| Issue |
Korean Journal of Chemical Engineering,
Vol.26, No.5, 1235-1240, 2009
Vol.26, No.5, 1235-1240, 2009
Direct incorporation of vanadium into three-dimensional KIT-6: 1. Optimization of synthesis conditions
Three dimensional (3-D) cubic KIT-6 with directly incorporated vanadium was hydrothermally synthesized by using Pluronic P123 and n-butanol as the structure-directing mixture, tetraethyl orthosilicate (TEOS) as the silica source and NH4VO3 as the vanadium source. The molar composition was varied in the range of 0.017 P123/0.08-2.4 V/1.0-2.0 TEOS/1.31-1.70 BuOH/1.83-3.00 HCl/195 H2O. The orderness of mesopore structure was estimated by X-ray diffraction, N2 adsorption, and TEM analysis. The effects of the amount of HCl, TEOS and BuOH on the structure of KIT-6 were discussed. The time and temperature for the synthesis of KIT-6 were also optimized. The amount of vanadium content influenced the framework structure and crystallinity of the Ia3d phase significantly.
[References]
- Zhang W, Wang J, Tanev PT, Pinnavaia T, J. Chem. Soc., Chem. Commun., 979, 1996
- Reddy KM, Moudrakaski I, Sayari AJ, J. Chem. Soc., Chem. Commun., 1059, 1994
- Gontier S, Tuel A, Microporous Mater., 5, 161, 1995
- Luan Z, Maes EM, Van der Heide PAW, Zhao D, Czernuszewicz RS, Kevan L, Chem. Mater., 11, 3680, 1999
- Luan Z, Bae JY, Kevan L, Chem. Mater., 12, 3202, 2000
- Gao F, Zhang Y, Wan H, Kong Y, Wu X, Dong L, Li B, Chen Y, Micro. Meso. Mater., 2007, doi:10.1016/j.micromeso.2007.06.041.
- Murugavel R, Roesky HW, Angew. Chem., Int. Ed., 109, 44491, 1997
- Fan J, Yu CZ, Wang LM, Tu B, Zhao DY, Sakamoto Y, Terasaki O, J. Am. Chem. Soc., 123(48), 12113, 2001
- Sakamoto Y, Kaneda M, Terasaki O, Zhao DY, Kim JM, Stucky GD, Shin HY, Ryoo R, Nature, 408, 449, 2000
- Morey MS, Davidson A, Stucky GD, J. Porous Mater., 5, 195, 1998
- Kim TW, Kleitz F, Paul B, Ryoo R, J. Am. Chem. Soc., 127(20), 7601, 2005
- Chen YW, Lu YH, Ind. Eng. Chem. Res., 38(5), 1893, 1999
- Lim S, Haller GL, J. Phys. Chem. B, 106(33), 8437, 2002
- Du GA, Lim SY, Yang YH, Wang C, Pfefferle L, Haller GL, Appl. Catal. A: Gen., 302(1), 48, 2006
- Dapurkar SE, Sakthivel A, Selvam P, J. Mol. Catal. A-Chem., 223(1-2), 241, 2004
- Selvam P, Dapurkar SE, Appl. Catal. A: Gen., 276(1-2), 257, 2004
- Galarneau A, Driole MF, Petitto C, Chiche B, Bonelli B, Armandi M, Onida B, Garrone E, Renzo F, Fajula F, Micro. Meso. Mater., 83, 172, 2005
- Zhang WH, Lu J, Han B, Li M, Xiu J, Ying P, Li C, Chem. Mater., 14, 3413, 2002
- Van der Voort P, Mathieu M, Mees F, Vansant EF, J. Phys. Chem. B, 102(44), 8847, 1998
- Vinu A, Anandan S, Anand C, Srinivasu P, Ariga K, Mori T, Micro. Meso. Mater. 2007, doi:10.1016/j.micromeso.2007.05.037.
- Shylesh S, Singh AP, J. Catal., 233(2), 359, 2005
- Mathieu M, Van Der Voort P, Weckhuysen BM, Rao RR, Catana G, Schoonheydt RA, Vansant EF, J. Phys. Chem. B, 105(17), 3393, 2001
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