The present study aims at the removal of copper from industrial wastewater by using a low - cost adsorbent. Activated periwinkle shell carbon (PSC) was prepared and characterized for various physiochemical properties. To determine copper removal capacity, the performance of PSC was compared with commercial activated carbon (CAC) and a mixture of activated periwinkle shell carbon and commercial activated carbon (PSC : CAC) in a ratio 1 : 1. The effect of adsorbent dose, contact time, pH, agitation speed and adsorbent particle size was studied for adsorption of copper from wastewater under batch conditions. The result obtained showed that PSC competes favourably with CAC. The maximum adsorption capacity was observed for PSC : CAC with 88.12% removal at an optimal pH of 8. The PSC and CAC had 84.19% removal and 85.15% removal, respectively. The equilibrium data obtained fitted both the Langmuir and the Freundlich models. Good correlation coefficients were obtained for the pseudo-second-order kinetic model.
American Public Health Association, Standard methods for examination of wastewater, 17th Ed., New York, 1985
Goltermann HL, Method for physical and chemical analysis of fresh water, Well scientific publications, 2nd Ed., Blackwell Scientific Publications, 1978
Ho YS, John Wase DA, Forster CF, Water Res., 29, 5, 1995
Low KS, Lee CK, Lee KP, Bioresour. Technol., 44, 109, 1993
Baes GB, Mesmer RE, Hydrolysis of Ca ions, John Wiley and Sons, New York, 1976
Gau JX, Chen YA, Huang SD, Proc. Nat. Sci. Rep. China, 9(3), 228, 1985
Knocke WR, Hemphill LM, Water Res., 15, 245, 1981
Domenico PA, Schwartz FW, Physical and chemical hydrogeology, 1st Ed., John Wiley and Sons, New York, 1990
Reddi LN, Inyang HI, Geo-environmental engineering principles and applications, Marcel Dekker Inc., New York, 2000
Nitzsche O, Vereecken H, Mine Water and the Environment, 21, 15, 2002