Issue
Korean Journal of Chemical Engineering,
Vol.40, No.1, 235-247, 2023
An effective and smart corrosion inhibitor in acidic environment: Experimental & theoretical studies
The application of corrosion inhibitors is the best way to protect metals from degradation. Therefore, the P-anisidine molecule was investigated as a corrosion inhibitor for mild steel in a 1M HCl medium. This study used different methods, such as electrochemical impedance spectroscopy, polarization potentiodynamic curves, scanning electron microscopy, and theoretical method. The addition of this molecule to the aggressive medium achieved inhibition of 81% at a concentration of 10-3M. The potentiodynamic polarization curves reveal a mixed type character (anodic and cathodic) and adsorb on the metal surface according to Langmuir adsorption isotherm. This adsorption was also proved by scanning electron microscopy proving the presence of a protective layer on the steel surface used. The theoretical results confirmed the experimental part and showed that P-anisidine adsorbed parallel onto the steel surface covering a large surface area.
[References]
  1. Haldhar R, Kim SC, Prasad D, Bedair MA, Bahadur I, Kaya S, Dagdag O, Guo L, J. Mol. Struct., 1242, 130822, 2021
  2. Salim R, Ech-chihbi E, Oudda H, El-hajjaji F, Taleb M, Jodeh S, J. Bio-Tribo-Corros., 13, 5, 2019
  3. Arrousse N, Mabrouk E, Salim R, Alaoui KI, El-hajjaji F, Rais Z, Taleb M, Hammouti B, Mater. Today: Proc., 27, 3184, 2020
  4. Haldhar R, Prasad D, J. Bio-Tribo-Corros., 6, 48, 2020
  5. El-hajjaji F, Abrigach F, Hamed O, Hasan AR, Taleb M, Jodeh S, Rodriguez-Castellon E, Yuso MVM, Algarra M, Coatings, 8, 330, 2018
  6. Haldhar R, Prasad D, Bahadur I, Dagdag O, Berisha A, J. Mol. Liq., 323, 114958, 2021
  7. Haldhar R, Prasad D, Bahadur I, Dagdag O, Kaya S, Verma DK, Kim SC, J. Mol. Liq., 335, 116184, 2021
  8. Haldhar R, Prasad D, Kamboj D, Kaya S, Dagdag O, Guo L, Appl. Sci., 3, 25, 2021
  9. Butoi B, Groza A, Dinca P, Balan A, Barna V, Polymer, 9, 732, 2017
  10. Haldhar R, Prasad D, Mandal N, Benhiba F, Bahadur I, Dagdag O, Colloids Surf. A: Physicochem. Eng. Asp., 614, 126211, 2021
  11. Shukla SK, Quraishi A, J. Appl. Polym. Sci., 124, 5130, 2012
  12. Karthikaiselvi R, Subhashini S, J. Assoc. Arab Univ. Basic Appl. Sci., 16, 74, 2014
  13. Ma Y, Fan B, Liu H, Fan G, Hao H, Yang B, Appl. Surf. Sci., 514, 146086, 2020
  14. Abdellaoui O, Skalli MK, Haoudi A, Rodi YK, Mazzah A, Arrousse N, Taleb M, Ghibate R, Senhaji O, Mor. J. Chem., 9, 44, 2021
  15. Arrousse N, Mabrouk E, Hammouti B, El-hajjaji F, Rais Z, Taleb M, Int. J. Corros. Scale Inhib., 9, 661, 2020
  16. Arrousse N, Salim R, Abdellaoui A, El-hahhaji F, Hammouti B, Mabarouk E, Dino WA, Taleb M, J. Taiwan Inst. Chem. Eng., 120, 344, 2021
  17. Haldhar R, Prasad D, Nguyen LTD, Kaya S, Bahadur I, Dagdag O, Kim SC, Mater. Chem. Phys., 267, 124613, 2021
  18. Ech-chihbi E, Nahlé A, Salim R, Benhiba F, Moussaif A, Elhajjaji F, Oudda H, Guenbour A, Taleb M, Warad I, Zarrouk A, J. Alloy. Compd., 844, 155842, 2020
  19. Haldhar R, Prasad D, Saharan H, J. Ind. Eng. Chem., 11, 1, 2020
  20. Bourzi H, Oukhrib R, El-Ibrahimi B, Oualid HA, Abdellaoui Y, Balkard B, El-Issami S, Hilali M, Bazzi L, Len C, Sustainability, 12, 3304, 2020
  21. Haldhar R, Prasad D, Saxena A, J. Environ. Chem. Eng., 6, 5230, 2018
  22. El-Ibrahimi B, Jmiai A, El-Mouaden K, Oukhrib R, Soumoue A, El-Issami S, Bazzi L, J. King Saud Univ. Sci., 32, 163, 2020
  23. El-Ibrahimi B, Colloids Interface Sci. Commun., 37, 100279, 2020
  24. Farhadian A, Kashani SA, Rahimi A, Oguzie EE, Parvar AJ, Nwanonenyi SC, Zadeh SY, Nabi MR, J. Mol. Liq., 338, 11660, 2021
  25. Haldhar R, Prasad D, Saxena A, Kaur A, Eur. Phys. J. Plus, 133, 356, 2018
  26. Saha SK, Dutta A, Ghosh P, Sukul D, Banerjee P, Phys. Chem. Chem. Phys., 18, 17898, 2016
  27. Kumari PP, Shetty P, Rao SA, Arab. J. Chem., 10, 653, 2017
  28. Saady A, Ech-chihbi E, El-hajjaji F, Benhiba F, Zarrouk A, Kandrirodi Y, Taleb M, El-Biache A, Rais Z, J. Appl. Electrochem., 51, 245, 2021
  29. Zhang Y, Tan B, Zhang X, Guo L, Zhang S, J. Mol. Liq., 33, 116702, 2021
  30. Sĭgircik G, Tunc T, Erbil M, Corrosion Sci., 102, 437, 2016
  31. Xu B, Yang W, Liu Y, Yin X, Gong W, Chen Y, Corrosion Sci., 78, 260, 2014
  32. Hameed RSA, Alfakeer M, Abdallah M, Surf. Eng. Appl. Electrochem., 54, 599, 2018
  33. Arrousse N, Salim R, Obot IB, Abdellaui A, El-hajjaji F, Mabrouk E, Taleb M, J. Mol. Liq., 359, 119311, 2022
  34. Ghazoui A, Benchat N, El-hajjaji F, Taleb M, Rais R, Saddik R, Elaatiaoui A, Hammouti B, J. Alloy. Compd., 693, 510, 2017
  35. Mrani SA, Ech-chihbi E, Arrousse N, Rais Z, El-hajjaji F, El-Abiad C, Radi S, Mabrouki J, Taleb M, Jodeh S, Arab. J. Sci. Eng., 46, 5691, 2021
  36. Liu YW, Chen Y, Chen XH, Yang ZN, Hang ZZ, J. Alloy. Compd., 758, 184, 2018
  37. Nahlé A, Salim R, El-hajjaji F, Aouad MR, Messali M, Echchihbi E, Hammouti B, Taleb M, RSC Adv., 11, 4147, 2021
  38. Messali M, Larouj M, Lgaz H, Rezki N, Al-Blewi FF, Aouad MR, Chaouiki A, Salghi R, Chung ML, J. Mol. Struct., 1168, 39, 2018
  39. Arrousse N, Salim R, Benhiba F, Mabrouk EH, Abdelaoui A, El-hajjaji F, Warad I, Zakkrouk A, Taleb M, J. Mol. Liq., 338, 116610, 2021
  40. El-hajjaji F, Salim R, Messali M, Hammouti B, Chauhan DS, Almutairi SM, Quraishi MA, J. Bio-Tribo-Corros., 5, 4, 2019
  41. Rahimi A, Abdouss M, Farhadian A, Guo L, Neshati J, Eng. Chem. Res., 60, 11030, 2020
  42. Chile NE, Haldhar R, Godffrey UK, Chijioke OC, Umezuruike EA, Ifeoma OP, Oke MO, Ichou H, Arrousse N, Kim SC, Lubricants, 10, 1, 2022
  43. Saady A, El-hajjaji F, Taleb M, Alaoui KI, El-Biache A, Mahfoud A, Alhouari G, Hammouti B, Chauhan DS, Quraishi MA, Mater. Discov., 12, 30, 2019
  44. Kumari PP, Shetty P, Rao SA, Arab. J. Chem., 10, 653, 2017
  45. Dohare P, Chauhan DS, Sorour AA, Quraishi MA, Mater. Discov., 9, 30, 2017
  46. Obaid AY, Ganash AA, Qusti AH, Elroby SA, Hermas AA, Arab. J. Chem., 10, S1276, 2017
  47. Murulana LC, Singh AK, Shukla SK, Kabanda MM, Ebenso EE, Ind. Eng. Chem. Res., 51, 13282, 2012
  48. Ma Q, Qi S, He X, Tang Y, Lu G, Corrosion Sci., 129, 91, 2017
  49. Lazrak J, Salim R, Arrousse N, Ech-chihbi E, El-hajjaji F, Taleb M, Farah F, Ramzi A, Int. J. Corros. Scale Inhib., 9, 1580, 2020
  50. Olasunkanmil O, Obot IB, Kabanda MM, Ebenso EE, J. Phys. Chem., 119, 16004, 2015
  51. El-hajjaji F, Ech-chihbi E, Rezki N, Benhiba F, Taleb M, Chauhan DS, Quraishi MA, J. Mol. Liq., 314, 113737, 2020
  52. Kumar R, Chahal S, Kumar S, Lata S, Salghi R, Jodeh S, Lgaz H, J. Mol. Liq., 243, 439, 2017
  53. Hamani H, Douadi T, Daoud D, Al-Noaimi M, Rikkouh RA, Chafaa S, J. Electroanal. Chem., 801, 425, 2017
  54. El-Ibrahimi B, Jmiai A, El-Mouaden K, Baddouh A, El-Issami S, Bazzi L, Hilali M, J. Mol. Struct., 1196, 105, 2019
  55. Qiang Y, Zhang S, Guo L, Zheng X, Xiang B, Chen S, Corrosion Sci., 119, 68, 2017
  56. Singh A, Ansari KR, Lin Y, Quraishi MA, Lgaz H, Chung IM, J. Taiwan Inst. Chem. Eng., 95, 341, 2018
  57. El-hajjaji F, Salim R, Taleb M, Benhiba F, Rezki N, Chauhan DS, Quraishi MA, Surf. Interfaces, 22, 100881, 2021
  58. Li F, Bai M, Wei SA, Jin S, Shen W, Ind. Eng. Chem. Res., 58, 7166, 2019
  59. Feng L, Zhang S, Qiang Y, Xu S, Tan B, Chen S, Mater. Chem. Phys., 215, 229, 2018