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Issue
Korean Journal of Chemical Engineering,
Vol.16, No.1, 111-117, 1999
DYE SOLUBILITY IN SUPERCRITICAL CARBON DIOXIDE. EFFECT OF HYDROGEN BONDING WITH COSOLVENTS
Muthukumaran P, Gupta RB, Sung HD, Shim JJ, Bae HK
The use of supercritical carbon dioxide is emerging as a potential method for achieving pollution-free dyeing. An important factor in supercritical fluid dyeing is the solubility of the dye in supercritical carbon dioxide. Our measurements show that the solubility of C.I. Disperse Red-60 dye in supercritical carbon dioxide is significantly enhanced upon addition of polar cosolvents : ethanol and acetone. The solubility enhancement is attributed to the formation of hydrogen bonds between cosolvent and dye molecules. Observed solubility behavior is correlated using dilute-solution theory with lattice-fluid-hydrogen-bonding model. Needed physical and hydrogen-bonding molecular parameters are estimated using the experimental data.
Keywords: Dye Solubility; Supercritical Carbon Dioxide; Hydrogen Bonding; Cosolvent; Solubility Enhancement
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[Cited By]
  1. Cao X, Lee HJ, Yun HS, Koo YM, Korean Journal of Chemical Engineering, 18(1), 133, 2001
  2. Kim YH, Lee YW, Park JK, Lee CH, Lim JS, Korean Journal of Chemical Engineering, 19(6), 986, 2002
  3. Baek JK, Kim S, Lee GS, Shim JJ, Korean Journal of Chemical Engineering, 21(1), 230, 2004
  4. Youn HS, Roh MK, Weber A, Wilkinson GT, Chun BS, Korean Journal of Chemical Engineering, 24(5), 831, 2007
  5. Park SC, Tuma D, Kim S, Lee YR, Shim JJ, Korean Journal of Chemical Engineering, 27(1), 299, 2010
  6. Park JN, Ali-Nehari A, Woo HC, Chun BS, Korean Journal of Chemical Engineering, 29(11), 1604, 2012
  7. Morais AB, Jayakumar C, Gandhi NN, Korean Journal of Chemical Engineering, 30(4), 925, 2013
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