Issue
Korean Journal of Chemical Engineering,
Vol.7, No.1, 13-17, 1990
ABSORPTION OF NOx IN PACKED COLUMN(II)-COMPARISON OF EXPERIMENTAL WITH THEORETICAL-
An absorption efficiency of packed column removing nitrogen oxides with water and NaOH solution under atmospheric pressure was studied. The efficiency and the acidity produced by absorption of NOx were measured in a packed column. The model developed that was based on the mass-transfer information for packed column and absorption mechanism accompanying the chemical reaction was compared with experimental results. Predictions using the model presented by the previous paper(part I) was shown well to agree with from the experimental results(part II). The efficiency of NOx absorption is largely dependent on the height of packing material and the partial pressure of NOx in the feed gas. The efficiency of NOx absorption decreases with the increase of the acidity produced by recycling of were as a scrubber liquid. For the recycle mode with an aqueous NaOH solution as a scrubber liquid, NOx absorption efficiency is shown to be constant until all of the COH- in the scrubber liquid are converted into CHH+.
[References]
  1. Saltzman BE, Anal. Chem., 26, 1949, 1954
  2. Lee HK, Chun KS, Park HS, Cho JH, Korean J. Chem. Eng., 6(4), 294, 1989
  3. Levenspiel O, Chemical Reaction Engineering," John Wiley, NY, 1972
  4. Lee HK, Cheong MS, Chun KS, Park HS, HWAHAK KONGHAK, 24(4), 255, 1986
  5. Kim BT, Lee HK, Chun KS, Lee KJ, Park HS, HWAHAK KONGHAK, 25(2), 169, 1987
  6. Peters MS, Holman JL, Ind. Eng. Chem., 47, 2536, 1955