Issue
Korean Journal of Chemical Engineering,
Vol.27, No.5, 1469-1475, 2010
Removal of acid dye (violet 54) and adsorption kinetics model of using musa spp. waste: A low-cost natural sorbent material
Experimental studies and biosorption kinetics of an intraparticle diffusion model for acid dye removal using a musa spp. waste sorbent were carried out to find the removal effects and dynamics of various operating parameters, such as initial dye concentration, sorbent dosage, pH and temperature. Experimental data were modeled with kinetic models and two biosorption isotherms of intraparticle diffusion models as well as the physiochemical data of sorbents characterized by SEM and FT-IR. Kinetic studies showed that the sorption process follows second-order rate kinetics with an average rate constant of 0.0018675 (g/mg·min). Thermodynamic parameters such as entropy of biosorption (ΔS°), enthalpy of biosorption (ΔH°) and Gibbs free energy of biosorption (ΔG°) were obtained and analyzed. Sorbent, musa spp. waste (banana peel) was characterized by FTIR and SEM. The results showed that musa spp. waste can be considered as potential sorbent for the sorption of acid violet 54 from dilute aqueous solution.
[References]
  1. Ray PK, J. Sci. Ind. Res., 45, 370, 1986
  2. Lee JW, Choi SP, Thiruvenkatachari R, Shim WG, Moon H, Dyes Pigments., 69, 196, 2006
  3. Nigam P, Armour G, Banat IM, Singh D, Marchant R, Bioresour. Technol., 72(3), 219, 2000
  4. Seshdari S, Bishop PL, Agha AM, Waste Manage., 15, 127, 1994
  5. Ramakrishna KR, Viraraghavan T, Water Sci. Technol., 36, 189, 1997
  6. Garg VK, Kumar R, Gupta R, Dyes Pigments., 62, 1, 2004
  7. Aksu Z, Process Biochem., 40, 997, 2005
  8. Won SW, Choi SB, Yun YS, Colloids Surfaces A: Phys. Eng. Aspects., 262, 175, 2005
  9. Won SW, Choi SB, Yun YS, Biochem. Eng. J., 28, 208, 2006
  10. Meshko V, Markovska L, Mincheva M, Rodrigues AE, Water Res., 35, 3357, 2001
  11. Kannan N, Sundaram MM, Dyes Pigments., 51, 25, 2001
  12. EL-Geundi MS, Adsorpt. Sci. Technol., 15, 777, 1997
  13. Annadurai G, Juang RS, Lee DJ, Adv. Environ. Res., 6, 191, 2002
  14. Waranusantigul P, Pokethitiyook P, Kruatrachue M, Upatham ES, Environ. Pollut., 125, 385, 2003
  15. Namasivayam C, Muniasamy N, Gayatri K, Rani M, Ranganathan K, Bioresour. Technol., 57(1), 37, 1996
  16. Han RP, Wang YF, Yu WH, Zou WH, Shi H, Liu HM, J. Hazard. Mater., 141(3), 713, 2007
  17. Chuah TG, Jumasiah A, Azni I, Katayon S, Choong SYT, Desalination, 175(3), 305, 2005
  18. Oliveira LS, Franca AS, Alves TM, Rocha SDF, J. Hazard. Mater., 155(3), 507, 2008
  19. Arami M, Limaee NY, Mahmoodi NM, Tabrizi NS, J. Hazard. Mater., B135, 171, 2006
  20. Akar T, Ozcan AS, Tunali S, Ozcan A, Bioresour. Technol., 99(8), 3057, 2008
  21. Hameed BH, Mahmoud DK, Ahmad AL, J. Hazard. Mater., 158(1), 65, 2008
  22. Medeiros RG, Soffner MLAP, Thome JA, Cacais AOG, Estelles RS, Salles BC, Ferreira HM, Neto SAL, Silva FG, Filho EXF, Biotechnol. Prog., 16(3), 522, 2000
  23. Shibi IG, Anirudhan TS, Chemosphere., 58, 1117, 2005
  24. Srivastava SK, Gupta VK, Mohan D, J. Env. Modeling Assessment., 1, 281, 1998
  25. Sumanjit, Walia TPS, Kaur R, J. Health Allied Scs., 3, 3, 2007
  26. Vijayakumar G, Dharmendirakumar M, Renganathan S, Sivanesan S, Baskar G, Elango KP, Clean-soil Air Water., 37(4-5), 355, 2009
  27. Nandi BK, Goswami A, Das AK, Mondal B, Purkait MK, Sep. Sci. Technol., 43(6), 1382, 2008
  28. Vadivelan V, Vasanthakumar K, J. Colloid Interf. Sci., 286, 91, 2005
  29. Langmuir I, J. Am. Chem. Soc., 40, 1361, 1918
  30. Hall KR, Eagleton LC, Acrivos A, Vermeulen T, IEC Fundam., 5, 212, 1966
  31. Freundlich H, J. Phys. Chem., 57, 384, 1906
  32. Treybal RE, Mass Transfer Operations, 2nd Ed., McGraw Hill, New York, 1968
  33. Ho YS, McKay G, Chem. Eng. J., 70, 115, 1978
  34. Lagergren S, Handlingar., 24, 1, 1898
  35. McKay G, Ho YS, Water Res., 33, 578, 1999
  36. Weber WJ, Morris JC, Proceedings of the International Conference on Water Pollution Symposium 2, Pergamon, Oxford, 231, 1962
  37. Weber WJ, Morris JJC, J. Sanitary Eng. Div. Proceed. Am. Soc. Civil Eng., 89, 31, 1963