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Issue
Korean Journal of Chemical Engineering,
Vol.27, No.1, 152-158, 2010
Adsorption of Nickel from aqueous solution by the use of low-cost adsorbents
Hannachi Y, Shapovalov NA, Hannachi A
The removal of Ni(II) from aqueous solution by different adsorbents was investigated. Calcined phosphate, red mud, and clarified sludge (a steel industry waste material) were used for the adsorption studies. The influence of pH, contact time, initial metal concentration, adsorbent nature and concentration on the selectivity and sensitivity of the removal process was investigated. The adsorption process was found to follow a first-order rate mechanism and rate constant was evaluated at 30 ℃. Langmuir and Freundlich adsorption isotherms fit well in the experimental data and their constants were evaluated. The thermodynamic equilibrium constant and the Gibbs free energy were calculated for each system. The adsorption capacity (q(max)) calculated from Langmuir isotherm and the values of Gibbs free energy obtained showed that calcined phosphate has a higher capacity and affinity for the removal of Ni(II) compared to the other adsorbents used in the study.
Keywords: Calcined Phosphate; Red Mud; Clarified Sludge; Langmuir Isotherm; Freundlich Isotherm; Gibbs Free Energy; First-order Rate Mechanism
[References]
  1. Bencko V, J. Hyg. Epidemiol. Microbiol. Immunol., 27, 237, 1983
  2. Barton RT, Hogetveit AC, Cancer, 45, 3061, 1980
  3. Norseth T, J. Toxicol. Environ. Health, 6, 1219, 1980
  4. Morgan LG, Valerie U, Ann. Occup. Hyg., 38, 189, 1994
  5. Kazimierz S, Kasprzak F, William S, Konstantin S, Mutat. Res., Fundam. Mol. Mech. Mutagen., 553, 67, 2003
  6. Hanif MA, Nadeem R, Zafar MN, Akhtar K, Bhatti HN, J. Hazard. Mater., 145(3), 501, 2007
  7. Babel S, Kurniawan TA, J. Hazard. Mater., 97(1-3), 219, 2003
  8. Carrasco-Martin F, Mueden A, Centeno TA, Stoeckli F, Moreno-Castilla C, J. Chem. Soc. Faraday Trans., 93, 2211, 1997
  9. van den Brandt P, Voorrips L, Hertz Picciotto I, Shuker L, Boeing H, Speijers G, Guittard C, Knowles M, Wolk A, Goldbohm A, Food Chem. Toxicol., 40, 387, 2002
  10. Brach Papa C, Coulomb B, Boudenne JL, Cerda V, Theraulaz F, Anal. Chem. Acta, 457, 311, 2002
  11. Patterson JW, Industrial wastewater treatment technology, second ed., Butterworth-Heinemann, London, 1985
  12. Tavlaride LL, Bae JH, Lee CK, Sep. Sci. Technol., 22, 581, 1987
  13. Karabulut S, Karabakan A, Denizli A, Yurum Y, Sep. Purif. Technol., 18(3), 177, 2000
  14. Brown PA, Gill SA, Allen SJ, Water Res., 34, 3907, 2000
  15. Axtell NR, Sternberg SPK, Claussen K, Bioresour. Technol., 89(1), 41, 2003
  16. Kandah MI, Sep. Purif. Technol., 35(1), 61, 2004
  17. Poon CPC, Removal of Cd(II) from wastewater, in: Mislin H, Raverva O (Eds.), Cadmium in the Environment, Birkha User Basal, Switzerland, 6, 1986
  18. Seco A, Gabaldon C, Marzal P, Aucejo A, J. Chem. Technol. Biotechnol., 74(9), 911, 1999
  19. Corapcioglu MO, Haung CP, Water Res., 21, 1031, 1987
  20. Reed BE, Nonavivakere SK, Sep. Sci. Technol., 27, 1985, 1992
  21. Murano E, Ital. J. Biochem., 42, 303A, 1993
  22. Gao YM, Sengupta AK, Simpson D, Water Res., 29, 2195, 1995
  23. Lothenbach B, Furrer G, Schulin R, Environ. Sci. Technol., 31, 1452, 1997
  24. Gaikwad RW, Bhardwaj V, Indian J. Environ. Health, 37, 111, 1975
  25. Srivastava RK, Ayachi AK, Sehgal V, Ind. J. Environ. Prot., 21, 154, 2000
  26. Reddad Z, Gerente C, Andres Y, Cloirec P, Environ. Sci. Technol., 36, 2067, 2002
  27. Celis R, Hermosin JC, Environ. Sci. Technol., 34, 4593, 2000
  28. Cooper C, Jiang JQ, Ouki S, J. Chem. Technol. Biotechnol., 77(5), 546, 2002
  29. Muzzarelli RAA, Rocchetti R, Metal adsorption by modified chitins, in: Thomson R (Ed.), Trace Metal Removal from Aqueous Solution, The Royal Society of Chemistry, London, 44, 1986
  30. Kadirvelu K, Namasivayam C, Adv. Environ. Res., 7, 471, 2003
  31. Sag Y, Kutsal T, Biochem. Eng. J., 6, 145, 2000
  32. Liu HL, Chen BY, Lan YW, Cheng YC, Chem. Eng. J., 97(2-3), 195, 2004
  33. Scott J, Guang D, Naeramitmarnsuk K, Thabuot M, Amal R, J. Chem. Technol. Biotechnol., 77(1), 63, 2002
  34. Panayotova M, Velikov B, J. Environ. Sci. Health Part A, 37, 139, 2002
  35. Marshall WE, Johns MM, J. Chem. Technol. Biotechnol., 66(2), 192, 1996
  36. Sun G, Shi WX, Ind. Eng. Chem. Res., 37(4), 1324, 1998
  37. Lee TW, Khan ARM, Environ. Technol., 9, 1223, 1988
  38. Lee DH, Moon H, Korean J. Chem. Eng., 18(2), 247, 2001
  39. Ferro-Garcia MA, Rivera-Utrilla J, Rodriguez-Gordillo J, Bautista-Toledo I, Carbon, 26, 363, 1988
  40. Zhou XD, Kot SC, J. Environ. Hyd., 3, 367, 1995
  41. Namasivayam C, Periasamy K, Water Res., 27, 1663, 1993
  42. Khan SA, Rehman R, Khan MA, Waste Manage., 15, 271, 1995
  43. Sciban M, Klasnja M, Cent. Eur. J. Occup. Environ. Med., 9, 337, 2003
  44. Sciban M, Klasnja M, Holz. Roh. Werkst., 62, 69, 2004
  45. Gupta VK, Sharma S, Ind. Eng. Chem. Res., 42(25), 6619, 2003
  46. Annadurai G, Juang RS, Lee DJ, Water Sci. Technol., 47, 185, 2003
  47. Eslamzadeh T, Nasernejad B, Pour BB, Zamani A, Bygi ME, Iranian J. Sci. Technol. Trans. A, 28A1, 161, 2004
  48. Standard Methods for Examination of Water and Wastewater, 20th ed., APHA, AWWA, Washington, DC, New York, 1998
  49. Namasivayam C, Yamuna RT, Chemosphere, 30, 561, 1995
  50. Kandah MI, Sep. Purif. Technol., 35(1), 61, 2004
  51. Kalyani S, Priya A, Rao SP, Krishnaiah A, Indian J. Environ. Health, 45, 163, 2003
  52. Zouboulis AI, Lazaridis NK, Matis KA, J. Chem. Technol. Biotechnol., 77(8), 958, 2002
  53. Dakiky M, Khamis M, Manassra M, Mer’eb M, Adv. Environ. Res., 6, 533, 2002
  54. Weber TW, Chakraborti RK, AIChE J., 20, 228, 1974
  55. McKay G, Blair HS, Gardener JR, J. Appl. Polym. Sci., 27, 3043, 1982
  56. Calace N, Di Muro A, Nardi E, Petronio BM, Pietroletti M, Ind. Eng. Chem. Res., 41(22), 5491, 2002
[Cited By]
  1. Panda L, Das B, Rao DS, Korean Journal of Chemical Engineering, 28(10), 2024, 2011
  2. He L, Wang BB, Liu DD, Qian KS, Xu HB, Korean Journal of Chemical Engineering, 31(2), 343, 2014
  3. Ciobanu G, Harja M, Rusu L, Mocanu AM, Luca C, Korean Journal of Chemical Engineering, 31(6), 1021, 2014
  4. Li X, Li F, Fang L, Korean Journal of Chemical Engineering, 32(12), 2449, 2015
  5. Srivastava S, Agrawal SB, Mondal MK, Korean Journal of Chemical Engineering, 33(2), 567, 2016
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