Korean Journal of Chemical Engineering, Vol.24, No.1, 16-23, 2007
An experimental investigation on the rate of CO2 absorption into aqueous methyldiethanolamine solutions
In this paper, the CO2 absorption rates into aqueous solutions of Methydiethanolamine (MDEA) at various concentrations of 1, 2, 3 and 4M and temperatures varying from 293 to 323 K were measured by using a laboratory stirred reactor. The kinetics experiments were conducted under a pseudo first order regime. The data were analyzed by means of chemical absorption theory and the kinetic parameters associated with the reaction, such as the reaction order and the reaction rate constants, were evaluated. The effect of temperature on the reaction rate constant was assessed and the activation energy was evaluated at about 44.12 kJoule/mol.
[References]
Alvarez-Fuster C, Midoux N, Laurent A, Charpentier JC, Chem. Eng. Sci. , 35 , 1717, 1980
Benitez-Garcia J, Ruiz-Ibanez G, Al-Ghawas HA, Sandall OC, Chem. Eng. Sci. , 46 , 2927, 1991
Blauwhoff PMM, Versteeg GF, Van Swaaij WPM, Chem. Eng. Sci. , 39 , 207, 1984
Danckwerts PV, Gas liquid reaction, Mcgraw-Hill, New York, 1970
Davis RA, Pogainis BJ, J. Chem. Eng. Data , 40 (6), 1249, 1995
Donaldson TL, Nguyen YN, Ind. Eng. Chem. Fundam. , 19 , 260, 1980
Glasscock DA, Critchfield JE, Rochelle GT, Chem. Eng. Sci. , 46 , 2829, 1991
Haimour N, Bidarian A, Sandall OC, Chem. Eng. Sci. , 42 , 1393, 1987
Handbook of chemistry and physics, 83rd Edition, CRC press, 2002
Hatta S, Tohoku Imp. University , 8 , 1, 1928
Jensen MB, Jorgensen E, Faurholt C, Acta Chem. Scand. , 8 , 1137, 1954
Kohl AL, Riesenfeld FC, Gas purification, Houston, 4th Edition, Gulf Publishing Company, Texas, 1985
Laddha SS, Danckwerts PV, Chem. Eng. Sci. , 36 , 479, 1981
Laddha SS, Diaz JM, Danckwerts PV, Chem. Eng. Sci. , 36 , 229, 1981
Little RJ, Versteeg GF, Van Swaaij WPM, Chem. Eng. Sci. , 47 , 2037, 1992
Perrin DD, Dissociation constants of organic bases in aqueous solutions, Butterworths, London, 1965
Pinsent BRW, Pearson L, Roughton FGW, Trans. Faraday. Soc. , 52 , 1512, 1956
Rangwala HA, Morrell BR, Mather AE, Otto FD, Can. J. Chem. Eng. , 70 , 482, 1992
Rinker EB, Ashour SS, Sandall OC, Ind. Eng. Chem. Res. , 35 (4), 1107, 1996
Rinker EB, Ashour SS, Sandall OC, Chem. Eng. Sci. , 50 (5), 755, 1995
Snijder ED, Riele MJM, Versteeg GF, Van Swaaij WPM, J. Chem. Eng. Data , 38 , 475, 1993
Tomcej RA, Otto FD, AIChE J. , 35 , 861, 1989
Versteeg GF, Van Swaaij WPM, Chem. Eng. Sci. , 43 , 587, 1988
Versteeg GF, Van Swaaij WPM, J. Chem. Eng. Data , 33 , 29, 1988
Versteeg GF, Van Dijck LAJ, Van Swaaij WPM, Chem. Eng. Sci. , 144 , 113, 1996
Whitman WG, Chem. Met. Eng. , 29 , 146, 1923
Yu WC, Astarita G, Savage DW, Chem. Eng. Sci. , 40 , 1585, 1985
[Cited By]
Lee S, Song HJ, Maken S, Yoo SK, Park JW, Kim S, Shim JG, Jang KR, Korean Journal of Chemical Engineering , 25 (1), 1, 2008
Ou Z, Wu J, Yang L, Cen P, Korean Journal of Chemical Engineering , 25 (1), 124, 2008
Benamor A, Ali BS, Aroua MK, Korean Journal of Chemical Engineering , 25 (3), 451, 2008
Hussain MA, Aroua MK, Yin CY, Rahman RA, Ramli NA, Korean Journal of Chemical Engineering , 27 (6), 1864, 2010
Kierzkowska-Pawlak H, Chacuk A, Korean Journal of Chemical Engineering , 29 (6), 707, 2012
Naeem S, Ghaemi A, Shahhosseini S, Korean Journal of Chemical Engineering , 33 (4), 1278, 2016
이전 논문 다음 논문
Result Search