Issue
Korean Journal of Chemical Engineering,
Vol.15, No.5, 516-521, 1998
EFFECTS OF BASE METAL PROMOTERS IN VOC CATALYSTS FOR CHLOROCARBONS AND n-HEXANE OXIDATION
The oxidation reactions of dichloromethane, dichloroethane and n-hexane were carried out over honeycomb type platinum basic VOC catalyst (BVC) containing vanadium, chromium, manganese, cobalt, copper or barium. In dichloromethane and dichloroethane catalytic oxidation up to 450℃, chromium was found as the most active component. Although vanadium was also effective initially, it was deactivated after treatment in the furnace at 800℃ for 120 hours. Chromium, cobalt, vanadium and barium promoted catalysts showed higher activities than BVC in the reaction of n-hexane.
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