Issue
Korean Journal of Chemical Engineering,
Vol.27, No.3, 977-982, 2010
Hybrid supercapacitor based on poly(aniline-co-m-anilicacid) and activated carbon in non-aqueous electrolyte
A hybrid asymmetrical super capacitor has been fabricated based on p-doped poly(aniline-co-m-anilicacid) and activated carbon coated on SS electrodes. The characterization of material, electrode and performance of the super capacitor has been studied by FTIR, Cyclic Voltammetry, TGA/DTA, AC Impedance spectroscopy, and galvanostatic charge-discharge tests. The super capacitor showed a maximum specific capacitance of 102 F/g at a scan rate of 10 mV/s. The normalized active-reactive power behavior of the capacitor has been determined. The time constant calculated for the super capacitor is 6 milliseconds, indicating the suitability of the system for efficient use at low frequency range.
[References]
  1. Croce P, Passerini S, Scrosati B, J. Electrochem. Soc., 141(6), 1405, 1994
  2. Osaka T, Komaba S, Fujihana K, Okamoto N, Momma T, Kaneko N, J. Electrochem. Soc., 144(2), 742, 1997
  3. Kitteson GP, White HS, Wrighton MS, J. Am. Chem. Soc., 106, 7389, 1984
  4. Mattes BR, Wang H, Yang D, Zhu YT, Blamenthal WR, Hundley MF, Synth. Met., 45, 84, 1997
  5. Rudge A, Davey J, Raistrick J, Gottesteid S, J. Power Sources., 47, 89, 1994
  6. Libent J, Bredas JW, Esptein AJ, Phys. Rev. B., 51, 5711, 1995
  7. Hua MY, Hwang GW, Chuang YH, Chen SA, Tsai RY, Macromolecules, 33(17), 6235, 2000
  8. Karyakin AA, Strakhova AK, Yatsimirsky AK, J. Electroanal. Chem., 259, 371, 1994
  9. Shenglong W, Fosong W, Xiabhui G, Synth. Met., 16, 99, 1998
  10. Leclerc M, Guay J, Dao LH, J. Electroanal. Chem., 21, 251, 1988
  11. Macinnes D, Funt BL, Synth. Met., 25, 235, 1998
  12. Gazotti WA, Matencio T, De Paoli MA, Electrochim. Acta, 43(5-6), 457, 1998
  13. Wang XH, Wang LX, Jing XP, Wang FS, Synth. Met., 69, 335, 1995
  14. Ranger M, Leclerc M, Synth. Met., 84, 85, 1997
  15. Christopher MA, Brett Thiemann C, J. Electroanal. Chem., 538, 215, 2002
  16. Ryu K, Kim K, Park N, Park Y, Chang S, J. Power Sources, 103, 305, 2002
  17. Park JH, Park OO, J. Power Sources, 111(1), 185, 2002
  18. Hatchett DW, Josowicz M, Janata J, J. Electrochem. Soc., 146(12), 4535, 1999
  19. Ryu KS, Kim KM, Park NG, Park YJ, Chang SH, J. Power Sources, 103(2), 305, 2002
  20. Clemente A, Panero S, Spila E, Scrosati B, Solid State Ion., 85(1-4), 273, 1996
  21. Arbizzani C, Mastragostino M, Soavi F, J. Power Sources, 100(1-2), 164, 2001
  22. Ryu KS, Lee YG, Hong YS, Park YJ, Wu XL, Kim KM, Kang MG, Park NG, Chang SH, Electrochim. Acta, 50(2-3), 843, 2004
  23. Seo KI, Chung IJ, Polym., 41, 4491, 2004
  24. Tranvan F, Garreau S, Louarn G, Froyer G, Chevrot C, J.Mater Chem., 11, 1378, 2001
  25. Hatchett DW, Josowicz M, Janata J, J. Electrochem. Soc., 146(12), 4535, 1999
  26. Wei Y, Hsueh KF, J. Polym. Sci., 27, 4351, 1989
  27. Ansari R, Price WE, Wallace GG, React. Funct. Polym., 56, 141, 2003
  28. Hagiwara T,Yamaura M, Iwata K, Synth. Met., 25, 243, 1988
  29. B. E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic Publishers, Plenum press, New York, 1999
  30. Qu DY, Shi H, J. Power Sources, 74(1), 99, 1998
  31. Song HK, Jung YH, Lee KH, Dao LH, Electrochim. Acta, 44(20), 3513, 1999
  32. Keiser H, Beccu KD, Gutjahr MA, Electrochim Acta., 12, 539, 1976
  33. Taberna PL, Simon P, Fauvarque JF, J. Electrochem. Soc., 150(3), A292, 2003
  34. Zheng JP, Huang J, Jow TR, J. Electrochem. Soc., 144(6), 2026, 1997