About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.39, No.4, 1011-1019, 2022
Selective separation of gallium from various ions by polymer inclusion membranes based on CTA/PVC blend using TOPO as carrier
Tutkun O, Kaparova K
Selective transport of gallium from HCl media containing other ions such as Zn, Co, and Ni, by polymer inclusion membranes (PIM), based on CTA/PVC blend using trioctylphosphine oxide (TOPO) as carrier and 2-nitrophenylpentyl ether (2-NPPE) as plasticizer is studied. The effect of various parameters such as the HCl concenration in the feed, HCl concenration in the stripping phase, carrier (TOPO) concentration, 2-NPPE concentration, the cellulose triacetate (CTA)/poly(vinyl chloride) (PVC) as the polymer-blend was experimentally studied and the optimum conditions were determined. It was possible to selectively extract gallium ions from the ions (Zn, Co, and Ni) in the acidic solutions. The separation factors of gallium over Zn, Co, and Ni, at the optimum conditions, were found to be of 963, 702, and 514, respectively, for the feed solution of 100mg/dm3 Ga, 1,000mg/dm3 Zn, 600mg/dm3 Co, and 600mg/dm3 Ni.
Keywords: Polymer Inclusion Membranes; Gallium Separation; Trioctyl Phosphine Oxide (TOPO); CTA-PVC Blend; Membranes; Separation Factor
[References]
  1. Gupta B, Mudhar N, Begum IZ, Singh I, Hydrometallurgy, 87, 18, 2007
  2. Moskalyk RR, Miner. Eng., 16(10), 921, 2003
  3. Mihaylov I, Distin PA, Hydrometallurgy, 28, 13, 1992
  4. Abisheva ZS, Blaida IA, Ponomareva EI, Rozen AM, Hydrometallurgy, 37, 393, 1995
  5. Raiguel S, Dehaen W, Binnemans K, Dalton Transact., 49(11), 3532, 2020
  6. de San Miguel ER, Aquilar JC, Rodriguez MTC, de Gyves J, Hydrometallurgy, 57, 151, 2000
  7. Ahmed IM, El-Nadi YA, El-Hefni NE, Hydrometallurgy, 131-132, 24, 2013
  8. Lee MS, Ahn JG, Lee EC, Hydrometallurgy, 63, 269, 2002
  9. Zhang X, Yin G, Hu Z, Talanta, 59, 905, 2003
  10. Chen WS, Huang SH, Chang FC, Chang JE, Wang YN, Desal. Water Treatment, 54, 1452, 2015
  11. Ahmed IM, Ismail ZH, Hamed MM, J. Radioanal. Nucl. Chem., 317(2), 969, 2018
  12. Assadian A, Ahmadi A, Mineral. Eng., 148, 106207, 2020
  13. Draxler J, Marr RJ, Chem. Eng. Process., 20, 319, 1986
  14. Parthasarathy N, Pelletier M, Buffle J, Anal. Chim. Acta, 35, 183, 1997
  15. Alguacil FJ, Revista de Metalurgia, 38(6), 419, 2002
  16. Alizadeh N, Salimi S, Jabbari A, Sep. Purif. Technol., 28, 173, 2002
  17. Kumbasar RA, Tutkun O, Hydrometallurgy, 75(1-4), 111, 2004
  18. Kumbasar RA, Tutkun O, Sep. Sci. Technol., 41(12), 2825, 2006
  19. Zhang XJ, Liu JH, Lu TS, Water Treatment, 2, 127, 1987
  20. Draxler J, Fürst W, Marr RJ, J. Membr. Sci., 38, 281, 1988
  21. Kolev SD, in Encyclopedia of analytical science, Worsfold P, Townshend A, Poole C eds., Elsevier, Amsterdam (2005).
  22. St John AM, Cattrall RW, Kolev SD, J. Membr. Sci., 364(1-2), 354, 2010
  23. Nghiem LD, Mornane P, Potter ID, Perera JM, Cattrall RW, Kolev SD, J. Membr. Sci., 281, 7, 2006
  24. Gherasim CVI, Bourceanu G, Olariu RI, Arsene C, J. Membr. Sci., 377, 67, 2011
  25. Kagaya S, Cattrall RW, Kolev SD, Anal. Sci., 27, 653, 2011
  26. Abdellaoui N, Arous O, Macromol. Symp., 386(1), 20180024, 2019
  27. Sellami F, Kebiche-Senhadji O, Marais S, Couvrat N, Fatyeyeva K, React. Funct. Polym., 139, 120, 2019
  28. Hasegawa Y, Shimada T, Nitsu M, J. Inorg. Nucl. Chem., 42, 1487, 1980
  29. Yamamoto K, Katoh N, Anal. Sci., 15, 1013, 1999
  30. Sato T, Nakamura T, Ishikawa S, Solvent Extr. Ion. Exch., 2(2), 201, 1984
  31. Gutierrez B, Pazos C, Coca J, J. Chem. Tech. Biotechnol., 61, 241, 1994
  32. Judin V, Bautista RG, Metallurgical Trans. B, 17B, 259, 1986
  33. Fujinawa K, Akiyama M, Shono A, Imaishi N, Hozawa M, Kagaku Kogaku Ronbunshu, 15, 381, 1989
  34. Kirgios I, Schügerl K, Degener W, US Patent, 5,326,441 (1994).
  35. Kusumocahyo SP, Kanamori T, Sumaru K, Aomatsu S, Matsuyama H, Teramoto M, Shinbo T, J. Membr. Sci., 244, 251, 2004
  36. Kebiche-Senhadji O, Tingry S, Seta P, Benamor M, Desalination, 258, 59, 2010
  37. Pospiech B, Sep. Sci. Technol., 47(9), 1413, 2012
  38. Mohebali S, Nazari M, Rahbar-Kelishami A, Davoodi-Nasab P, Desal. Water Treat., 64, 173, 2017
  39. Zidi C, Tayeb R, Dhahbi M, J. Hazard. Mater., 194, 62, 2011
  40. Yildiz Y, Manzak A, Tutkun O, Desal. Water Treat., 57(10), 4616, 2016
  41. Meng X, Gao C, Wang L, Wang X, Tang W, J. Membr. Sci., 493, 615, 2015
  42. Venkateswaran P, Navaneetha A, Palanivelu K, J. Environ. Sci., 19, 1446, 2007
  43. Kozlowski CA, Walkowiak W, J. Membr. Sci., 266, 143, 2005
  44. Kozlowski CA, Walkowiak W, Water Res., 36, 4870, 2002
  45. Baczynska M, Regel-Rosocka M, Nowicki M, Wisniewski M, J. Appl. Polym. Sci., 132(30), 42319, 2015
  46. de San Miguel ER, Garduno-Garcia AV, Aguilar JC, de Gyves J, Ind. Eng. Chem. Res., 46, 2861, 2007
  47. Haghighi HK, Irannajad M, Moradkhani D, Physicochem. Probl. Miner. Process., 55(1), 225, 2019
  48. Rehman S, Akhtar G, Chaudry MA, Ali K, Ullah N, J. Membr. Sci., 389, 287, 2012
  49. Kusumocahyo SP, Sumaru K, Iwatsubo T, Shinbo T, Kanamori T, Matsuyama H, Teramoto M, J. Membr. Sci., 280(1-2), 73, 2006
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.