Korean Journal of Chemical Engineering, Vol.26, No.1, 48-56, 2009
Kinetic study and hydrogen peroxide consumption of phenolic compounds oxidation by Fenton’s reagent
Synthetic solutions of phenol, o-, m- and p-cresol were oxidised by using Fenton’s reagent. The application of substoichiometric dosage of H2O2 led to the formation of intermediate compounds, continuing later the oxidation to complete oxidation. An important objective was to analyze the effect of hydrogen peroxide dosage applied and the reaction pH together with the iron oxidation state on the degradation level. A kinetic model was derived from a reaction mechanism postulated which was used to analyze the results of the experiments. Another aim was to analyze the hydrogen peroxide consumption. Noteworthy results include an increase in oxidant consumption to intensify phenol removal. Furthermore, oxidant consumption was analyzed through the ratio H2O2 to phenol removed and the average specific rate of removal (ASRR). By analyzing these two parameters it has been possible to ascertain the most favorable strategy for an efficient application of H2O2.
[References]
Ko CH, Fan C, Chiang PN, Wang MK, Lin KC, J. Hazard. Mater. , 149 (2), 275, 2007
Sklyar V, Epov A, Gladchenko M, Danilovich D, Kalyuzhnyi S, Appl. Biochem. Biotechnol. , 109 (1-3), 253, 2003
Esplugas S, Gimenez J, Contreras S, Pascual E, Rodriguez M, Water Res. , 36 , 1034, 2002
Kim YO, Nam HU, Park YR, Lee JH, Park TJ, Lee TH, Korean J. Chem. Eng. , 21 (4), 801, 2004
Rao L, Kanmani S, Indian J. of Environ. Prot. , 26 , 619, 2006
Sedlak DL, Andren AW, Environ. Sci. Technol. , 25 , 777, 1991
Pignatello JJ, Environ. Sci. Technol. , 26 , 944, 1992
Bishop DF, Stern G, Fleischman M, Marshall LS, Ind. Eng. Chem. Process Design Dev. , 7 , 110, 1968
Buxton GV, Greenstock CL, Helman WP, Ross AB, J. Phys. Chem. Ref. Data , 17 , 513, 1988
Carvalho RH, Lemos F, Lemos MANDA, Vojinovic V, Fonseca LP, Cabral JMS, Bioprocess Biosyst. Eng. , 29 , 99, 2006
Kang N, Lee D, Yoon J, Chemosphere , 47 , 915, 2002
Lunak S, Sedlak P, J. of Photoch. Photobio. A , 68 , 1, 1992
Zazo JA, Casas JA, Molina CB, Quintanilla A, Rodriguez JJ, Environ. Sci. Technol. , 41 , 7164, 2007
Hong SH, Kwon BH, Lee JK, Kim IK, Korean J. Chem. Eng. , 25 (1), 46, 2008
Kolthoff IM, Medalia AI, J. Am. Chem. Soc. , 71 , 3777, 1949
Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ. , 47 (4), 219, 2004
Yavuz Y, Koparal AS, Ogutveren UB, Chem. Eng. Technol. , 30 (5), 583, 2007
Sanz J, Lombrana JI, De Luis A, Ortueta M, Varona F, Environ. Chem. Lett. , 1 , 45, 2003
Eisenberg GM, Ind. Eng. Chem. , 15 , 327, 1942
Guittonneau S, de Laat J, Dore M, Duguet JP, Bonnel C, Environ. Technol. Lett. , 9 , 1115, 1988
Masschelein WJ, Denis M, Lendent R, Water and Sewage Works , 8 , 69, 1977
Striolo P, Debelle H, Foussard JN, Tribune de l’eau. , 556 , 1992
Anbar M, Meyerstein D, Neta P, J. Phys. Chem. A , 70 , 2660, 1966
Litvintsev IY, Mikhailyuk AI, Sapunov VN, Kinet. Catal. , 36 , 482, 1995
Benitez FJ, Beltranheredia J, Gonzalez T, Real F, Ind. Eng. Chem. Res. , 34 (11), 4099, 1995
de Luis A, Lombrana JI, Menendez A, J. Adv. Oxid. Technol. , 11 , 21, 2008
Montaser YG, Hartel G, Mayer R, Haseneder R, Waste Manage. , 21 , 41, 2001
Kavitha V, Palanivelu K, Chemosphere , 55 , 1235, 2004
Martinez F, Calleja G, Melero JA, Molina R, Appl. Catal. B: Environ. , 70 (1-4), 452, 2007
Kavitha V, Palanivelu K, Water Res. , 39 , 3062, 2005
de Asin K, Dutta BK, Bhattacharjee S, Environ. Prog. , 25 , 64, 2006
Nicell JA, Wright H, Enzyme Microb. Technol. , 21 (4), 302, 1997
Glaze WH, Lay Y, Kang JW, Ind. Eng. Chem. Res. , 34 (7), 2314, 1995
Karpel N, Dore M, Wat. Res. , 31 , 1383, 1997
Lombrana JI, Varona F, Martinez C, de Luis A, Recent Res. Devel. In Chemical Engg. , 1 , 41, 1997
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