Issue
Korean Journal of Chemical Engineering,
Vol.27, No.5, 1560-1564, 2010
Preparation of sawdust functionalized with aspartic acid and its sorption capacity, kinetics and thermodynamics for basic dyes
An ion exchanger with carboxyl groups as active sites was prepared by activating sawdust with epichlorohydrin, followed by coupling the epoxy-activated sawdust with aspartic acid. The optimal sorption condition, sorption capacity, kinetics and thermodynamics of basic dyes on sawdust ion exchanger (SIE) from aqueous solution were investigated in a batch system. Two basic dyes, methylene blue (MB) and crystal violet (CV), were selected as sorbates. The optimal pH value of MB and CV solutions for favorable sorption was pH 4 and above. The removal ratios of MB and CV on SIE increased with increasing sorbent dose but decreased with increasing dye concentration. The isothermal data of MB and CV sorbed on SIE correlated basically with the Langmuir model. The maximum sorption capacity (Qm) of SIE for MB and CV was 222.22 and 232.56 mg/g, respectively. The sorption equilibriums of MB and CV on SIE were reached at about 9 h, and the sorption processes could be described by the pseudo-second-order kinetic model. The thermodynamic study indicated that the sorptions of MB and CV on SIE were spontaneous and endothermic at the predetermined temperatures. High temperatures were favorable for the sorption processes.
[References]
  1. Pearce CI, Lloyd JR, Guthrie JT, Dyes Pigments., 58, 179, 2003
  2. McMullan G, Meehan C, Conneely A, Kirby N, Robinson T, Nigam P, Banat IM, Marchant R, Smyth WE, Appl. Microbiol. Biotechnol., 56(1-2), 81, 2001
  3. McKay G, Otterburn MS, Aga DA, Water Air Soil Pollut., 24, 307, 1985
  4. Gregory AR, Elliot S, Kluge P, J. Appl. Toxicol., 1, 308, 1991
  5. Kim BK, Kim YH, Yamamoto T, Korean J. Chem. Eng., 25(5), 1140, 2008
  6. Allen SJ, Gan Q, Matthews R, Johnson PA, Bioresour. Technol., 88, 143, 2003
  7. Vadivelan V, Kumar KV, J. Colloid Interface Sci., 286(1), 90, 2005
  8. Gong RM, Li M, Yang C, Sun YZ, Chen J, J. Hazard. Mater., 121(1-3), 247, 2005
  9. Bulut Y, Aydin H, Desalination, 194(1-3), 259, 2006
  10. Sulak MT, Demirbas E, Kobya M, Bioresour. Technol., 98(13), 2590, 2007
  11. Kumar KV, Dyes Pigments., 74, 595, 2007
  12. Osma JF, Saravia V, Toca-Herrera JL, Couto SR, J. Hazard. Mater., 147(3), 900, 2007
  13. Hameed BH, El-Khaiary MI, J. Hazard. Mater., 154(1-3), 639, 2008
  14. Hameed BH, Mahmoud DK, Ahmad AL, Colloid. Surface. A., 316, 78, 2008
  15. Pavan FA, Lima EC, Dias SLP. Mazzocato AC, J. Hazard.Mater., 150, 703, 2008
  16. Marchetti V, Gerardin P, Loubinoux B, Holz Roh Werkst., 58, 53, 2000
  17. Gong RM, Jin YB, Chen FY, Chen J, Liu ZL, J. Hazard. Mater., 137(2), 865, 2006
  18. Ong ST, Lee CK, Zainal Z, Bioresour. Technol., 98(15), 2792, 2007
  19. Sureshkumar MV, Namasivayam C, Colloid. Surface. A., 317, 277, 2008
  20. Disbudak A, Bektas S, Patir S, Genc O, Denizli A, Sep. Purif. Technol., 26(2-3), 273, 2002
  21. Gupta SC, Dass P, Sharma P, Singh AV, Gupta S, Desalination, 143(2), 141, 2002
  22. Oshita K, Oshima M, Gao Y, Lee KH, Motomizu S, Anal.Chim. Acta., 480, 239, 2003
  23. Lei YL, Lin DQ, Yao SJ, Zhu ZQ, React. Funct. Polym., 62, 169, 2005
  24. Chakraborty S, De S, DasGupta S, Basu JK, Chemosphere., 58, 1079, 2005
  25. Vinod VP, Anirudhan TS, Water Air Soil Pollut., 150, 193, 2003
  26. Porkodi K, Kumar KV, J. Hazard. Mater., 143(1-2), 311, 2007