Issue
Korean Journal of Chemical Engineering,
Vol.21, No.2, 469-476, 2004
Adsorption Dynamics for the Capillary Condensation of Trichloroethylene Vapor on Mesoporous Material
The adsorption of Trichloroethylene (TCE) vapors on both powder and pelletized MCM-48 was measured by using a quartz spring balance equipped in a high vacuum system. Single species equilibrium data show typical IV isotherms based on the IUPAC classification. Equilibrium data obtained were reasonably well fitted to a temperaturedependent hybrid (Langmuir+Sips) isotherm. To investigate the applicability of the hybrid isotherm on the prediction of breakthrough patterns, experimental and theoretical studies were carried out in a fixed bed charged with MCM-48.
[References]
  1. Brown PN, Byrne GD, Hindmarsh AC, SIAM J. Sci. Stat. Comput., 10, 1038, 1989
  2. Cho SY, Jeong SJ, Kim SJ, Chun HS, Korean J. Chem. Eng., 20(2), 387, 2003
  3. Corma A, Chem. Rev., 97(6), 2373, 1997
  4. Farooq S, Ruthven DM, Ind. Eng. Chem. Res., 29, 1084, 1990
  5. Edwards MF, Richardson JF, Chem. Eng. Sci., 23, 109, 1968
  6. Fuller EN, Schettler PD, Giddings JC, J. Gas Chromatogr., 3, 222, 1965
  7. Gregg SJ, Sing KSW, "Adsorption, Surface Area and Porosity," Academic Press, New York, 1982
  8. Hartmann M, Bischof C, J. Phys. Chem. B, 103(30), 6230, 1999
  9. Hill TL, J. Chem. Phys., 17, 520, 1949
  10. Hwang KS, Choi DK, Gong SY, Cho SY, Chem. Eng. Sci., 52(7), 1111, 1997
  11. Khan FI, Ghoshal AK, J. Loss. Prevent. Proc., 13(6), 527, 2000
  12. Kim SJ, Cho SY, Kim TY, Korean J. Chem. Eng., 19(1), 61, 2002
  13. Lee JW, Lee JW, Shim WG, Suh SH, Moon H, J. Chem. Eng. Data, 48, 381, 2003
  14. Lee JW, Shim WG, Moon H, Microporous Mesoporous Mater., submitted, 2003
  15. Malek A, Farooq S, AIChE J., 42(11), 3191, 1996
  16. Malek A, Farooq S, AIChE J., 43(3), 761, 1997
  17. Oh JS, Shim WG, Lee JW, Kim JH, Moon H, Seo G, J. Chem. Eng. Data, 48(6), 1458, 2003
  18. Park I, Knabel KS, AIChE J., 38(5), 660, 1992
  19. Riggs JB, "An Introduction to Numerical Methods for Chemicals Engineers," Texas Tech. University Press, Lubbock, 1988
  20. Ruddy EN, Carroll LA, Chem. Eng. Prog., 89, 28, 1993
  21. Shim WG, Lee JW, Lee JW, Moon H, "Adsorption Dynamics of CVOCs Vapor on MCM-48," Fourth International Symposium Effect of Surface Heterogeneity in Adsorption and Catalysis on Solids, Krakow, Poland, 2001
  22. Shim WG, Lee JW, Moon H, J. Chem. Eng. Data, 48(2), 286, 2003
  23. Shim WG, Lee JW, Moon H, Sep. Sci. Technol., 38(16), 3905, 2003
  24. Silva JA, Rodrigues AE, Ind. Eng. Chem. Res., 36(9), 3769, 1997
  25. Sircar S, Carbon, 25, 39, 1987
  26. U.S. Department of Health and Human Services, 9th Report on Carcinogens. http://ehp.niehs.nih.gov/
  27. Villadesen JV, Stewart WE, Chem. Eng. Sci., 22, 1483, 1967
  28. Yang RT, "Gas Separation by Adsorption Processes," Butterworths, Boston, 1986
  29. Yun JH, Korean J. Chem. Eng., 17(5), 613, 2000
  30. Wakao N, Funazkri T, Chem. Eng. Sci., 33, 1375, 1978
  31. Zhao XS, Lu GQ, Hu X, Colloids Surf. A: Physicochem. Eng. Asp., 179, 261, 2001