| Issue |
Korean Journal of Chemical Engineering,
Vol.12, No.2, 188-192, 1995
Vol.12, No.2, 188-192, 1995
A REACTION KINETIC STUDY ON THE GIF-TYPE BIOMIMETIC OXIDATION OF CYCLOHEXANE
Kinetics of the oxidation of cyclohexane under Gif type conditions have been studied. A kinetic model is proposed, which is in agreement with the experimental results obtained. The rate equation showed the first order with respect to cyclohexane. A temperature-dependence study of the reaction rate affords an activation energy of 14.3 kcal/mol.
[References]
- About-Jaudet E, Barton DHR, Csuhai E, Ozbalik N, Tetrahedron Lett., 31, 1657, 1990
- Amatsu H, Miyamoto TK, Sasaki Y, Bull. Chem. Soc. Jpn., 31, 3193, 1988
- Archakov AI, Bachmanopva GI, "Cytochrome P-450 and Active Oxygen," Taylor & Francis: London, 1990
- Balch AL, Lamar GN, Latos-Grazynski L, Renner MW, Thanabal V, J. Am. Chem. Soc., 107, 3003, 1985
- Barton DHR, Biviere SD, Chavasiri W, Csuhai E, Doller D, J. Am. Chem. Soc., 114, 2147, 1992
- Barton DHR, Gastiger MJ, Motherwell WB, J. Chem. Soc.-Chem. Commun., 41, 731, 1983
- Barton DHR, Lee KW, Mehr W, Ozbalik N, Zhang L, Tetrahedron, 46, 3753, 1990
- Chin DH, Balch AL, LaMar GM, J. Am. Chem. Soc., 102, 1446, 1980
- Collman JP, Brauman JI, Meunier B, Hayashi T, Kodadek T, Raybuck SA, J. Am. Chem. Soc., 107, 2000, 1985
- Dicken CM, Woon TC, Bruice TC, J. Am. Chem. Soc., 108, 1636, 1986
- Groves JT, Nemo TE, Meyers RS, J. Am. Chem. Soc., 101, 1032, 1979
- Lee KY, Kim SB, Kim YJ, Hong SI, Bull. Korean Chem. Soc., 15, 424, 1994
- Mansuy D, Bartoli JF, Momenteau M, Tetrahedron Lett., 23, 2781, 1982
- Nolte RJM, Razenberg JASJ, Schurman R, J. Am. Chem. Soc., 108, 2751, 1986
- Ojima R, Kobayashi N, Osa T, Bull. Chem. Soc. Jpn., 63, 1374, 1990
- Sugimoto H, Tung HC, Saywer DT, J. Am. Chem. Soc., 110, 2465, 1988
- Traylor TG, Miksatal AR, J. Am. Chem. Soc., 109, 2770, 1981
- Traylor TG, Xu F, J. Am. Chem. Soc., 10, 1953, 1988
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.