About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.21, No.4, 858-866, 2004
Thermodynamic Modeling of Vapor-Liquid Equilibria and Excess Properties of the Binary Systems Containing Diethers and n-Alkanes by Cubic Equation of State
Serbanovic SP, Grguric IR, Kijevcanin MLJ, Tasic AZ, Djordjevic BD
A comparison of the performances of two different approaches of cubic equations of state models, based on a classical van der Waals and mixing rules incorporating the GE equation, was carried out for correlation of Vapor-Liquid Equilibria (VLE), HE and cPE data alone, and simultaneous correlation of VLE+HE, VLE+cPE, HE+cPE and VLE+HE+cPE data for the diethers (1,4-dioxane or 1,3-dioxolane) with n-alkane systems. For all calculations the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) was used. A family of mixing rules for the PRSV CEOS based on the Modified van der Waals one-fluid mixing rule (MvdW1) and two well-known CEOS/GE mixing rules (MHV1 and MHV2), was considered. The NRTL equation, as the GE model with linear or reciprocal temperature dependent parameters, was incorporated in the CEOS/GE models. The results obtained by the CEOS/GE models exhibit significant improvement in comparison to the MvdW1 models.
Keywords: Cubic Equation of State; Thermodynamic Properties; Diether; n-Alkane; Simultaneous Correlation
[References]
  1. Anderko A, Fluid Phase Equilib., 61, 145, 1990
  2. Brocos P, Calvo E, Amigo A, Bravo R, Pintos M, Roux AH, Roux-Desgranges G, J. Chem. Eng. Data, 43(1), 112, 1998
  3. Calvo E, Brocos P, Bravo R, Pintos M, Amigo A, Roux AH, Roux-Desgranges G, J. Chem. Eng. Data, 43(1), 105, 1998
  4. Dahl S, Michelsen ML, AIChE J., 36, 1829, 1990
  5. Djordjevic BD, Kijevcanin ML, Serbanovic SP, Fluid Phase Equilib., 155(2), 205, 1999
  6. Djordjevic BD, Grguric IR, Kijevcanin ML, Tasic AZ, Serbanovic SP, "Simultaneous Representation of Binary HE and cpE Data Usingthe PRSV-MHV-1 Model," ICheaP-4, The Fourth Italian Conference on Chemical and Process Engineering, Florence, 1999
  7. Djordjevic BD, Kijevcanin ML, Orlovic JP, Serbanovic SP, J. Serb. Chem. Soc., 66, 213, 2001
  8. Djordjevic BD, Kijevcanin ML, Tasic AZ, Serbanovic SP, J. Serb. Chem. Soc., 64, 801, 1999
  9. Grguric IR, Serbanovic SP, Kijevcanin ML, Tasic AZ, Djordjevic BD, Thermochim. Acta, 412, 25, 2004
  10. Heidemann RA, Fluid Phase Equilib., 116, 454, 1996
  11. Hooke R, Jeeves TA, J. Assoc. Comput. Mach., 8, 212, 1961
  12. Kang SP, Lee H, Lee YW, Lee YY, Korean J. Chem. Eng., 12(5), 535, 1995
  13. Kijevcanin ML, Djordjevic BD, Serbanovic SP, Grguric IR, Tasic AZ, Phys. Chem. Liquids, 42, 147, 2004
  14. Knudsen K, Stenby EH, Fredenslund A, Fluid Phase Equilib., 82, 361, 1993
  15. Malanowski S, Anderko A, "Modeling Phase Equilibria. Thermodynamic Background and Practical Tools," John Wiley & Sons, Inc., New York, 1992
  16. Michelsen ML, Fluid Phase Equilib., 60, 213, 1990
  17. Ohta T, Fluid Phase Equilib., 129(1-2), 89, 1997
  18. Orbey H, Sandler SI, Fluid Phase Equilib., 121(1-2), 67, 1996
  19. Orbey H, Sandler SI, Fluid Phase Equilib., 111(1), 53, 1995
  20. Panagiotopoulos AZ, Reid RC, "New Mixing Rule for Cubic Equations of State for Highly Polar, Asymmetric Systems," Equation of State Theories and Applications, Chao, K.C. and Robinson Jr., R.L., Eds., ACS Symposium Series 300, American Chemical Society, Washington, DC, 1986
  21. Park BH, Yoo KP, Lee CS, Fluid Phase Equilib., 212(1-2), 221, 2003
  22. Renon H, Prausnitz JM, AIChE J., 14, 135, 1968
  23. Sandler SI, Orbey H, "Mixing and Combining Rules," Equation of State for Fluid and Fluid Mixtures, Part I, Sengers, J.V., Kayser, R.F., Peters, C.J. and White Jr., H.J., eds., Elsevier, Amsterdam, 2000
  24. Sandler SI, Orbey H, "Modeling Vapor-Liquid Equilibria. Cubic Equation of State and Their Mixing Rules," Cambridge Series in Chemical Engineering: Cambridge University Press, 1998
  25. Sandler SI, "Models for Thermodynamics and Phase Equilibria Calculations," Marcel-Dekker, New York, 1994
  26. Schwartzentruber J, Renon H, Ind. Eng. Chem. Res., 28, 1049, 1989
  27. Stryjek R, Vera JH, Can. J. Chem. Eng., 64, 323, 1986
  28. Tassios D, vanWinkle M, J. Chem. Eng. Data, 12, 555, 1967
  29. Valderrama JO, Silva A, Korean J. Chem. Eng., 20(4), 709, 2003
  30. Voros NG, Tassios DP, Fluid Phase Equilib., 91, 1, 1993
  31. Wu HS, Sandler SI, J. Chem. Eng. Data, 34, 209, 1989
[Cited By]
  1. Wang C, Lei Z, Korean Journal of Chemical Engineering, 23(1), 102, 2006
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.