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Issue
Korean Journal of Chemical Engineering,
Vol.25, No.3, 419-422, 2008
Adiabatic runaway studies for methyl ethyl ketone peroxide with inorganic acids by vent sizing package 2
Chen JR, Tseng JM, Lin YF, Wang SYS, Shu CM
Methyl ethyl ketone peroxide (MEKPO) is an unstable material that is classified as an explosive substance. We evaluated MEKPO 10 mass% under mixing with three inorganic acids (6 N HNO3, 6 N H3PO4, and 6 N H2SO4) by adiabatic system of vent sizing package 2 (VSP2). Results from evaluation and testing indicated that these three inorganic acids could increase the degree of hazard while combined with pure MEKPO. Therefore, information on the hazards and phenomena of runaway reaction should be provided in order to lessen the degree of hazard.
Keywords: Methyl Ethyl Ketone Peroxide; Inorganic Acids; Vent Sizing Package 2 (VSP2); Runaway Reaction; Degree of Hazard
[References]
  1. Duh YS, Kao CS, Hwang HH, Lee WL, Trans. Inst. Chem. Eng., 76B, 271, 1998
  2. Chuang GS, Chao AC, Li HY, Korean J. Chem. Eng., 21(5), 963, 2004
  3. Kim KS, Ko JW, Korean J. Chem. Eng., 22(1), 26, 2005
  4. Nam YW, Park KS, Korean J. Chem. Eng., 21(2), 370, 2004
  5. Arpornwichanop A, Kittisupakorn P, Hussain MA, Korean J. Chem. Eng., 19(2), 221, 2002
  6. Chung TJ, Kim MC, Choi CK, Korean J. Chem. Eng., 21(1), 41, 2004
  7. Kim EH, Kwon SW, Lee EH, Yoo JH, Korean J. Chem. Eng., 19(2), 305, 2002
  8. Leila BD, Fierz HJ, Hazard. Mater., 93, 137, 2002
  9. Parulekar SJ, Chem. Eng. Sci., 53(13), 2379, 1998
  10. El-Sayed SA, J. Loss Prev. Process Ind., 16, 249, 2003
  11. Kumar J, Nath S, Chem. Eng. Sci., 52(20), 3455, 1997
  12. Kotoyori T, J. Hazard. Mater., A64, 1, 1999
  13. Chervin S, Bodman GT, Thermochim. Acta, 392-393, 371, 2002
  14. Wang YW, Shu CM, Duh YS, Kao CS, Ind. Eng. Chem. Res., 40(4), 1125, 2001
  15. Kossoy AA, Hofelich T, Pro. Saf. Prog., 22, 235, 2003
  16. Kossoy AA, Akhmetshin Y, Pro. Saf. Prog., DOI: 10.1002/prs.10189, 2007
  17. Milas NA, Golubovic A, J. Am. Chem. Soc., 82, 5824, 1959
  18. OSHA, Methyl Ethyl Ketone Peroxide Organic Method # 77, Occupational Safety and Health Administration, USA, 1989
  19. Ingold KU, Chem. Rev., 61, 563, 1961
  20. Farkaas, Passaqlied, J. Am. Chem. Soc., 72, 3333, 1950
  21. Knorred G, Maizusz K, Emanueln M, Doklady Akad. Nauk S.S.S.R., 123, 123, 1958
  22. Tiwari G, Bose P, Ind. Eng. Chem. Res., 45(1), 109, 2006
  23. Kwon BG, Lee JH, Anal. Chem., 76, 6359, 2004
  24. Black ED, Hayon E, J. Phys. Chem., 74, 3199, 1970
  25. Maruthamuthu P, Neta P, J. Phys. Chem., 82, 710, 1978
  26. Jiang PY, Katsumura Y, Domae M, Ishikawa K, Nagaishi R, Ishigure K, Yoshida Y, J. Chem. Soc.-Faraday Trans., 88, 3319, 1992
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