Issue
Korean Journal of Chemical Engineering,
Vol.10, No.2, 124-126, 1993
A PREDICTION OF THE ABNORMAL BEHAVIOR IN THE VISCOSITY OF LIQUID WATER UNDER PRESSURE
A phenomenological theory of viscosity proposed by authors was applied to liquid water under high pressure. Thermodynamic properties used in the calculation were obtained by using the theory of liquid proposed by Pak[13]. The calculated viscosities decreased abnormally with increasing pressure. We found this behavior was due to the decrease of the absolute value of kinetic and internal pressure with the pressure increase near 273.15 K.
[References]
  1. Bridgman PW, Proc. Am. Acad. Arts Sci., 61, 57, 1926
  2. Tammann G, Rabe H, Z. Allgem. Chem., 168, 73, 1927
  3. Bett KE, Cappi JB, Nature, 207, 602, 1965
  4. Webber W, Z. Angew. Phys., 15, 342, 1963
  5. Einstein A, Ann. Physik., 19, 289, 1906
  6. Jhon MS, Grosh J, Ree T, Eyring H, J. Chem. Phys., 44, 1486, 1966
  7. Eyring H, Jhon MS, Chemistry, 39, 12, 1966
  8. Chair TS, Kim W, Pak H, Jhon MS, Korean J. Chem. Eng., 6(2), 121, 1989
  9. Kim W, Bull. Korean Chem. Soc., 9, 213, 1988
  10. Kim W, Pak H, Chair TS, Bull. Korean Chem. Soc., 10, 372, 1989
  11. Kim W, Pak H, Chair TS, Bull. Korean Chem. Soc., 11, 28, 1990
  12. Kim W, Chair TS, Bull. Korean Chem. Soc., 11, 446, 1990
  13. Pak H, Korean Chem. Soc., 20, 460, 1976
  14. Horne RA, Johnson DS, J. Phys. Chem., 70, 2182, 1966
  15. Kerr EC, Taylor RD, Ann. Phys., 26, 292, 1964
  16. Rowlinson JS, Swinton FL, "Liquid and Liquid Mixture," 3rd ed., Butterworth Scientific, London, 46, 1982