Skov A, Oil Gas J., 78, 120, 1980
  3. Rostrup-Nielsen JR, Pedersen K, Sehested J, Appl. Catal. A: Gen., 330, 134, 2007
  4. Takenaka S, Shimizu T, Otsuka K, Int. J. Hydrog. Energy., 29, 1065, 2004
  5. Udengaard NR, Olsen A, Wix-Nielsen C, Pittsburgh Coal Conf., 2006
  6. Akin AN, Ataman M, Aksoylu AE, Oensan ZI, React. Kinet. Catal. Lett., 76, 365, 2002
  7. Nawdali M, Bianchi D, Appl. Catal. A: Gen., 231(1-2), 45, 2002
  8. Satterfield CN, Heterogeneous catalysis in industrial practice, 2nd Ed., Krieger Publishing, Malabar, FL, 1991
  9. Fujita S, Nakamura M, Doi T, Takezawa N, Appl. Catal. A., 104, 87, 1993
  10. Kester KB, Zagli E, Falconer JL, Appl. Catal., 22, 311, 1986
  11. Andersson MP, Bligaard T, Kustov A, Larsen KE, Greeley J, Johannessen T, Christensen CH, Norskov JK, J. Catal., 239(2), 501, 2006
  12. Sehested J, Dahl S, Jacobsen J, Rostrup-Nielsen JR, J. Phys. Chem. B, 109(6), 2432, 2005
  13. Habazaki H, Yamasaki M, Zhang BP, Kawashima A, Kohno S, Takai T, Hashimoto K, Appl. Catal. A: Gen., 172(1), 131, 1998
  14. Ishihara T, Eguchi K, Arai H, Appl. Catal., 30, 225, 1987
  15. Kustov AL, Frey AM, Larsen KE, Johannessen T, Norskov JK, Christensen CH, Appl. Catal. A: Gen., 320, 98, 2007
  16. Yaccato K, Carhart R, Hagemeyer A, Lesik A, Strasser P, Volpe AF, Turner H, Weinberg H, Grasselli RK, Brooks C, Appl. Catal. A: Gen., 296(1), 30, 2005
  17. http://www.topsoe.com/research.
  18. Kim JH, Kang SH, Ryu JH, Lee SK, Kim SH, Lee DY, Kim MH, Yoo YD, Byun CD, Lim HJ, Korean Chem. Eng. Res., In press, 2011
  19. Kang SH, Bae JW, Prasad PSS, Jun KW, Catal. Lett., 125(3-4), 264, 2008
  20. Espinoza RL, Steynberg AP, Jager B, Vosloo AC, Appl. Catal. A: Gen., 186(1-2), 13, 1999
  21. Seglin L, Methanation of synthesis gas, American Chemical Society, 1974
  22. Rostrup-Nielsen JR, Pedersen K, Sehested J, Appl. Catal. A: Gen., 330, 134, 2007
  23. Kopyscinski J, Schildhauer TJ, Biollaz SMA, Fuel., 89, 1763, 2010
  24. Kang SH, Bae JW, Cheon JY, Lee YJ, Ha KS, Jun KW, Lee DH, Kim BW, Appl. Catal. B., 1-2, 169, 2010
  25. Van Herwijnen T, Vav Doesburg H, De Jong WA, J. Catal., 28, 391, 1973
  26. Ning WS, Koizumi N, Chang H, Mochizuki T, Itoh T, Yamada M, Appl. Catal. A: Gen., 312, 35, 2006