About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.39, No.10, 2861-2874, 2022
Exploration of anti-corrosive activity of TP (thespesia populnea)-TiO2 composite coating for mild steel (CS) in aggressive environments
Krishnan A
As part of promoting eco-friendly research & development, corrosion chemistry encourages green inhibitors for metal corrosion prevention. Thespesia Linoleic acid, n-Hexadecanoic acid, trans-Squalene, Phytol were identified as the active components responsible for corrosion inhibition. The optimum concentration of 500 ppm could deliver protection with efficiency in the range of 97%-98%. Additionally, we extended the study to evaluate the extract's capability for its use in the paint industry. The remarkable potential of the TiO2-TP composite coating thus developed was illustrated by physico-chemical, electrochemical, and surface analyses. According to the electrochemical impedance spectroscopy (EIS) study, the applied leaf extract loaded coatings resist corrosion of CS at efficiencies of 97.9%, 91.6%, and 98.5% in 1M HCl, 1M HCl at 80℃, and rainwater mediums, respectively. The proposed composite coating is undoubtedly promising for industrial application and is also recommended by green protocols.
Keywords: Green Inhibitor; Electrochemical Corrosion; Thespesia Populnea; TiO2; Passive Film; Barrier Protection
[References]
  1. Ali IH, Suleiman MHA, Int. J. Electrochem. Sci., 13, 3910, 2011
  2. Krishnan A, Shibli SMA, Akashnath S, Chithi A, Vanikrishna AN, Vinayak S, Asian J. Chem., 29, 2755, 2017
  3. Fouda AS, Nazeer AA, EI Behairy WT, J. Bio. Tribo. Corros., 4, 8, 2018
  4. Bhuvaneshwari TK, Vasantha VS, Jeyaprabha C, Silicon, 10, 1793, 2018
  5. Gopalakrishnan A, Kariyil BJ, John R, Usha PTA, Phcog. Mag., 15, 150, 2019
  6. Derfouf H, Harek Y, Larabi L, Basirun WJ, Ladan M, J. Adhes. Sci. Technol., 33, 808, 2019
  7. Mobin M, Basik M, El Aoufir Y, J. Mol. Liq., 286, 110890, 2019
  8. Miralrio A, Vázquez AE, Processes, 8, 942, 2020
  9. Krishnan A, Shibli SMA, Anti-Corros Method M, 65, 210, 2018
  10. Mobin M, Basik M, Aslam J, Measurement, 134, 595, 2019
  11. Saxena A, Prasad D, Haldhar R, Singh G, Kumar A, J. Environ. Chem. Eng., 6, 694, 2018
  12. Li D, Zhang P, Guo X, Zhao X, Xu Y, RSC Adv., 9, 40997, 2019
  13. Tiwari P, Srivastava M, Mishra R, Ji G, Prakash R, J. Environ. Chem. Eng., 6, 4773, 2018
  14. Raghavendra N, Bhat JI, Res. Chem. Intermed., 42, 6351, 2016
  15. Verma C, Quraishi MA, Ebenso EE, Bahadur I, J. Bio. Tribo. Corros., 4, 33, 2018
  16. Al-Moubaraki AH, Al-Howiti AA, Al-Dailami MM, Al-Ghamdi EA, J. Environ. Chem. Eng., 5, 4194, 2017
  17. Sangeetha R, Vedasree N, ISRN Pharmacol., 2012, 1, 2012
  18. Rajamurugan R, Shilpa GR, Kumaravel S, Paranthaman R, Bio. Med. Rx., 1, 248, 2013
  19. Rangani J, Kumari A, Patel M, Brahmbhatt H, Parida AK, J. Food Biochem., 43, 12731, 2019
  20. Gowtham R, Umamaheswari G, Bavani S, Ambikapathy V, RJLBPCS, 5, 138, 2019
  21. Gadow HS, Motawea MM, RSC Adv., 7, 24576, 2017
  22. Saxena A, Prasad D, Haldhar R, Singh G, Kumar A, J. Mol. Liq., 258, 89, 2018
  23. Suma MS, Basheer R, Sreelekshmy BR, Vipinlal V, Sha MA, Jineesh P, Krishnan A, Archana SR, Shibli SMA, Int. Biodeterior. Biodegrad., 137, 59, 2019
  24. Veedu KK, Kalarikkal TP, Jayakumar N, Gopalan NK, ACS Omega, 4, 10176, 2019
  25. Krishnan A, Joseph B, Bhaskar KM, Suma MS, Shibli SMA, Polym. Compos., 40, 2400, 2019
  26. Shehata OS, Korshed LA, Attia A, Shehata OS, Korshed LA, Attia A, Corrosion inhibitors, principles and recent applications, United Kingdom: IntechOpen, London (2017).
  27. Zheng X, Gong M, Li Q, Guo L, Sci. Rep., 8, 9140, 2018
  28. Dehghani A, Bahlakeh G, Ramezanzadeh B, Bioelectrochem, 130, 107339, 2019
  29. Wang X, Lingua Y, Wang Q, Wan Y, Huang X, Jing C, Int. J. Electrochem. Sci., 13, 5228, 2018
  30. Qiang Y, Zhang S, Tan B, Chen S, Corrosion Sci., 133, 6, 2018
  31. Casaletto MP, Figà V, Privitera A, Bruno M, Napolitano A, Piacente S, Corrosion Sci., 136, 91, 2018
  32. Beenakumari KS, Oriental J. Chem., 29, 213, 2013
  33. Umoren SA, Gasem ZM, Obot IB, Ind. Eng. Chem. Res., 52, 14855, 2013
  34. Ibrahim T, Habbab M, Int. J. Electrochem. Sci., 6, 5357, 2011
  35. Al Hasan NHJ, Alaradi HJ, Al Mansor ZAK, Al Shadood AHJ, Case Stud. Constr. Mater., 11, e00300, 2019
  36. Odusote JK, Owalude DO, Olusegun SJ, Yahya RA, West Indian J. Eng., 38, 64, 2016
  37. Verma C, Ebenso EE, Bahadur I, Quraishi MA, J. Mol. Liq., 266, 577, 2018
  38. Begum AAS, Vahith RMA, Kotra V, Shaik MR, Abdelgawad A, Awwad EM, Khan M, Coatings, 11, 106, 2021
  39. Shukla SK, Singh AK, Murulana LC, Kabanda MM, Ebenso EE, Int. J. Electrochem. Sci., 7, 5057, 2012
  40. Saxena A, Sharma V, Thakur KK, Bhardwaj N, J. Bio. Tribo. Corros., 6, 41, 2020
  41. Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M, J. Ind. Eng. Chem., 84, 52, 2020
  42. Ekere I, Agboola O, Sanni SE, J. Phys. Conf. Ser., 1378, 022049, 2019
  43. Harb MB, Abubshait S, Etteyeb N, Kamoun M, Dhouib A, Arabian J. Chem., 13, 4846, 2020
  44. Saeed MT, Saleem M, Usmani S, Malik IA, Al-Shammari FA, Deen KM, J. King Saud Univ. Sci., 31, 1344, 2019
  45. Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M, J. Mol. Liq., 255, 185, 2018
  46. Krishnegowda PM, Venkatesha VT, Kumar MP, Krishnegowda, Shivayogiraju SB, Ind. Eng. Chem. Res., 52, 722, 2013
  47. Sanaei Z, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, J. Ind. Eng. Chem., 69, 18, 2019
  48. Umoren SA, Gasem ZM, Obot IB, Ind. Eng. Chem. Res., 52, 14855, 2013
  49. de Souza FS, Spinelli A, Corrosion Sci., 51, 642, 2009
  50. Krishnan A, Krishnan AV, Ajith A, Shibli SMA, Surf. Interfaces, 25, 101238, 2021
  51. Abdel-Gaber AM, Rahal HT, Beqai FT, Int. J. Ind. Chem., 11, 123, 2020
  52. Tezeghdenti M, Dhouibi L, Etteyeb N, J. Bio. Tribol. Corros., 1, 16, 2018
  53. Kalaiselvi K, Chung IM, Kim SH, Prabakaran M, Anti-Corros. Method, 65, 408, 2018
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.