Issue
Korean Journal of Chemical Engineering,
Vol.39, No.10, 2594-2599, 2022
Recycling of LiMO2 cathode materials by a chlorination-based Li extraction technique
The recycling of Li(Ni1/3Co1/3Mn1/3)O2 (NCM) and LiCoO2 (LCO), which are cathode materials for Li-ion batteries, was demonstrated via a chlorination-based Li extraction technique. The recycling process follows a chlorination - washing/filtering - drying - mixing - re-synthesis process. Around 86% of Li was removed through the chlorination - washing/filtering steps. The resulting transition metal oxide powder was dried and then mixed with Li2CO3, a Li precursor. Re-synthesis experiments were conducted at 900 ℃ for 24 h and the weight of the final products was 88.5 and 88.0 wt% of their input amounts in NCM and LCO, respectively. Structural changes were analyzed by X-ray diffraction to confirm the absence of impurity phases in the re-synthesized specimens. Electrochemical evaluation revealed that the re-synthesized NCM and LCO exhibit corresponding initial specific capacities of 157 and 153 mAh/g.
[References]
  1. Or T, Gourley SWD, Kaliyappan K, Yu A, Chen Z, Carbon Energy, 2, 6, 2020
  2. Harper G, Sommerville R, Kendrick E, Driscoll L, Slater P, Stolkin R, Walton A, Christensen P, Heidrich O, Lambert S, Abbott A, Ryder K, Gaines L, Anderson P, Nature, 575, 75, 2019
  3. Bae H, Kim Y, Mater. Adv., 2, 3234, 2021
  4. Jeon MK, Kim SW, Eun HC, Lee KY, Kim H, Oh M, Korean J. Chem. Eng., 39, 1472, 2022
  5. Nitta N, Wu F, Lee JT, Yushin G, Mater. Today, 18, 252, 2015
  6. Jeon MK, Kim SW, Oh M, Eun HC, Lee K, Korean J. Chem. Eng., In press (2022),
  7. Jeon MK, Kim SW, Korean J. Chem. Eng., 39, 2109, 2022
  8. Anufrieva TA, Derlyukova LE, Russ. J. Inorg. Chem., 52, 1840, 2007
  9. Wang H, Jang YI, Huang B, Sadoway DR, Chiang YM, J. Electrochem. Soc., 146, 473, 1999