Issue
Korean Journal of Chemical Engineering,
Vol.24, No.1, 83-92, 2007
Combustion characteristics of vacuum residue in a test furnace and its utilization for utility boiler
Recently, increased attention has been exerted on the utilization of cheaper hydrocarbons fuel such as Vacuum Residue (VR). As a fundamental investigation for VR utilization, VR combustion tests were carried out in a test furnace with a fuel feed rate of 20 kg/h. As compared with heavy oil, VR used in this work is much more viscous and contains high percentages of sulfur, carbon residue and heavy metals. Successful fuel transportation and atomization has been achieved with the indirect heating of fuel by a thermia oil. The measured distributions of temperature, major species concentrations and solid samples along with the furnace revealed that the main reaction zone remains within about 1 m from the burner tip and the characteristics of VR flame are dependent on the ratio of fuel/air feeding rate. VR carbonaceous particles collected along with the furnace showed that their complete conversion would be a very essential factor for the utilization of VR as a fuel. Several issues for applying it to utility boilers have been investigated in line with the present results, and some suggestions have been made.
[References]
  1. Aoki H, Fukushima H, Yoshida T, The Thermal and Nuclear Power, 55, 1356, 2004
  2. Basu P, Kefa C, Jestin L, Boilers and burners, Springer, New York, 2000
  3. Chigier N, Combustion measurements, Hemisphere Publishing Corporation, New York, 1991
  4. Choi YC, Lee JG, Yoon SJ, Park MH, Korean J. Chem. Eng., 23, 2006
  5. Clayton RM, Back LH, Journal of Engineering for Gas Turbines and Power, 111, 679, 1989
  6. Cullis CF, Mulcahy MFR, Combustion and Flame, 18, 225, 1972
  7. Fujimura K, Mastumoto H, Arakawa Y, Fujii H, Mizoguchi T, Mitsubishi Juco Giho, See also http://www. mhi.co.jp/tech/htm/ 9362/e936211a.htm, 36, 1999
  8. Gollahalli SR, Nasrullah MK, Bhashi JH, Combustion and Flame, 55, 93, 1984
  9. Gray MR, Upgrading petroleum residues and heavy oils, Marcel Dekker, Inc., New York, 1994
  10. Glassman I, Combustion, 2nd Ed., Academic Press, Orlando, 1987
  11. Hashimoto A, Ichinose T, Fujimura K, Kaneko S, Hishida M, Arakawa Y, Mitsubishi Juco Giho, See also http://www. mhi.co.jp/tech/htm/8351/e835108a.htm, 35, 1998
  12. Ichinose T, Fujimura K, Takeno K, Motai T, Arakawa Y, Fujii H, JSME International Journal, 41, 1055, 1998
  13. Lefebre H, Atomization and sprays, Hemisphere Publishing Corporation, New York, 1989
  14. Linak WP, Miller CA, Santoianni DA, King CJ, Shinagawa T, Wendt JOL, Yoo JI, Seo YC, Korean J. Chem. Eng., 20(4), 664, 2003
  15. Ma J, Fletcher TH, Webb BW, “Conversion of coal tar to soot during coal pyrolysis in a post-flame environment,” Twenty-Sixthh Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 3161, 1996
  16. Marrone NJ, Kennedy IM, Dryer FL, Combust. Sci. Technol., 36, 149, 1984
  17. Miller JA, Bowman CT, Prog. Energy Combust. Sci., 15, 287, 1989
  18. Nenniger RD, Howard JB, Sarofim AF, “Sooting potential of coals,” International Conference on Coal Science, Pittsburgh, 521, 1983
  19. Moleo LJ, Pollutant formation and interaction in the combustion of heavy liquid fuels, PhD thesis, University college London, 1998
  20. Northrop PS, Gavalas GR, Energy Fuels, 5, 587, 1991
  21. Moszkowicz P, Witzel L, Claus G, Chem. Eng. Sci., 51(17), 4075, 1996
  22. Park HY, Kim TH, Energy Conv. Manag., 47(15-16), 2118, 2006
  23. Park HY, Seo SI, International Journal of Energy Research, 30, 365, 2006
  24. Pfefferle LD, Churchill SW, Combustion Science and Technology, 48, 235, 1986
  25. Richter H, Howard JB, Prog. Energy Combust. Sci., 26, 565, 2000
  26. Seeker WR, Samuelsen GS, Heap MP, Trolinger JD, “Thermal decomposition of pulverised coal particles,” Eighteenth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1213, 1980
  27. Serio MA, Hamblen DG, Markham JR, Solomon PP, Energy Fuels, 1, 138, 1987
  28. Simbeck D, Johnson H, “World gasification survey: Industry trends & developments,” Gasification Technologies 2001 Conference, San Francisco, CA, 2001
  29. Singer JG, Combustion fossil power, Combustion Engineering, Inc. Rand McNally, 1991
  30. Sonoda T, Komori T, Kato M, Kitauchi Y, Iwasaki Y, Akizuki W, Hashi T, Kunihiro K, “Development of M701F gas turbine for integrated gasification combined cycle plants,” Technical Review, 41, Mitsubishi Heavy Industries. Ltd., 2004
  31. Timothy LD, Froelich D, Sarofim AF, Beer JM, “Soot formation and burnout during the combustion of dispersed pulverised coal particles,” Twenty-First Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1141, 1986
  32. Urban DL, Huey SPC, Dryer FL, “Evaluation of the coke formation potential of residual fuel oils,” Twenty-Fourth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1357, 1992
  33. Villasenor R, Escalera R, International Journal of Heat and Mass Transfer, 41, 3087, 1998
  34. Villasenor R, Garcia F, Fuel, 78(8), 933, 1999
  35. Wolff J, Radtke K, Karg J, Gunster W, “Refinery residue based IGCC power plants and market potential,” Gasification Technologies 2001 Conference, San Francisco, CA, 2001