A series of a new type of ionic liquids was prepared. The synthesis and purification procedure of N-alkyl-N-methylmorpholinium bromide, N-alkyl-N-methylmorpholinium tetrafluoroborate, N-alkyl-N-methylmorpholinium hexafluorophosphate, and N-alkyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide were presented. Thermal properties of morpholinium salts and ionic conductivities of lithium-doped ionic liquids were measured in the temperature range of 303.15 to 323.15 K. In the case of the pure ionic liquids, the ionic conductivities were 10-4 S·cm-1.