About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.28, No.7, 1632-1635, 2011
On-line measurement of monomer concentration in UV photopolymerization using a quartz crystal resonator
Kim YH
In spite of the importance of monomer concentration measurement in polymerization, it is difficult to measure the concentration in thin film polymerization, such as the UV photopolymerization of acrylates. A small device, a quartz crystal resonator, has been applied to the measurement of monomer amount in the UV photopolymerization of trimethylolpropane triacrylate with an initiator of 2-ethylanthraquinone. The resonant resistance of the resonator is converted to the monomer concentration using an empirical relationship. The measurement results indicate that the proposed technique is effective for determining the monomer concentration. The simplicity and ready availability of the proposed application have been proven experimentally.
Keywords: UV Photopolymerization; On-line Monitoring; Quartz Crystal Resonator
[References]
  1. Steeman PAA, Dias AA, Wienke D, Zwartkruis T, Macromolecules, 37(18), 7001, 2004
  2. Schmidt LE, Leterrier Y, Vesin JM, Wilhelm M, Manson JAE, Macromol. Mater. Eng., 290, 1115, 2005
  3. Piguet-Ruinet F, Love BJ, J. Appl. Polym. Sci., 107(3), 1523, 2008
  4. Slopek RP, McKinley HK, Henderson CL, Breedveld V, Polm. Commun., 47, 2263, 2006
  5. Lintinen K, Storbacka L, Efimov A, Hietala S, Ahorinta R, Tkachenko N, Lemmetyinen H, J. Polym. Sci. A: Polym. Chem., 47(22), 6095, 2009
  6. Chai XS, Schork FJ, Oliver EM, J. Appl. Polym. Sci., 99(4), 1471, 2006
  7. Lee TY, Kaung W, Jonsson ES, Lowery K, Guymon CA, Hoyle CE, J. Polym. Sci. A: Polym. Chem., 42(17), 4424, 2004
  8. Corcione CE, Frigione M, Maffezzoli A, Malucelli G, Europ. Polym. J., 44, 2010, 2008
  9. Xu K, Zhou S, Wu L, Prog. Organ. Coat., 65, 237, 2009
  10. Lin Y, Stansbury JW, J. Polym. Sci. A: Polym. Chem., 42(8), 1985, 2004
  11. Scherzer T, Mehnert R, Lucht H, Macromol. Symp., 205, 151, 2004
  12. Scherzer T, Buchmeister MR, Macromol. Chem. Phys., 208, 946, 2007
  13. Marx KA, Biomacromolecules, 4(5), 1099, 2003
  14. Buttry DA, Ward MD, Chem. Rev., 92, 1355, 1992
  15. Serizawa T, Hamada K, Kitayama T, Fujimoto N, Hatada K, Akashi M, J. Am. Chem. Soc., 122(9), 1891, 2000
  16. Hossenlopp J, Jiang LH, Cernosek R, Josse F, J. Polym. Sci. B: Polym. Phys., 42(12), 2373, 2004
  17. Wain KS, Sen A, Kim SH, J. Polym. Sci. A: Polym. Chem., 43(9), 1930, 2005
  18. Kim BC, Kim YH, Fukui K, Anal. Chim. Acta., 491, 71, 2003
  19. Joung OJ, Kim YH, Fukui K, Sens. Actuat. B-Chem., 105, 464, 2005
  20. Joung OJ, Kim YH, Maeda K, Fukui K, Korean J. Chem. Eng., 22(1), 99, 2005
  21. Joung OJ, Kim YH, Sens. Actuat. B-Chem., 113, 335, 2006
  22. Choi HS, Kim YH, Shin SM, J. Polym. Sci. A: Polym. Chem., 44(8), 2428, 2006
  23. Hedin J, Ostlund A, Nyden M, Carbohydr. Polym., 79, 606, 2010
  24. Sauerbrey GZ, Phyzik., 155, 206, 1959
  25. Calvo EJ, Etchenique R, Bartlett PN, Singhal K, Santamaria C, Faraday Discuss., 107, 141, 1997
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.