Korean Journal of Chemical Engineering, Vol.39, No.10, 2652-2663, 2022
Vapor-phase hydrogenolysis of glycerol to value-added 1,2-propanediol over copper-nickel bimetallic catalysts supported on activated carbon
In the production of biodiesel, a sustainable energy alternative to fossil fuel, surplus glycerol, is generated as a by-product. Valorization of excess glycerol is the most promising approach for rendering the biodiesel sector fiscally practical. Herein, copper and nickel monometallic and bimetallic catalysts supported over activated carbon were developed using the incipient wetness impregnation technique for the hydrogenolysis of vapor-phase glycerol to 1,2-propanediol (1,2-PDO) at a pressure of 0.75MPa and temperature of 220℃. The catalysts were characterized by Brunauer- Emmett-Teller, X-ray diffraction, H2-temperature-programmed reduction, NH3-temperature-programmed desorption, X-ray photoelectron spectroscopy, and scanning electron microscopy analyses. The bimetallic catalysts afforded higher product yields than the monometallic catalysts did in glycerol hydrogenolysis. Cu-Ni(1 : 1)/AC gave the maximum yield of 1,2-PDO (87.3%), with high glycerol conversion (95.7%) under the previously mentioned reaction conditions, with a comparatively low molar ratio of hydrogen to glycerol (54.6). The strong copper-nickel synergy, smaller crystallite size, and high acid strength of Cu-Ni(1 : 1)/AC account for this superior performance.
[References]
Renewable energy policy Network 21st Century steering committee. Renewables 2021: global status report. (2021)
OECD/FA, OECD-FAO Agricultural Outlook 2018-2027. Paris, Rome, OECD Publishing, FAO (2018).
Ayoub M, Abdullah AZ, Renew. Sust. Energ. Rev. , 16 , 2671, 2012
Yang F, Hanna MA, Sun R, Biotechnol. Biofuels , 5 , 1, 2012
Bagheri S, Julkapli NM, Yehye WA, Renew. Sust. Energ. Rev. , 41 , 113, 2015
Quispe CAG, Coronado CJR, Carvalho JA, Renew. Sust. Energ. Rev. , 27 , 475, 2013
Wang Y, Zhou J, Guo X, RSC Adv. , 5 , 74611, 2015
Brandner A, Lehnert K, Bienholz A, Lucas M, Claus P, Top. Catal. , 52 , 278, 2009
Marinas A, Bruijnincx P, Ftouni J, Urbano FJ, Pinel C, Catal. Today , 239 , 31, 2015
Miyazawa T, Kusunoki Y, Kunimori K, Tomishige K, J. Catal. , 240 , 213, 2006
Hu J, Liu X, Wang B, Pei Y, Qiao M, Fan K, Chin. J. Catal. , 33 , 1266, 2012
Montassier C, Giraud D, Barbier J, Guisnet M, Barrault J, Bouchoule C, Duprez D, Montassier C, Perot G, Heter. Catal. Fine Chem., Elsevier, 165 (1988).
Feng J, Fu H, Wang J, Li R, Chen H, Li X, Catal. Commun. , 9 , 1458, 2008
Wang S, Yin K, Zhang Y, Liu H, ACS Catal. , 3 , 2112, 2013
Nakagawa Y, Tomishige K, Catal. Sci. Technol. , 1 , 179, 2011
Montassier C, Menezo JC, Hoang LC, Renaud C, Barbier J, J. Mol. Catal. , 70 , 99, 1991
Lahr DG, Shanks BH, J. Catal. , 232 , 386, 2005
Mane R, Patil S, Shirai M, Rayalu S, Rode C, Appl. Catal. B: Environ. , 204 , 134, 2017
Furikado I, Miyazawa T, Koso S, Shimao A, Kunimori K, Tomishige K, Green Chem. , 9 , 582, 2007
Nakagawa Y, Shinmi Y, Koso S, Tomishige K, J. Catal. , 272 , 191, 2010
Pudi SM, Biswas P, Kumar S, Sarkar B, J. Braz. Chem. Soc. , 26 , 1551, 2015
Mai CTQ, Ng FTT, Catal. Today , 291 , 195, 2017
Tan H, Hedhill MN, Wang Y, Zhang J, Li K, Sioud S, Al-Talla ZA, Amad MH, Zhan T, Tall OE, Han Y, Catal. Sci. Technol. , 3 , 3360, 2013
Zheng J, Zhu W, Ma C, Hou Y, Zhang W, Wang Z, React. Kinet. Mech. Catal. , 99 , 455, 2010
Tanielyan SK, Marin N, Alvez G, Bhagat R, Miryala B, Augustine RL, Schmidt SR, Org. Process Res. Dev. , 18 , 1419, 2014
Zhao H, Zheng L, Li X, Chen P, Hou Z, Catal. Today , 355 , 84, 2020
Yuan Z, Wang J, Wang L, Xie W, Chen P, Hou Z, Zheng X, Bioresour. Technol. , 101 , 7088, 2010
Wu Z, Mao Y, Song M, Yin X, Zhang M, Catal. Commun. , 32 , 52, 2013
Pudi SM, Biswas P, Kumar S, J. Chem. Technol. Biotechnol. , 91 , 2063, 2016
Pandhare NN, Pudi SM, Biswas P, Sinha S, Org. Process Res. Dev. , 20 , 1059, 2016
Pandhare NN, Pudi SM, Biswas P, Sinha S, J. Taiwan Inst. Chem. Eng. , 61 , 90, 2016
Bienholz A, Hofmann H, Claus P, Appl. Catal. A: Gen. , 391 , 153, 2011
Sato S, Akiyama M, Takahashi R, Hara T, Inui K, Yokota M, Appl. Catal. A: Gen. , 347 , 186, 2008
Sun D, Yamada Y, Sato S, Ueda W, Appl. Catal. B: Environ. , 193 , 75, 2016
Sun D, Yamada Y, Sato S, Appl. Catal. A: Gen. , 475 , 63, 2014
Yuan Z, Wu P, Gao J, Lu X, Hou Z, Zheng X, Catal. Lett. , 130 , 261, 2009
Zheng L, Xia S, Hou Z, Appl. Clay Sci. , 118 , 68, 2015
Yuan Z, Wang L, Wang J, Xia S, Chen P, Hou Z, Zheng X, Appl. Catal. B: Environ. , 101 , 431, 2011
Pandey DK, Biswas P, React. Chem. Eng. , 5 , 2221, 2020
Huang L, Zhu YL, Zheng HY, Li YW, Zeng ZY, J. Chem. Technol. Biotechnol. , 83 , 1670, 2008
Akiyama M, Sato S, Takahashi R, Inui K, Yokota M, Appl. Catal. A: Gen. , 371 , 60, 2009
Zhu S, Gao X, Zhu Y, Zheng H, Li Y, J. Catal. , 303 , 70, 2013
Zhao J, Yu W, Chen C, Miao H, Ma H, Xu J, Catal. Lett. , 134 , 184, 2010
Jiménez-Morales I, Vila F, Mariscal R, Jiménez-López A, Appl. Catal. B: Environ. , 117-118 , 253, 2012
Soares OSGP, Órfão JJM, Pereira MFR, Appl. Catal. B: Environ. , 91 , 441, 2009
Soares OSGP, Órfão JJM, Pereira MFR, Catal. Lett. , 126 , 253, 2008
Bandosz TJ, in Surface chemistry of carbon materials, Serp P, Figueiredo JL Eds., Carbon Materials for Catalysis, J. Wiley & Sons, Hoboken, NJ (2009).
Rodríguez-Reinoso F, Carbon , 36 , 159, 1988
Suarez EG, Ruiz AG, Ramos IR, Arcoya A, Chem. Eng. J. , 262 , 326, 2015
Kruk M, Jaroniec M, Chem. Mater. , 13 , 3169, 2001
Leofanti G, Padovan M, Tozzola G, Venturelli B, Catal. Today , 41 , 207, 1998
Vanama PK, Kumar A, Ginjupalli SR, Komandur VRC, Catal. Today , 250 , 226, 2015
Gandarias I, Requies J, Arias PL, Armbruster U, Martin A, J. Catal. , 290 , 79, 2012
Zhang B, You H, Wang F, Yang Z, Catal. Commun. , 88 , 56, 2017
Tüysüz H, Salabaş EL, Bill E, Bongard H, Spliethoff B, Lehmann CW, Schüth F, Chem. Mater. , 24 , 2493, 2012
Hierl R, Knözinger H, Urbach HP, J. Catal. , 69 , 475, 1981
Merabti R, Bachari K, Halliche D, Rassoul Z, Saadi A, React. Kinet. Mech. Catal. , 101 , 195, 2010
Arbeláez O, Reina TR, Ivanova S, Bustamante F, Villa AL, Centeno MA, Odriozola JA, Appl. Catal. A: Gen. , 497 , 1, 2015
Khandan N, Kazemeini M, Aghaziarati M, Appl. Catal. A: Gen. , 349 , 6, 2008
Feng Y, Yin H, Wang A, Shen L, Yu L, Jiang T, Chem. Eng. J. , 168 , 403, 2011
Khromova SA, Smirnov AA, Bulavchenko OA, Saraev AA, Kaichev VV, Reshetnikov SI, Yakovlev VA, Appl. Catal. A: Gen. , 470 , 261, 2014
Barbieri PF, de Siervo A, Carazzolle M, Landers R, Kleiman GG, J. Electron Spectrosc. Relat. Phenom. , 135 , 113, 2004
Huang L, Lv Y, Wu S, Liu P, Xiong W, Hao F, Luo H, Appl. Catal. A: Gen. , 577 , 76, 2019
Kaichev VV, Gladky AY, Prosvirin IP, Saraev AA, Hävecker M, Knop-Gericke A, Schlogl R, Bukhtiyarov VI, Surf. Sci. , 609 , 113, 2013
Patil SP, Pande JV, Biniwale RB, Int. J. Hydrog. Energy , 38 , 15233, 2013
Mane RB, Yamaguchi A, Malawadkar A, Shirai M, Rode CV, RSC Adv. , 3 , 16499, 2013
Balaraju M, Rekha V, Devi BLAP, Prasad PSS, Prasad RBN, Lingaiah N, Appl. Catal. A: Gen. , 354 , 82, 2009
Mane RB, Hengne AM, Ghalwadkar AA, Vijayanand S, Mohite PH, Potdar HS, Rode CV, Catal. Lett. , 135 , 141, 2010
Riaz N, Chong FK, Dutta BK, Man ZB, Khan MS, Nurlaela E, Chem. Eng. J. , 185-186 , 108, 2012
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