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Issue
Korean Journal of Chemical Engineering,
Vol.19, No.2, 337-341, 2002
Rheological Properties of Polystyrene and Poly(methyl methacrylate) Blends
Han MS, Jung HC, Park JH, Hyun JC, Kim WN
Rheological properties of the polystyrene (PS) and poly(methyl methacrylate) (PMMA) blends were studied by Advanced Rheometric Expansion System (ARES). Storage modulus and loss modulus of the PS and PMMA blends were measured, and the interfacial tension of the PS and PMMA blends were obtained with various emulsion models by using the storage modulus and loss modulus of the blends. The value of interfacial tension estimated from the Palierne emulsion model was found to be 2.0 mN/m. Also, the interfacial tension between PS and PMMA was calculated by a theoretical model. The values of interfacial tension of the PS and PMMA blends obtained by the experiment and theoretical model were found to be in good agreement.
Keywords: Interfacial Tension; Rheological Properties; Emulsion Model; Polymer-Polymer Interaction Parameter
[References]
  1. Broseta D, Fredrickson GH, Helfand E, Leiber L, Macromolecules, 23, 132, 1990
  2. Burns CM, Kim WN, Polym. Eng. Sci., 28, 1362, 1988
  3. Choi SJ, Schowalter WR, Phys. Fluids, 18, 420, 1975
  4. Everaert V, Groeninckx G, Pionteck J, Favis BD, Aerts L, Moldenaers P, Mewis J, Polymer, 41(3), 1011, 2000
  5. Ferry JD, "Viscoelastic Properties of Polymers," John Wiley & Sons, Inc., New York, 1980
  6. Friedrich C, Gleinser W, Korat E, Maier D, Weese J, J. Rheol., 39(6), 1411, 1995
  7. Graebling D, Muller R, J. Rheol., 34, 193, 1990
  8. Graebling D, Muller R, Colloids Surf., 55, 89, 1991
  9. Graebling D, Muller R, Palierne JF, Macromolecules, 26, 320, 1993
  10. Graebling D, Benkira A, Gallot Y, Muller R, Eur. Polym. J., 30, 301, 1994
  11. Gramespacher H, Meissner J, J. Rheol., 36, 1127, 1992
  12. Gramespacher H, Meissner J, J. Rheol., 41(1), 27, 1997
  13. Grizzuti N, Buonocore G, Iorio G, J. Rheol., 44, 149, 2000
  14. Grizzuti N, Bifulco O, Rheol. Acta, 36(4), 406, 1997
  15. Hara M, Sauer JA, Korean J. Chem. Eng., 15(4), 353, 1998
  16. Helfand E, Tagami Y, Polym. Lett., 9, 741, 1971
  17. Helfand E, Tagami Y, J. Chem. Phys., 56, 3592, 1972
  18. Helfand E, Sapse AM, J. Chem. Phys., 62, 1327, 1975
  19. Helfand E, Bhattacharjee SM, Fredrickson GH, J. Chem. Phys., 91, 7200, 1989
  20. Helfand E, Macromolecules, 25, 1676, 1992
  21. Larson RG, "The Structure and Rheology of Complex Fluid," Oxford Univ. Press, New York, 1999
  22. Lee HS, Denn MM, J. Rheol., 43(6), 1583, 1999
  23. Lee HS, Denn MM, Polym. Eng. Sci., 40(5), 1132, 2000
  24. Liang H, Favis BD, Yu YS, Eisenberg A, Macromolecules, 32(5), 1637, 1999
  25. Leiber L, Macromolecules, 13, 1602, 1980
  26. Luciani A, Champagne MF, Utracki LA, J. Polym. Sci. B: Polym. Phys., 35(9), 1393, 1997
  27. Kim YJ, Lee YM, Lee HM, Park OO, Korean J. Chem. Eng., 11(3), 172, 1994
  28. Kim SW, Chun YH, Korean J. Chem. Eng., 16(4), 511, 1999
  29. Kim WN, Denn MM, J. Rheol., 36, 1477, 1992
  30. Palierne JF, Rheol. Acta, 29, 204, 1990
  31. Rundqvist T, Cohen A, Klason C, Rheol. Acta, 35(5), 458, 1996
  32. Scholz P, Froelich D, Muller R, J. Rheol., 33, 481, 1989
  33. Tang H, Freed KF, J. Chem. Phys., 94, 1572, 1991
  34. Tang H, Freed KF, J. Chem. Phys., 94, 6307, 1991
  35. van Krevelen DW, "Properties of Polymers," Elsevier Sci. Publisher, New York, 1990
  36. Vignaux-Nassiet V, Allal A, Montfort JP, Eur. Polym. J., 34, 309, 1998
  37. Vinckier I, Moldenaers P, Mewis J, J. Rheol., 40(4), 613, 1996
[Cited By]
  1. Zueco J, Anwar Beg O, Chang TB, Korean Journal of Chemical Engineering, 26(5), 1226, 2009
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