Issue
Korean Journal of Chemical Engineering,
Vol.26, No.1, 1-6, 2009
Multiresponse optimization based on the desirability function for a pervaporation process for producing anhydrous ethanol
A pervaporation process for producing anhydrous ethanol from industrial ethyl alcohol (95% v/v) was performed with a commercial PVA/PAN membrane. A central composite rotatable experimental design together with response surface methodology was implemented for studying and modeling the influence of operating conditions in terms of the temperature and the flow rate of the feed on the pervaporation performance, namely, the permeate flux and the separation factor. To obtain a trade-off between the permeate flux and the separation factor, a method for simultaneous optimization of multiple responses based on an overall desirability function was used. The optimization resulted in a feed temperature of 66 oC and a feed flow rate of 42 L/h. These operating conditions are expected to respond with a permeate flux of 0.107 kg/m2 h and a separation factor of 40, which correspond to a satisfactory overall desirability.
[References]
  1. Praptowidodo VS, J. Molec. Struct., 739, 207, 2005
  2. Perry RH, Green DW, Maloney JO, Perry’s chemical engineers’ handbook, 7th ed., McGraw-Hill, USA (1999)
  3. Van Hoof V, Van den Abeele L, Buekenhoudt A, Dotremont C, Leysen R, Sep. Purif. Technol., 37(1), 33, 2004
  4. Lipnizki F, Field RW, Environ. Prog., 21, 265, 2002
  5. Jiraratananon R, Chanachai A, Huang RYM, Uttapap D, J. Membr. Sci., 195(2), 143, 2002
  6. Huang RYM (Ed.), Pervaporation membrane separation processes, Elsevier, Amsterdam (1991)
  7. Huang Z, Shi Y, Wen R, Guo YH, Su JF, Matsuura T, Sep. Purif. Technol., 51(2), 126, 2006
  8. Aminabhavi TM, Khinnavar RS, Harogoppad SR, Aithal US, Nguyen QT, Hansen KC, J. Macromol. Chem. Phys., 34, 139, 1994
  9. Ruckenstein E, Liang L, J. Membr. Sci., 110(1), 99, 1996
  10. Volkov VV, Russ. Chem. Bull., 43, 187, 1994
  11. Hsu CS, Liou RM, Chen SH, Hung MY, Tsia HA, Lai JY, J. Appl. Polym. Sci., 87(13), 2158, 2003
  12. Wijmans JG, Baker RW, J. Membr. Sci., 107(1-2), 1, 1995
  13. Schaetzel P, Vauclair C, Nguyen QT, Bouzerar R, J. Membr. Sci., 244(1-2), 117, 2004
  14. Yu J, Lee CH, Hong WH, Chem. Eng. Process., 41(8), 693, 2002
  15. Lazic ZR, Design of experiments in chemical engineering - A practical guide, WILEY-VCH, Federal Republic of Germany (2004)
  16. Fuller D, Scherer W, The desirability function: Underlying assumptions and application implications, University of Virginia Charlottesville, VA 22903 (1998)
  17. JMP Introductory Guide, Release 7, Copyright ⓒ 2007, SAS Institute Inc., Cary, NC, USA
  18. Chen SH, Liou RM, Hsu CS, Chang DJ, Yu KC, Chang CY, J. Membr. Sci., 193(1), 59, 2001
  19. Lee YM, Nam SY, Woo DJ, J. Membr. Sci., 133(1), 103, 1997