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Issue
Korean Journal of Chemical Engineering,
Vol.26, No.1, 235-239, 2009
Modified Guggenheim-Huggins-Miller combinatorial factor and its application to lattice fluid equation of state
Lee JH, Shin MS, Kim HY
The Guggenheim-Huggins-Miller (GHM) combinatorial factor is modified by introducing a factor in the pair probability of a hole-hole pair. The proposed contribution is combined with the expanded quasi-chemical contribution and tested against saturated vapor pressure and liquid density. The proposed model correlates experimental saturated liquid density better than a quasi-chemical nonrandom lattice fluid (QLF) model based on original GHM combinatorial factor. The optimized parameters show a quite different behavior compared with that of the QLF model and the relationships between the parameters of two models are discussed.
Keywords: Combinatorial Factor; Equation of State; Guggenheim-Huggins-Miller; Lattice Fluid; Pair Probability
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