Issue
Korean Journal of Chemical Engineering,
Vol.27, No.1, 163-167, 2010
Thermogravimetric characteristics and pyrolysis kinetics of Giheung Respia sewage sludge
Sewage sludge acquired from Giheung Respia treatment facility was characterized and converted into gas, bio-oil and char by pyrolysis. The rate of conversion as a function of temperature was obtained from differential thermogravimetric analysis (DTG) for different heating rates. The activation energy calculated from data selected conversions shows that the activation energy decreased with increasing conversion up to 10%, steadily increased from 10 to 70%, and substantially increased from 70 to 90%. Depending on the level of conversion, the values of activation energies varied between 181 and 659 kJ/mol. The gas product obtained in the experiment at 450 ℃, 20 min mainly included CO2 (30%), CO (23%) and CH4 (17%). The product yields of gas, oil and char were systematically studied by changing the pyrolysis temperature and residence time.
[References]
  1. Lundin M, Olofsson M, Pettersson G, Zetterlund H, Resource Conservation and Recycling, 41, 255, 2004
  2. Minimi G, Di R, Zuccarello B, Lotito V, Spinosa L, DiPinto AC, Water Sci. Technol., 36, 211, 1997
  3. Malerius O, Werther J, Chem. Eng. J., 96(1-3), 197, 2003
  4. Khiari B, Marias F, Zagrouba F, Vaxelaire J, Desalination, 167(1-3), 39, 2004
  5. Choung YH, Cho KC, Choi WJ, Kim SG, Han YS, Oh KJ, Korean J. Chem. Eng., 24(4), 660, 2007
  6. Annual Book of ASTM Standards, 1997
  7. Annual Book of ASTM Standards, 1999
  8. Standard Methods. See also - http://www.standardmethods.org/
  9. Park YH, Kim J, Kim SS, Park YK, Bioresource Technology, 100, 400, 2009
  10. Hanaoka T, Inoue S, Uno S, Ogi T, Minowa T, Biomass Bioenerg., 28(1), 69, 2005
  11. Parnaudeau V, Dignac MF, J. Anal. Appl. Pyr., 78, 140, 2007
  12. Demirbas A, Fuel, 76(5), 431, 1997
  13. Lapuerta M, Hernandez JJ, Rodriguez J, Biomass Bioenerg., 31(1), 13, 2007
  14. Caballero JA, Font R, Marcilla A, Conesa JA, J. Anal. Appl. Pyr., 40, 433, 1997
  15. Sinfelt JH, Rohrer JC, J. Phys. Chem., 66, 1559, 1962
  16. Yaman S, Energy Conv. Manag., 45(5), 651, 2004
  17. REED TB, GAUR S, Biomass Bioenerg., 7(1-6), 143, 1994
  18. Vamvuka D, Kakaras E, Kastanaki E, Grammelis P, Fuel, 82, 1949, 2003
  19. Meier D, Faix O, Bioresour. Technol., 68(1), 71, 1999
  20. Chen G, Andries J, Luo Z, Spliethoff H, Energy Conv. Manag., 44(11), 1875, 2003