| Issue |
Korean Journal of Chemical Engineering,
Vol.18, No.6, 935-940, 2001
Vol.18, No.6, 935-940, 2001
Effect of Humidity on the Photocatalytic Degradation of Trichloroethylene in Gas Phase over TiO2 Thin Films Treated by Different Conditions
The effect of humidity on the photocatalytic degradation reaction of trichloroethylene (TCE) in gas phase was investigated by using pretreated TiO2 sol-gel films. It was observed that the photocatalytic activity of the TiO2 films depended more greatly on the pretreatment conditions, for example, UV pre-illumination, than on the moisture content. When the relative humidity was over 50%, the reaction rates decreased regardless of treatment conditions of the photocatalyst. The photocatalytic decomposition rate of TCE increased with the increase of light intensity. However, the influence of humidity on the reaction rate was less significant under the increased light intensity The intermediates and byproducts of the reaction were not changed in different humidity conditions.
[References]
- Al-Ekabi H, Serpone N, J. Phys. Chem., 92, 5726, 1988
- Dibble LA, Raupp GB, Catal. Lett., 4, 345, 1990
- Eleazer WE, Odle WS, Wang YS, Barlaz MA, Environ. Sci. Technol., 31, 911, 1997
- Fox MA, Dulay MT, Chem. Rev., 93, 341, 1993
- Hsiao CY, Lee CL, Ollis DF, J. Catal., 82, 418, 1983
- Hisanaga T, Harada K, Tanaka K, J. Photochem. Photobiol. A-Chem., 54, 113, 1990
- Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69, 1995
- Hilgendorff M, Bahnemann AW, J. Adv. Oxid. Technol., 1, 35, 1996
- Hong SS, Ju CS, Lim CG, Ahn BH, Lim KT, Lee GD, J. Ind. Eng. Chem., 7(2), 99, 2001
- Hung CH, Marinas BJ, Environ. Sci. Technol., 31, 562, 1997
- Hung CH, Marinas BJ, Environ. Sci. Technol., 31, 1440, 1997
- Izumi I, Dunn WW, Wilbourn KO, Fan FF, Bard AJ, J. Phys. Chem., 84, 3207, 1980
- Jeong HR, Kim JS, Joo H, Auh C, Lee TK, Moon I, Yun WS, HWAHAK KONGHAK, 39(3), 352, 2001
- Kim JS, Itoh K, Murabayashi M, Denki Kagaku, 64, 1200, 1996
- Kim JS, Itoh K, Murabayashi M, Chemosphere, 36, 483, 1998
- Kim JS, Itoh K, Murabayashi M, Chemosphere, 38, 2969, 1999
- Kim JS, Joo HK, Lee TK, Itoh K, Murabayashi M, J. Catal., 194(2), 484, 2000
- Liu TC, Cheng TI, Catal. Today, 26(1), 71, 1995
- Kutsuna S, Ebihara Y, Nakamura K, Ibusuki T, Atmospheric Environ., 27A, 599, 1993
- Matthews RW, J. Catal., 111, 264, 1988
- Jeon MS, Lee TK, Kim DH, Joo H, Kim HT, Sol. Energy Mater. Sol. Cells, 57(3), 217, 1999
- Murabayashi M, Itoh K, Kuroda S, Huda R, Masuda R, Takahashi W, Kawashima K, Denki Kagaku, 60, 741, 1992
- Murabayashi M, Itoh K, Togashi K, Shiozawa K, Yamazaki H, J. Adv. Oxid. Technol., 4, 71, 1999
- Nimlos MR, Jacoby WA, Blake DM, Milne TA, Environ. Sci. Technol., 27, 732, 1993
- Ollis DF, Hsiao CY, Budiman L, Lee CL, J. Catal., 88, 89, 1984
- Ollis DF, Environ. Sci. Technol., 19, 480, 1985
- Ollis DF, Pelizzetti E, Serpone N, Environ. Sci. Technol., 25, 1523, 1991
- Tanguay JF, Suib SL, Coughlin RW, J. Catal., 117, 335, 1989
- Turchi CS, Ollis DF, J. Catal., 122, 178, 1990
- Yamazaki-Nishida S, Nagano KJ, Phillips LA, Cervera-March S, Anderson MA, J. Photochem. Photobiol. A-Chem., 70, 95, 1993
- Yamazakinishida S, Cerveramarch S, Nagano KJ, Anderson MA, Hori K, J. Phys. Chem., 99(43), 15814, 1995
- Yoon JK, Yoon WS, Joo HK, Jeon MS, Lee TK, HWAHAK KONGHAK, 38(2), 288, 2000
[Cited By]
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.