Issue
Korean Journal of Chemical Engineering,
Vol.28, No.12, 2329-2335, 2011
Green synthesis of gold nanostructures using pear extract as effective reducing and coordinating agent
Biosynthesis of gold nanoparticles and nanoplates (GNPs) was accomplished using aqueous fractions of pear extract as a safe, reducing, particle-stabilizing, and shape-directing agent. The maximum yields of spherical gold nanoparticles having the average sizes of 40, 20, and 10 nm were achieved at 30, 60, and 90℃ , respectively, at a pear extract concentration of 45% (v/v). The maximum yield of gold nanoplates was obtained with sizes ranging from 20 to 400 nm, particularly at reaction temperatures of 30, 60, and 90℃ , at a pear extract concentration of 5% (v/v). The surface chemistry analysis of the GNPs suggests that the sugars and peptides or proteins as key biomolecules of the pear extract play a crucial role in the reduction of Au(III), subsequently resulting in healthy capping. Therefore, this environmentally friendly synthesis method of GNPs for the particular type of morphologies is expected to be a competitive alternative to existing physical and chemical methods.
[References]
  1. Chen RJ, Bangsaruntip S, Drouvalakis KA, Kam NWS, Shim M, Li Y, Kim W, Utz PJ, Dai H, Proc. Natl. Acad. Sci., 100, 4984, 2003
  2. Nowack B, Bucheli TD, Environ. Pollut., 150, 5, 2007
  3. Meltzer S, Resch R, Koel BE, Thompson ME, Madhukar A, Requicha AAG, Will P, Langmuir, 17(5), 1713, 2001
  4. Gole A, Murphy CJ, Chem. Mater., 16, 3633, 2004
  5. Dahl JA, Maddux BLS, Hutchison JE, Chem. Rev., 107(6), 2228, 2007
  6. Hutchison JE, ACS Nano., 2, 395, 2008
  7. Li H, Carter JD, LaBean TH, Mater. Today., 12, 24, 2009
  8. Niemeyer CM, Ceyhan B, Ange. Chem. Inter. Edi., 40, 3685, 2001
  9. Tsai CJ, Zheng J, Zanuy D, Haspel N, Wolfson H, Aleman C, Nussinov R, Proteins., 68, 1, 2007
  10. Kumar V, Yadav SK, J. Chem. Technol. Biotechnol., 84(2), 151, 2009
  11. Mohanpuria P, Rana NK, Yadav SK, J. Nanopart. Res., 10, 507, 2008
  12. Huang J, Wang W, Lin L, Li Q, Lin W, Li M, Mann S, Chem.Asian J., 4, 1050, 2009
  13. Castro L, Blazquez ML, Gonzalez F, Munoz JA, Ballester A, Chem. Eng. J., 164(1), 92, 2010
  14. Shankar SS, Rai A, Ankamwar B, Singh A, Ahmad A, Sastry M, Nat. Mater., 3, 482, 2004
  15. Tan YN, Lee JY, Wang DIC, J. Phys. Chem. C., 112, 5463, 2008
  16. Song JY, Jang HK, Kim BS, Process Biochem., 44, 1133, 2009
  17. Tripathy A, Raichur AM, Chandrasekaran N, Prathna TC, Mukherjee A, J. Nanopart. Res., 12, 237, 2010
  18. USDA National Nutrient Database for Standard Reference, Release 23. U.S. Department of Agriculture, Agricultural Research Service, Scientific Name: Pyrus pyrifolia (Pears, asian, raw) NDB No: 09340, 2010
  19. Nie SM, Emery SR, Science, 275(5303), 1102, 1997
  20. El-Sayed MA, Accounts Chem. Res., 34, 257, 2001
  21. Liz-Marzan LM, Langmuir, 22(1), 32, 2006
  22. Shukla R, Nune SK, Chanda N, Katti K, Mekapothula S, Kulkarni RR, Welshons WV, Kannan R, Katti KV, Small., 4, 1425, 2008