Issue
Korean Journal of Chemical Engineering,
Vol.22, No.4, 528-535, 2005
The Electrokinetic Microfluidic Flow in Multi-Channels with Emergent Applicability Toward Micro Power Generation
In order to elaborate the possible applicability of microfluidic power generation from conceptualization to system validation, we adopt a theoretical model of the electrokinetic streaming potential previously developed for the single channel problem. The ion transport in the microchannel is described on the basis of the Nernst-Planck equation, and a monovalent symmetric electrolyte of LiClO4 is considered. Simulation results provide that the flow-induced streaming potential increases with increasing the surface potential of the microchannel wall as well as decreasing the surface conductivity. The streaming potential is also changed with variations of the electric double layer thickness normalized by the channel radius. From the electric circuit model with an array of microchannels, it is of interest to evaluate that a higher surface potential leads to increasing the power density as well as the energy density. Both the power density and the conversion efficiency tend to enhance with increasing either external resistance or number of channels. If a single microchannel is assembled in parallel with the order of 103, the power density of the system employing large external resistance is estimated to be above 1W/m3 even at low pressure difference less than 1 bar.
[References]
  1. Bowen WR, Jenner F, J. Colloid Interface Sci., 173(2), 388, 1995
  2. Chang CC, Yang RJ, J. Micromech. Microeng., 14, 550, 2004
  3. Chun MS, Korean J. Chem. Eng., 19(5), 729, 2002
  4. Chun MS, Lee SY, Yang SM, J. Colloid Interface Sci., 266(1), 120, 2003
  5. Chun MS, Lee TS, Choi NW, J. Micromech. Microeng., 15, 710, 2005
  6. Dean JA, (eds.), Lange's Handbook of Chemistry, 15th Ed., McGraw-Hill, New York, 1999
  7. Effenhauser CS, Bruin GJ, Paulus A, Ehrat M, Anal. Chem., 69, 3451, 1997
  8. Harrison JD, Fluri K, Seiler K, Fan ZH, Effenhauser CS, Manz A, Science, 261, 895, 1993
  9. Hunter R, Zeta Potential in Colloid Science: Principles and Applications, Academic Press Inc., London, 1981
  10. Karniadakis GE, Beskok A, Micro Flows: Fundamentals and Simulation, Springer-Verlag Inc., New York, 2003
  11. Koeneman PB, Busch-Vishniac JJ, Wood KL, J. Microelectromech. Syst., 6, 355, 1997
  12. Levine S, Marriott JR, Neale G, Epstein N, J. Colloid Interface Sci., 52, 136, 1975
  13. Polson NA, Hayes MA, Anal. Chem., 72, 1088, 2000
  14. Probstein RF, Physicochemical Hydrodynamics, Wiley and Sons, New York, 1994
  15. Ren LQ, Li DQ, Qu WL, J. Colloid Interface Sci., 233(1), 12, 2001
  16. Rice CL, Whitehead R, J. Phys. Chem., 69, 4017, 1965
  17. Sung JH, Chun MS, Choi HJ, J. Colloid Interface Sci., 264(1), 195, 2003
  18. Szymczyk A, Aoubiza B, Fievet P, Pagetti J, J. Colloid Interface Sci., 216(2), 285, 1999
  19. Vainshtein P, Gutfinger C, J. Micromech. Microeng., 12, 252, 2002
  20. Werner C, Korber H, Zimmermann R, Dukhin S, Jacobasch HJ, J. Colloid Interface Sci., 208(1), 329, 1998
  21. Yang C, Li DQ, J. Colloid Interface Sci., 194(1), 95, 1997
  22. Yang J, Kwok DY, J. Micromech. Microeng., 13, 115, 2003
  23. Yang J, Lu F, Kostiuk LW, Kwok DY, J. Micromech. Microeng., 13, 963, 2003