Issue
Korean Journal of Chemical Engineering,
Vol.20, No.4, 693-697, 2003
Thermal and Catalytic Degradation of Waste High-density Polyethylene (HDPE) Using Spent FCC Catalyst
Thermal and catalytic degradation using spent fluid catalytic cracking (FCC) catalyst of waste high-density polyethylene (HDPE) at 430 ℃ into fuel oil were carried out with a stirred semi-batch operation. The product yield and the recovery amount, molecular weight distribution and paraffin, olefin, naphthene and aromatic (PONA) distribution of liquid product by catalytic degradation using spent FCC catalyst were compared with those by thermal degradation. The catalytic degradation had lower degradation temperature, faster liquid product rate and more olefin products as well as shorter molecular weight distributions of gasoline range in the liquid product than thermal degradation. These results confirmed that the catalytic degradation using spent FCC catalyst could be a better alternative method to solve a major environmental problem of waste plastics.
[References]
  1. Bagri R, Williams PT, J. Anal. Appl. Pyrolysis, 63, 29, 2002
  2. Bockhorn H, Hornung A, Hornung U, J. Anal. Appl. Pyrolysis, 46, 1, 1998
  3. Buekens AG, Huang H, Res. Con. Recycl., 23, 163, 1998
  4. de la Puente G, Klocker C, Sedran U, Appl. Catal. B: Environ., 36(4), 279, 2002
  5. Jeong SW, Kim JH, Seo G, Korean J. Chem. Eng., 18(6), 848, 2001
  6. Lee KH, Lee YW, Ha BH, J. Catal., 178(1), 328, 1998
  7. Lee KH, Ha BH, Lee YW, Ind. Eng. Chem. Res., 37(5), 1761, 1998
  8. Lee KH, Kim SK, Shin DH, J. Korean Solid Waste Eng. Soc., 18(5), 442, 2001
  9. Lee KH, Noh NS, Shin DH, Seo YH, Polym. Degrad. Stabil., 78, 539, 2002
  10. Lee KH, Shin DH, Korean J. Chem. Eng., 20(1), 89, 2003
  11. Patel MK, Jochem E, Radgen P, Worrell E, Res. Con. Recycl., 24, 191, 1998
  12. Park JJ, Park K, Park JW, Kim DC, Korean J. Chem. Eng., 19(4), 658, 2002
  13. Park JR, Yoon JH, Park DW, Polym. Degrad. Stabil., 76, 61, 2002
  14. Pinto F, Costa P, Gulyurtlu I, Cabrita I, J. Anal. Appl. Pyrolysis, 51, 39, 1999
  15. Sakata Y, Uddin MA, Muto A, J. Anal. Appl. Pyrolysis, 51, 135, 1999
  16. Seddegi ZS, Budrthumal U, Al-Arfaj AA, Al-Amer AM, Barri SAI, Appl. Catal. A: Gen., 225(1-2), 167, 2002
  17. Songip AR, Masuda T, Kuwahara H, Appl. Catal. B: Environ., 2, 153, 1993
  18. Walendziewski J, Fuel, 81, 473, 2002