Issue
Korean Journal of Chemical Engineering,
Vol.12, No.2, 168-175, 1995
MATHEMATICAL ANALYSIS AND EXPERIMENTAL RESULTS OF APPLYING ENHANCED-SURFACE-AREA PACKED-BED ELECTRODES IN ELECTROGENERATIVE SULFUR DIOXIDE OXIDATION
The results of applying enhanced-surface-area packed-bed (ESAP) electrodes in electrogenerative SO2/O2 cells are reported to illustrate their utility and potential applications. Mathematical analysis with parameters pertinent to the experimental conditions shows that all electrocatalyst sites in these electrodes are expected to be uniformly utilized for electrochemical SO2 oxidation. Experimental results showed that ESAP electrodes (1 mgPt/cm2) could provide at least 5 times higher SO2 conversion at given cell voltages than graphite sheet electrodes(1.5 mgPt/cm2).
[References]
  1. Appleby AJ, Pichon B, J. Electroanal. Chem., 95, 59, 1979
  2. Austin LG, Mariet M, Walker RD, Wood GB, Comyn RH, Ind. Eng. Chem., 4, 321, 1965
  3. Bard AJ, Faulkner LR, "Electrochemical Methods-Fundamentals and Applications," Wiley, New York, 1982
  4. Card JC, Foral MJ, Langer SH, Environ. Sci. Technol., 22, 1499, 1988
  5. Card JC, Valentin G, Storck A, J. Electrochem. Soc., 137, 2736, 1990
  6. Card JC, Lyke SE, Langer SH, J. Appl. Electrochem., 20, 269, 1990
  7. Comtat M, Mahenc J, Bull. Soc. Chim. France, 11, 3862, 1969
  8. Drazic DM, Adzic RR, Electrochim. Acta, 14, 405, 1969
  9. Fleet B, "Electrochemistry, Past and Present," Stock, J.T. and Orna, M.V., eds., ACS Symp. Ser., 390, Canada, 1990
  10. Gileadi E, "Electrosorption," Plenum Press, New York, 1967
  11. Goodenough JB, Hamnett A, Kennedy BJ, Monoharan R, Weeks SA, Electrochim. Acta, 35(1), 199, 1990
  12. Hollax E, Schwabe K, Wiesener K, "Electrochemical Disposal of Industrial Waste Gases and Development of a Double-Layer Electrodes," DECHEMA Monogr., 59 (1045-1069), 147, 1968
  13. Huss A, Lim PK, Eckert CA, J. Phys. Chem., 86, 4224, 1982
  14. Katagiri A, Takehara Z, Yoshizawa S, Denki Kagaku, 41, 692, 1973
  15. Kinoshita K, Stonehart P, "Modern Aspects Electrochemistry," vol. 12, Bockris, J.O'M. and Conway, B.E., eds., Chap. 4, Plenum Press, New York, 1977
  16. Kinoshita K, "Carbon," John Wiley & Sons, New York, 1988
  17. Langer SH, Sakellaropoulos GP, Ind. Eng. Chem. Process Des. Dev., 18(4), 567, 1979
  18. Lu PWT, Ammon RL, J. Electrochem. Soc., 127(12), 2610, 1980
  19. Lu PWT, Spotnitz R, J. Electrochem. Soc., 128(6), 1298, 1981
  20. Lyke SE, Langer SH, J. Electrochem. Soc., 138, 1682, 1991
  21. Lyke SE, Langer SH, J. Electrochem. Soc., 138, 2327, 1991
  22. Mclntyre JA, Phillips RF, "Electrochemical Process and Plant Design," Alkire, R.C., Beck, T.R. and Varjian, R.D., eds., pp. 79-97, The Electrochemical Society Softbound Proceedings Series, Princeton, NJ, 1982
  23. Mclntyre JA, Phillips RF, U.S. Patent, 4,457,953, 1984
  24. Newman JS, Tobias CW, J. Electrochem. Soc., 109(12), 1183, 1962
  25. Newman J, Tiedemann W, AIChE J., 21(1), 25, 1975
  26. Newman JS, Tiedemann W, "Advances in Electrochemistry and Electrochemical Engineering," Delahay, P., eds., Vol. 11, pp. 353-438, Interscience, New York, 1978
  27. Newman JS, "Electrochemical Systems," 2nd ed., Prentice-Hall, Inc., Englewood Cliffs, New Jersey, 1991
  28. Oloman C, "Tutorial Lectures in Electrochemical Engineering and Technology," Alkire, R. and Chin. D.T., eds., AIChE Symp. Ser., 79(229), New York, 1983
  29. Oloman C, Matte M, Lum C, J. Electrochem. Soc., 138, 2330, 1991
  30. Scott K, Winnick J, Gas. Sep. Purif., 2, 23, 1988
  31. Seo ET, Sawyer DT, J. Electroanal. Chem., 7, 184, 1964
  32. Seo ET, Sawyer DT, Electrochim. Acta, 10, 239, 1965
  33. Srinivasan S, "Electrocatalysis," Advances in Catalysis and Related Subjects, Eley, D.D., eds., Vol. 17, Academic Press, New York, 1967
  34. Srinivasan S, Hurwitz HD, Bockris JOM, J. Chem. Phys., 46(8), 3108, 1967
  35. Srinivasan S, Hurwitz HD, Electrochim. Acta, 12, 495, 1967
  36. Struck BD, Junginger R, Neumeister H, Dujka B, Int. J. Hydrog. Energy, 7(1), 43, 1982
  37. Townley D, Winnick J, Ind. Eng. Chem. Process Des. Dev., 20, 435, 1981
  38. Wilson FJ, Geankoplis CJ, Ind. Eng. Chem. Fundam., 5, 9, 1966
  39. Winnick J, "Electrochemical Separation of Gases," Advances in Electrochemical Science and Engineering, Gerischer, H. and Tobias, C.W., eds., Vol. 1, p. 205, 1990