Issue
Korean Journal of Chemical Engineering,
Vol.15, No.5, 486-490, 1998
ROLES OF Pt AND ALUMINA DURING THE COMBUSTION OF COKE DEPOSITS ON PROPANE DEHYDROGENATION CATALYSTS
Temperature programmed oxidation of coke deposited on Pt based Propane dehydrogenation catalysts reveals that the deposited coke can be categorised into three groups according to their burning temperatures. When coke was separated from the catalyst, however, only one TPO peak could be observed. Experimental results suggest that γ-Al2O3 enhances the coke burning process by increasing coke surface area contacts to oxygen. Pt may also act as a catalyst for the coke combustion reaction. Experiments also show that changing dehydrogenation reaction temperature, variation of H2/HC ratios, addition of only Sn or Sn and an alkali metal (Li, Na and K) can significantly affect the amount of each coke formed. Sample weight used in the temperature programmed oxidation (TPO) experiment also affects the resolution of TPO spectrum.
[References]
  1. Atchara S, "Combustion of Coke on Dehydrogenation Catalysts," M. Eng. Theses, Chulalongkorn University, 1995
  2. Barbier JB, Corro G, Zhang Y, Appl. Catal., 13, 245, 1985
  3. Barbier JB, Marecot P, Martin N, Elassal L, Maurel R, "Selective Poisoning by Coke Formation on Pt/Al2O3," Catalyst Deactivation (Delmon, B. and Froment, G.F. eds), Elsevier, Amsterdam, p. 53, 1980
  4. Bartholdy J, Zeuthen P, Massoth FE, Appl. Catal. A: Gen., 129(1), 33, 1995
  5. Biswas J, Gray PG, Do DD, Appl. Catal., 32, 249, 1987
  6. Bualom J, "Effect of Alkali Metals in Dehydrogenation Catalysts for Coke Reduction," M. Eng. Theses, Chulalongkorn University, 1995
  7. Carlos LP, Jose MP, Ind. Eng. Chem. Res., 28, 1785, 1989
  8. Larsson M, Hulten M, Blekkan EA, Andersson B, J. Catal., 164(1), 44, 1996
  9. Liwu L, Tao Z, Jingling Z, Zhusheng Z, Appl. Catal., 67, 11, 1990
  10. Marecot P, Akhachane A, Barbier J, Catal. Lett., 36(1-2), 37, 1996
  11. Nonglak P, "Characterization of Coke on Dehydrogenation Catalysts," M. Eng. Theses, Chulalongkorn University, 1996
  12. Pieck CL, Jablonski EL, Verderone RJ, Parera JM, Appl. Catal., 56, 1, 1989
  13. Querini CA, Fung SC, Catal. Today, 37(3), 277, 1997
  14. Querini CA, Fung SC, Appl. Catal. A: Gen., 117(1), 53, 1994
  15. Reyes P, Oportus M, Pecchi G, Frety R, Moraweck B, Catal. Lett., 37(3-4), 193, 1996
  16. Silipoln K, "Determination of Irreversible Coke Deposition of Platinum Active Site of Propane Dehydrogenation Catalyst," D. Eng. Theses, Chulalongkorn University, 1995
  17. Tao Z, Jingling Z, Liwu L, "Relation Between Surface Structure and Carbon Deposition on Pt/Al2O3 and Pt-Sn/Al2O3 Catalysts," Studies in Surface Science and Catalyst, Elsevier, Amsterdam, 34, 143, 1991