Issue
Korean Journal of Chemical Engineering,
Vol.28, No.5, 1221-1226, 2011
Nanoclays as nano adsorbent for oxidation of H2S into elemental sulfur
Modified bentonites were used for the oxidation of H2S into elemental sulfur. Active phases such as iron and cobalt sulfide were added to supports Cloisite 30B and 15A. The produced nano adsorbents were characterized by X-Ray diffraction, ICP, BET surface area and SEM. Selective oxidation of H2S was carried out over the nano adsorbent in the experimental setup. The tests were performed at 70 and 180 ℃, under atmospheric pressure and in the presence of 5,000 ppm of H2S in the inlet gas stream. The results confirmed the increase in the distribution of active metals and activity of Cloisite 30B, in comparison with Cloisite 15A. Cobalt-containing support showed significant improvement in the capacity of H2S removal, and in the outlet stream less than 50 ppm of H2S was detected.
[References]
  1. Wang R, Sep. Purif. Technol., 31(1), 111, 2003
  2. Sasaoka E, Hirano S, Kasaoka S, Sakata Y, Energy Fuels, 8(5), 1100, 1994
  3. Elsner MP, Menge M, Muller C, Agar DW, Catal. Today, 79(1-4), 487, 2003
  4. Van Den Brink P, Geus JW, US Patent, 5,286,697, 1994
  5. Berben PH, Geus JW, US Patent, 4,818,740, 1989
  6. Connock L, Sulphur., 257, 34, 1998
  7. Truong LVA, Abatzoglou N, Biomass Bioenerg., 29(2), 142, 2005
  8. Chun SW, Jang JY, Park DW, Woo HC, Chung JS, Appl. Catal. B: Environ., 16(3), 235, 1998
  9. Keller N, Pham-Huu C, Ledoux MJ, Appl. Catal. A: Gen., 217(1-2), 205, 2001
  10. Nguyen P, Edouard D, Nhut JM, Ledoux MJ, Pham C, Pham-Huu C, Appl. Catal. B: Environ., 76(3-4), 300, 2007
  11. Ania CO, Bandosz TJ, Energy Fuels, 20(3), 1076, 2006
  12. Bandosz TJ, Le Q, Carbon., 36, 39, 1998
  13. Bagreev A, Bandoz TJ, Carbon., 39, 2303, 2001
  14. Wang L, Cao B, Wang SD, Yuan Q, Chem. Eng. J., 118(3), 133, 2006
  15. Wang L, Cao B, Wang SD, Yuan Q, Chem. Eng. J., 118(3), 133, 2006
  16. Nahin PG, Sherbarne JE, US Patent, 2,243,049, 1960
  17. Krishna B, Prakash D, Appl. Clay Sci., 20, 65, 2001
  18. Mikhail S, Zaki T, Khalil L, Appl. Catal. A: Gen., 227(1-2), 265, 2002
  19. Adib A, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 34, 686, 2000
  20. Nguyen-Thanh D, Bandosz TJ, Carbon., 43, 359, 2005
  21. Nguyen D, Bandosz T, Micropor. Mesopor., 92, 47, 2006
  22. Stepova K, Maquarrie D, Krip I, Appl. Clay Sci., 42, 625, 2009
  23. Yilmaza O, Cheaburub CN, Durraccioc D, Gulumsera G, Vasileb C, Appl. Clay Sci., 49, 288, 2010
  24. Primavera A, Trovarelli A, Andreussi P, Dolcetti G, Appl. Catal. A: Gen., 173(2), 185, 1998
  25. Nhut JM, Nguyen P, Huu CP, Keller N, Ledoux MJ, Catal. Today., 92, 91, 2004