Issue
Korean Journal of Chemical Engineering,
Vol.13, No.4, 419-421, 1996
VIBRATIONAL SPECTROSCOPIC EVIDENCE FOR THE PRESENCE OF TiO6 STRUCTURAL UNITS IN TITANOSILICATE MOLECULAR SIEVE ETS-10
A comparison of infrared and Raman spectra of a titanosilicate molecular sieve ETS -10 with literature data on titanium-containing ZSM-5 (TS-1) and perovskite SrTiO3 provides conclusive evidence for the presence of intraframework TiO6 octahedral units in ETS-10. The appearance of a very strong band at 723 cm-1 in the Raman spectrum of ETS-10 suggests that the technique can be useful for the characterization of molecular sieves containing TiO6 structural units.
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