Issue
Korean Journal of Chemical Engineering,
Vol.26, No.5, 1259-1264, 2009
The effect of additive chemicals on the viscosity of coal-petroleum coke-water slurry fuel for a gasification process
As a preliminary study for the gasification of an anthracite and petroleum coke mixture, viscosity was measured at various temperatures (20-50 ℃), slurry concentrations (60-70 wt%) and additive amounts (0-0.8 wt%) by using an LV-II type viscometer. In addition, four types of different additives, sodium naphthalene sulfonate, poly(methyl methacrylate), polypropylene and a polypropylene glycol based additive, were applied to Korean anthracite, petroleum coke and mixtures of these materials, and the viscosity data were compared. Viscosity dependency values for coal, anthracite, bituminous and sub-bituminous coal, were compared, and it was found that a high content of moisture and particularly ash increases CWS viscosity. The four types of additives tested in this research can effectively diminish the viscosity of coal and especially petroleum coke-water slurry by more than 70% to 95%, respectively. Moreover, the sodium naphthalene sulfonate-based additive reduced the viscosity of coal and petroleum coke-water slurry best, especially at concentrations in excess of 65 wt%. Based on these results, highly loaded slurry created by mixing anthracite and petroleum coke with additives was achieved.
[References]
  1. Crawford RJ, Mainwaring DE, Fuel, 80(3), 313, 2001
  2. Kikkawa H, Takezaki H, Otani Y, Shoji K, Powder Technol., 55, 277, 1988
  3. Gross AE, Branning ML, Fong DW, US patent, 4,462,808, 1984
  4. Pawlik M, Colloids and Surfaces A: Physicochem. Eng. Aspects, 266, 82, 2005
  5. Cho H, Klima MS, Energy Fuels, 10(6), 1220, 1996
  6. Burdukov AP, Popov VI, Tomilov VG, Fedosenko VD, Fuel, 81, 927, 2002
  7. Choudhury PR, Prog. Energy Combust. Sci., 18, 409, 1992
  8. Atesok G, Boylu F, Sirkeci AA, Dincer H, Fuel, 81, 1855, 2002
  9. Ogura T, Tanoura M, Hiraki A, Bull. Chem. Soc. Jpn., 66, 1343, 1993
  10. Zhou LZ, Zhu SQ, J. Chem. Ind. Eng., 55, 775, 2004
  11. Heek KH, Strobel BO, Wanzl W, Fuel, 73, 1135, 1994
  12. Higman C, Burgt M, Gasification, Elsevier, New York, 2003
  13. Wang J, Anthony EJ, Abanades JC, Fuel, 83, 1341, 2004
  14. Ahn YK, Fischer WH, Int. J. Hydrogen Energy, 11, 783, 1986
  15. Gersten J, Fainberg V, Hetsconi G, Shidler Y, Fuel, 79, 1679, 2000
  16. Jones JM, Kubacki M, Kubica K, Ross AB, Williams A, J. Anal. Appl. Pyrolysis, 74, 502, 2005
  17. Moghtaderi B, Meesri C, Wall TF, Fuel, 83, 745, 2004
  18. Suelves I, Moliner R, Lazaro MJ, J. Anal. Appl. Pyrolysis, 55, 29, 2000
  19. Shin YJ, Shen YH, Chemosphere, 68, 389, 2007
  20. Guo Z, Feng R, Zheng Y, Fu X, Ultrason. Sonochem., 14, 583, 2007
  21. Aktas Z, Woodburn ET, Fuel Process. Technol., 62(1), 1, 2000
  22. Zhou MS, Qiu XQ, Yang DJ, Lou HM, Ouyang XP, Fuel Process. Technol., 88(4), 375, 2007
  23. Qiu X, Zhou M, Yang D, Lou H, Ouyang X, Pang Y, Fuel, 86, 1439, 2007
  24. Vitolo S, Belli R, Mazzanti M, Quanttroni G, Fuel, 75, 259, 1996
  25. Yoon SJ, Choi YC, Lee SH, Lee JG, Korean J. Chem. Eng., 24(3), 512, 2007