Korean Journal of Chemical Engineering, Vol.21, No.3, 733-738, 2004
Growth Mechanism of Needle-shaped ZnO Nanostructures over NiO-coated Si Substrates
ZnO nanostructures were synthesized over NiO-coated Si substrate by a thermal evaporation of Zn powders in a vertical chemical vapor deposition reactor. The ZnO nanostructures had a needle-like morphology and the diameter of the structures decreased linearly from the bottom to the top. The bottom diameters of the ZnO nano-needles normally ranged from 20-100 nm and the lengths were in the range of 2-3 μm. The clear lattice fringes in HRTEM image indicated the growth of good quality hexagonal single-crystal ZnO. Field emission characteristics of the ZnO nanoneedles showed that the turn-on field was about 8.87 V/μm with a field enhancement factor of about 1099. The growth mechanism of the ZnO nano-needles was proposed on the basis of experimental data.
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Lee J, Nam SC, Tak Y, Korean Journal of Chemical Engineering , 22 (1), 161, 2005
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Kim SH, Umar A, Hahn YB, Korean Journal of Chemical Engineering , 22 (3), 489, 2005
Kim SH, Hong JH, Hahn YB, Korean Journal of Chemical Engineering , 23 (2), 325, 2006
Umar A, Ra HW, Jeong JP, Suh EK, Hahn YB, Korean Journal of Chemical Engineering , 23 (3), 499, 2006
Umar A, Jeong JP, Suh EK, Hahn YB, Korean Journal of Chemical Engineering , 23 (5), 860, 2006
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