| Issue |
Korean Journal of Chemical Engineering,
Vol.26, No.1, 57-63, 2009
Vol.26, No.1, 57-63, 2009
Catalytic synthesis of thiophene from the reaction of n-butanol and carbon disulfide over K2CO3-promoted Cr2O3/γ-alumina catalyst
The synthesis of thiophene from the reaction of n-Butanol and carbon disulfide was performed in a fixedbed reactor in the presence of promoted chromia on γ-alumina. A high selectivity to thiophene (87%) and a long lifetime of the catalyst (55 hour) was obtained at 450 ℃ with a 1 : 6 n-Butanol to carbon disulfide molar ratio and LHSV 1 h^(-1) over γ-Al2O3 promoted by 7% K2CO3 with 15% Cr2O3 loaded. The catalytic behavior of these catalysts can be attributed to their dual-functional acidity and dehydrogenating and cyclized properties.
[References]
- Southward BWL, Fuller LS, Huctchings GJ, Joyner RW, Stewart RA, Chem. Commun., 5, 2541, 1998
- Rivers TJ, Hudson TW, Schmidt CE, Adv. Funct. Mater., 12(1), 33, 2002
- Perepichka IF, Perepichka DF, Meng H, Wudl F, Adv. Mater., 17(19), 2281, 2005
- Barbarella G, Melucci M, Sotgiu G, Adv. Mater., 17(13), 1581, 2005
- Barbarella G, Favaretto L, Zanelli A, Gigli G, Mazzeo M, Anni M, Bongini A, Adv. Funct. Mater., 15(4), 664, 2005
- Kim KL, Choi KS, Korean J. Chem. Eng., 15, 177, 1998
- Min W, Korean J. Chem. Eng., 19(4), 601, 2002
- Lee KW, Choi MJ, Kim SB, Korean J. Chem. Eng., 18, 143, 1991
- Barrault J, Guisnet M, Lucien J, Maurel R, US Patent, 4 143 052 (1979)
- Clark NR, Webster WE, British Patent, 1 345 203 (1971)
- Southward BWL, Fuller LS, Huctchings GJ, et al., Chem. Commun., 4, 369, 1999
- Clark NR, Webster WE, US Patent 3 822 289 (1974)
- Hutchings GJ, Joyner RW, Southward BWL, US Patent 5 726 326 (1998)
- Southward BWL, Fuller LS, Hutchings GJ, Joyner RW, Stewart RA, Catal. Lett., 55(3-4), 207, 1998
- Tomov A, Fajula F, Moreau C, Appl. Catal. A: Gen., 192(1), 71, 2000
- Appleby WG, Houston, Sartor AF, US Patent 2 558 508 (1951)
- Voronkov MG, Trofimov BA, Krjuchkov VV, US Patent 4 251 666 (1981)
- Henry M, Arnold M, US Patent 2 336 916 (1943)
- Kemp LC, Scarsdale, US Patent 2 694 074 (1954)
- Ruidishch LE, Fishkil, Eastman DB, US Patent 2 694 075 (1954)
- Sager WF, US Patent 2 570 722 (1947)
- Bell TR, US Patent 3 939 179 (1976)
- Appleby WG, Sartor AF, US Patent 2 558 507 (1951)
- Forquy C, Lacroix M, Breysse M, US Patent 5 166 362 (1992)
- Hansford RC, Rasmussen HE, US Patent 2 450 658 (1948)
- Love B, Massengale JT, US Patent 2 899 444 (1959)
- Buchholz B, Deger TE, US Patent 3 197 483 (1965)
- Li QF, Xu YQ, Liu XQ, Kim JC, Catal. Lett., 122, 354, 2008
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.