Issue
Korean Journal of Chemical Engineering,
Vol.21, No.3, 703-711, 2004
Effect of Heat Transfer on the Transient Dynamics of Temperature Swing Adsorption Process
The effect of radial heat transfer on temperature swing adsorption (TSA) was studied by using an air-drying TSA experiment. The experimental dynamics of water adsorption and thermal regeneration in a fixed bed packed with zeolite 13X were used to evaluate the predicted results from the developed models. One- and two-dimensional models for energy balance with various equations describing internal velocity were compared in terms of the prediction of transient dynamics of TSA. Since the heat effect in adsorption step depended on the isosteric heat of adsorption, a dynamic simulation was performed under adiabatic, near-adiabatic, and constant wall temperature conditions. A comparison between one- and two-dimensional models was also made under near-adiabatic condition, which reflected on the experimental condition. There was little difference between adsorption breakthrough curves predicted by the oneand two-dimensional models because the radial distribution of temperature was negligible at the adsorption step. In the case of the regeneration step, a small difference between two models was expected just at the early period of time because the radial effect disappeared with time. One-dimensional model could provide an adequate prediction of the transient dynamics in this system when the wall energy balance was included.
[References]
  1. Ahn H, Lee CH, AIChE J., 49(6), 1601, 2003
  2. Ahn H, Kim MB, Lee CH, Sep. Sci. Technol., in press
  3. Basmadjian D, Can. J. Chem. Eng., 53, 234, 1975
  4. Basmadjian D, Ha KD, Pan CY, Ind. Eng. Chem. Process Des. Dev., 14, 328, 1975
  5. Carter JW, Husian H, Chem. Eng. Sci., 29, 267, 1974
  6. Davis MM, AIChE J., 33, 470, 1987
  7. Farooq S, Ruthven DM, Ind. Eng. Chem. Res., 29, 1076, 1990
  8. Kumar R, Dissinger GR, Ind. Eng. Chem. Process Des. Dev., 25, 456, 1986
  9. Lin WC, Farooq S, Tien C, Chem. Eng. Sci., 54(18), 4031, 1999
  10. Liu YJ, Ritter JA, Ind. Eng. Chem. Res., 36(5), 1767, 1997
  11. Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases and Liquids," McGraw-Hill, Singapore, 1988
  12. Ross S, Oliver JP, "On Physical Adsorption," Interscience, New York, 1964
  13. Ruthven DM, Farooq S, Knaebel KS, "Pressure Swing Adsorption," VCH Publisher, New York, 1994
  14. Ryu YK, Lee SJ, Kim JW, Lee CH, Korean J. Chem. Eng., 18(4), 525, 2001
  15. Schork JM, Fair JR, Ind. Eng. Chem. Res., 27, 457, 1988
  16. Shim WG, Lee JW, Rhee HK, Moon H, Korean J. Chem. Eng., 21(2), 469, 2004
  17. Shim WG, Chaudhary DS, Vigneswaran S, Ngo HH, Korean J. Chem. Eng., 21(1), 212, 2004
  18. Suzuki M, "Adsorption Engineering," Elsevier, Japan, 1990
  19. Thomas WJ, Crittenden B, "Adsorption Technology and Design," Butterworth-Heinemann, 1997
  20. Tien C, "Adsorption Calculations and Modeling," Butterworth-Heinemann, Boston, 1994
  21. Wakao N, Kaguei S, "Heat and Mass Transfer in Packed Beds," Gordon and Breach Science Publishers, 1982
  22. Yang RT, "Gas Separation by Adsorption Processes," Butterworths, Boston, 1987