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Issue
Korean Journal of Chemical Engineering,
Vol.25, No.3, 437-442, 2008
High efficiency ester condensation using hydrophobic zeolite membranes
Inoue T, Nemoto Y, Nagase T, Hasegawa Y, Kiyozumi Y, Sato K, Nishioka M, Hamakawa S, Nishide T, Mizukami F
We successfully developed zeolite membranes with hydrophilic character, by choosing appropriate zeolites in terms of hydrophilicity and high acid tolerance. We evaluated thus developed membranes by their pervaporation (PV) performance, dehydration from acidic organic solvent. The zeolite membranes we developed, based on merlinoite (MER), chabazite (CHA) or phillipsite (PHI), are shown to exhibit stable dehydration performance, respectively. We successfully applied the membranes to the selective removal of water in an ester condensation reaction starting from a stoichiometric mixture of a carboxylic acid and an alcohol. The availability of pervaporation-assisted ester condensation reaction was validated by various kinds of combinations of carboxylic acid and alcohols, which implies the general availability of pervaporation-assisted process intensification by zeolite membranes.
Keywords: Zeolite Membranes; Pervaporation; Dehydration; Ester Condensation
[References]
  1. Baker RW, Membrane technology and applications second edition, John Wiley and Sons Ltd, West Sussex, 2004
  2. Bowen TC, Noble RD, Falconer JL, J. Membr. Sci., 245(1-2), 1, 2004
  3. Kondo M, Komori M, Kita H, Okamoto K, J. Membr. Sci., 133(1), 133, 1997
  4. Kalipcilar H, Bowen TC, Noble RD, Falconer JL, Chem. Mater., 14, 3458, 2002
  5. Masuda T, Otani S, Tsuji T, Kitamura M, Mukai SR, Sep. Purif. Technol., 32(1-3), 181, 2003
  6. Tanaka K, Yoshikawa R, Ying C, Kita H, Okamoto K, Chem. Eng. Sci., 57(9), 1577, 2002
  7. Shiina I, Tetrahedron, 60, 1587, 2004
  8. Wakasugi K, Nakamura A, Iida A, Nishii Y, Nakatani N, Fukushima S, Tanabe Y, Tetrahedron, 59, 5337, 2003
  9. Otera J, Accounts Chem. Res., 37, 288, 2004
  10. Yoshida A, Hao X, Nishikido J, Green Chem., 5, 554, 2003
  11. Ishihara K, Nakagawa S, Sakakura A, J. Am. Chem. Soc., 127(12), 4168, 2005
  12. Ishihara K, Nakayama M, Ohara S, Yamamoto H, Tetrahedron, 58, 8179, 2002
  13. Sato A, Nakamura Y, Maki T, Ishihara K, Yamamoto H, Adv. Synth. Catal., 347, 1337, 2005
  14. Asthana N, Kolah A, Vu DT, Lira CT, Miller DJ, Org. Proc. Res. Dev., 9, 599, 2005
  15. Kita H, Tanaka K, Okamoto KI, Yamamoto M, Chem. Lett., 2053, 1987
  16. Okamoto KI, Yamamoto M, Otoshi Y, Semoto T, Yano M, Tanaka K, Kita H, J. Chem. Eng. Jpn., 26, 475, 1993
  17. Okamoto K, Yamamoto M, Noda S, Semoto T, Otoshi Y, Tanaka K, Kita H, Ind. Eng. Chem. Res., 33(4), 849, 1994
  18. Lipnizki F, Field RW, Ten PK, J. Membr. Sci., 153(2), 183, 1999
  19. Tanaka K, Yoshikawa R, Ying C, Kita H, Okamoto K, Catal. Today, 67(1-3), 121, 2001
  20. Lim SY, Park B, Hung F, Sahimi M, Tsotsis TT, Chem. Eng. Sci., 57(22-23), 4933, 2002
  21. Benedict DJ, Parulekar SJ, Tsai SP, Ind. Eng. Chem. Res., 42(11), 2282, 2003
  22. http://www.iza-structure.org/database
  23. Nagase T, Kiyozumi Y, Hasegawa Y, Mizukami F, Clay Sci., 12, 100, 2005
  24. Inoue T, Hasegawa Y, Nagase T, Kiyozumi Y, Hamakawa S, Mizukami F, in Combinatorial methods and informatics in materials science (Materials Research Society Symposium Proceedings Volume 894), M. J. Fasolka, Q. Wang, R. A. Potyrailo, T. Chikyow, U. S. Schubert and A. Korkin Eds., Materials Research Society, Boston, p. 211, 2005
  25. Inoue T, Nagase T, Hasegawa Y, Kiyozumi Y, Sato K, Kobayashi K, Nishioka M, Hamakawa S, Mizukami F, Chem. Lett., 35(1), 76, 2006
  26. Inoue T, Nagase T, Hasegawa Y, Kiyozumi Y, Sato K, Nishioka M, Hamakawa S, Mizukami F, Ind. Eng. Chem. Res., 46(11), 3743, 2007
  27. Nagase T, Kiyozumi Y, Hasegawa Y, Inoue T, Ikeda T, Mizukami F, Chem. Lett., 36(5), 594, 2007
  28. Cui Y, Kita H, Okamoto KI, J. Membr. Sci., 236(1), 17, 2004
  29. Li G, Kikuchi E, Matsukata M, J. Membr. Sci., 218(1-2), 185, 2003
  30. Li G, Kikuchi E, Matsukata M, Sep. Purif. Technol., 32(1-3), 199, 2003
  31. Okamoto K, Kita H, Horii K, Tanaka K, Kondo M, Ind. Eng. Chem. Res., 40(1), 163, 2001
  32. Zhang YF, Xu ZQ, Chen QL, J. Membr. Sci., 210(2), 361, 2002
  33. Hasegawa Y, Ikeda T, Nagase T, Kiyozumi Y, Hanaoka T, Mizukami F, J. Membr. Sci., 280(1-2), 397, 2006
  34. Hasegawa Y, Nagase T, Kiyozumi Y, Mizukami F, J. Membr. Sci., 294(1-2), 186, 2007
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