About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.26, No.3, 654-659, 2009
Oxidation of cyclopentene catalyzed by tungsten-substituted molybdophosphoric acids
Xue J, Yin H, Li H, Zhang D, Jiang T, Yu L, Shen Y
A series of Keggin type tungsten-substituted molybdophosphoric acids (H3PMo12-nWnO40·XH2O) were synthesized and characterized by ICP-AES, FT-IR, TG-DSC, and XRD. The tungsten substitution extent significantly affected their catalytic activity in the oxidation of cyclopentene and the selectivity of the resultant products. The tungsten-substituted molybdophosphoric acids with tungsten substitution numbers in a range of 3-6.8 exhibited high catalytic activity in the oxidation of cyclopentene. After reaction for 8 h, the conversion of cyclopentene was up to 97%; the oxidation products mainly consisted of glutaraldehyde, cis-1,2-cyclopentanediol and trans-1,2-cyclopentanediol with the yields of ca. 23%, 27%, and 45%, respectively.
Keywords: Tungsten-substituted Molybdophosphoric Acid; Cyclopentene; Glutaraldehyde; cis-1,2-Cyclopentanediol; trans-1,2-Cyclopentanediol
[References]
  1. Yang XL, Dai WL, Chen H, Cao Y, Li HX, He HY, Fan KN, J. Catal., 229(1), 259, 2005
  2. Chen H, Dai WL, Yang XL, Gao RH, Cao Y, Li HX, Fan KN, Appl. Catal. A: Gen., 309(1), 62, 2006
  3. Deng J, Xu X, Chen H, Jiang A, Tetrahedron, 48, 3503, 1992
  4. Lu Y, Yin H, Wu H, Wu H, Jiang T, Wada Y, Catal. Commun., 7, 832, 2006
  5. Chen H, Dai WL, Deng JF, Fan KN, Catal. Lett., 81(1-2), 131, 2002
  6. Xia X, Jin RH, He YG, Deng JF, Li HX, Appl. Surf. Sci., 165(4), 255, 2000
  7. Jin RH, Li HX, Deng JF, J. Catal., 203(1), 75, 2001
  8. Jin RH, Xia X, Dai WL, Deng JF, Li HX, Catal. Lett., 62(2-4), 201, 1999
  9. Timofeeva MN, Appl. Catal. A: Gen., 256(1-2), 19, 2003
  10. Kozhevnikov IV, Chem. Rev., 98(1), 171, 1998
  11. Deusser LM, Petzoldt JC, Gaube JW, Hibst H, Ind. Eng. Chem. Res., 37(8), 3230, 1998
  12. La KW, Kim H, Jung JC, Lee J, Park DR, Lee SH, Song IK, Korean J. Chem. Eng., 25(4), 710, 2008
  13. Guo X, Huang C, Chen B, Korean J. Chem. Eng., 25(4), 675, 2008
  14. Lim SS, Park GI, Choi JS, Song IK, Lee WY, Catal. Today, 74(3-4), 299, 2002
  15. Inumaru K, Ono A, Kubo H, Misono M, J. Chem. Soc., Faraday Trans., 94, 1765, 1998
  16. Khenkin AM, Weiner L, Neumann R, J. Am. Chem. Soc., 127(28), 9988, 2005
  17. Zhang J, Tang Y, Li GY, Hu C, Appl. Catal. A: Gen., 278(2), 251, 2005
  18. Cai XE, Du DC, Ni JP, Jin YM, Zhu J, Qian YX, Thermochim. Acta, 292(1-2), 45, 1997
  19. Yu Z, Li S, Han F, Wang S, Zhou G, Zhang S, Kexue Tongbao (Chinese), 31, 1478, 1986
  20. Misono M, Mizuno N, Katamura K, Kasai A, Konishi Y, Sakata K, Okuhara T, Yoneda Y, Bull. Chem. Soc. Jpn., 55, 400, 1982
  21. Rao PM, Wolfson A, Kababya S, Vega S, Landau MV, J. Catal., 232(1), 210, 2005
  22. Yang L, Qi YT, Yuan XD, Shen H, Kim J, J. Mol. Catal. A-Chem., 229(1-2), 199, 2005
  23. Dimitratos N, Della Pina C, Falletta E, Bianchi CL, Dal Santo V, Rossi M, Catal. Today, 122(3-4), 307, 2007
  24. Zhong L, Zhang Y, Tang Y, Bai Y, Polyhedron, 22, 2647, 2003
  25. Alekar NA, Halligudi SB, Rajani R, Gopinathan S, Gopinathan C, React. Kinet. Catal. Lett., 72(1), 169, 2001
[Cited By]
  1. Xue J, Wang A, Yin H, Wang J, Zhang D, Chen W, Yu L, Jiang T, Journal of Industrial and Engineering Chemistry, 16(2), 288, 2010
  2. Baek J, Yun HJ, Kim ND, Choi Y, Yi J, Clean Technology, 16(3), 220, 2010
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.