Korean Journal of Chemical Engineering, Vol.39, No.2, 440-450, 2022
Hydrothermal synthesis and characterization of quartz nanocrystals - Implications from a simple kinetic growth model
Obtaining quartz nanocrystals (NCs) of high purity and uniform sizes remains a challenging problem. In this report, the synthesis and characterization of quartz NCs under hydrothermal conditions was investigated and the corresponding mathematical models were introduced to elucidate the growth kinetics of quartz NCs. Amorphous silica nanoparticles were dissolved in aqueous solutions followed by mild hydrothermal reactions, resulting in NCs with relatively uniform sizes and shapes. The NCs were made from highly crystalline α-quartz. Their hydrothermal growth process over an induction period of ~3 hr initially yielded amorphous silica nanoparticles that were aggregated into clusters. The crystallinity of α-quartz emerged from the products of the nanoparticle clusters after the induction period, which likely involved an amorphous to crystalline transition. The NCs continued to grow with increasing time. The growth kinetics exhibited a dependence on the square root of time, which has not been observed for other quartz nanocrystalline systems. The analysis suggests that the process is reaction-limited, not diffusion-limited, likely governed by the dissolved silicate monomer flux to the surface of the growing NCs followed by first-order rate-limiting attachment kinetics. This study highlights the growth kinetics of quartz NCs by unveiling the complex nature of multistep growth processes, offering an improved hydrothermal method for fine-tuning the size and morphology of quartz NCs, which have potential optoelectronics, sensing, and rechargeable battery, and novel biorefinery process applications.
[References]
Deng H, Yin J, Ma J, Zhou J, Zhang L, Gao L, Jiao T, Appl. Surf. Sci. , 543 , 148821, 2021
Geng R, Chang R, Zou Q, Shen G, Jiao T, Yan X, Small , 17 , 200811, 2021
Qian C, Yin J, Zhao J, Li X, Wang S, Bai Z, Jiao T, Colloids Surf. A: Physicochem. Eng. Asp. , 610 , 125752, 2021
Xu Y, Wang R, Wang J, Li J, Jiao T, Liu Z, Chem. Eng. J. , 417 , 129233, 2021
Hyde Emily D. E. R., Seyfaee Ahmad, Neville Frances, Moreno-Atanasio Roberto, Ind. Eng. Chem. Res. , 55 (33), 8891, 2016
Jang EH, Pack SP, Kim I, Chung S, Sci. Rep. , 10 , 5558, 2020
Qiao G, Liu L, Hao X, Zheng J, Liu W, Gao J, Zhang CC, Wang Q, Chem. Eng. J. , 382 , 122907, 2020
Zhou Z, Zheng Y, Gao J, Jiang L, Wang Q, J. Sol-Gel Sci. Technol. , 77 , 205, 2016
Pagliaro M, Silica-based materials for advanced chemical applications, Royal Society of Chemistry (2009).
Mason B, Berry LG, Elements of mineralogy, W. H. Freeman, San Francisco (1968).
Vatalis KI, Charalambides G, Benetis NP, Procedia Econ. Financ. , 24 , 734, 2015
Ballato A, in Piezoelectricity: Evolution and future of a technology, Berlin Heidelberg, Berlin, Heidelberg (2008).
Saigusa Y, in Advanced piezoelectric materials (second edition), K. Uchino, Ed., Woodhead Publishing (2017).
Yoder CH, in Ionic compounds: Applications of chemistry to mineralogy, Wiley (2006).
Spearing DR, Farnan I, Stebbins JF, Phys. Chem. Miner. , 19 , 307, 1992
Bettermann P, Liebau F, Contrib. Mineral Petrol. , 53 , 25, 1975
Fyfe WS, McKay DS, Am. Mineral. , 47 , 83, 1962
Jung YH, Pack SP, Chung S, Mater. Res. Bull. , 101 , 67, 2018
Liu J, Wang L, Wang J, Zhang LT, Mater. Res. Bull. , 48 (2), 416, 2013
Wang X, Zhuang J, Peng Q, Li YD, Nature , 437 , 121, 2005
Yoshimura M, Byrappa K, J. Mater. Sci. , 43 (7), 2085, 2008
Byrappa K, Keerthiraj N, Byrappa SM, in Handbook of crystal growth, P. Rudolph, Ed., Elsevier, Boston (2015).
Cambon O, Haines J, Crystals , 7 , 38, 2017
Hervey PR, Foise JW, Min. Metall. Explor. , 18 , 1, 2001
Johnson G, Foise J, in Encyclopedia of applied physics, VCH Publishers (1996).
Bertone JF, Cizeron J, Wahi RK, Bosworth JK, Colvin VL, Nano Lett. , 3 , 655, 2003
Buckley P, Hargreaves N, Cooper S, Commun. Chem. , 1 , 49, 2018
Jiang XM, Jiang YB, Brinker CJ, Chem. Commun. , 47 , 7524, 2011
Moon GS, Chung SW, Appl. Chem. Eng. , 31 (6), 697, 2020
Moon G, Lee N, Kang S, Park J, Kim YE, Lee SA, Chitumalla RK, Jang J, Choe Y, Oh YK, Chung S, Chem. Eng. J. , 413 , 127467, 2021
Finnegan MF, Zhang H, Banfield JF, Chem. Mater. , 20 , 3443, 2008
Laudise R, J. Am. Chem. Soc. , 81 , 562, 1959
Michibayashi K, Imoto H, Phys. Chem. Miner. , 39 , 213, 2012
Moxon T, Carpenter M, Mineral. Mag. , 73 , 551, 2009
de Ruijter WJ, Sharma R, McCartney MR, Smith DJ, Ultramicroscopy , 57 , 409, 1995
Malm JO, O'Keefe MA, Ultramicroscopy , 68 , 13, 1997
Ihinger PD, Zink SI, Nature , 404 (6780), 865, 2000
Smith GS, Alexander LE, Acta Crystallogr. , 16 , 462, 1963
Wei PH, Z Kristallogr , 92 , 355, 1935
Takeuchi M, Martra G, Coluccia S, Anpo M, J. Near Infrared Specrosc. , 17 , 373, 2009
Barr TL, Appl. Surf. Sci. , 15 , 1, 1983
Post P, Wurlitzer L, Maus-Friedrichs W, Weber AP, Nanomater. , 8 , 530, 2018
Holder CF, Schaak RE, ACS Nano , 13 , 7359, 2019
Balbuena PB, Gubbins KE, Langmuir , 9 , 1801, 1993
Sing KSW, Pure Appl. Chem. , 57 , 603, 1985
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW, Pure Appl. Chem. , 87 , 1051, 2015
Bullen CR, Mulvaney P, Nano Lett. , 4 , 2303, 2004
LaMer V, Ind. Eng. Chem. , 44 , 1270, 1952
LaMer VK, Dinegar RH, J. Am. Chem. Soc. , 72 , 4847, 1950
Lee DK, Park SI, Lee JK, Hwang NM, Acta Mater. , 55 , 5281, 2007
Lifshitz IM, Slyozov VV, J. Phys. Chem. Solids , 19 , 35, 1961
Lin X, Sorensen C, Klabunde K, J. Nanopart. Res. , 2 , 157, 2000
Peng XG, Wickham J, Alivisatos AP, J. Am. Chem. Soc. , 120 (21), 5343, 1998
Reiss H, J. Chem. Phys. , 19 , 482, 1951
Robb DT, Privman V, Langmuir , 24 (1), 26, 2008
Saunders AE, Sigman MB, Korgel BA, J. Phys. Chem. B , 108 (1), 193, 2004
Sugimoto T, Adv. Colloid Interface Sci. , 28 , 65, 1987
Talapin DV, Rogach AL, Haase M, Weller H, J. Phys. Chem. B , 105 (49), 12278, 2001
Wagner C, Z. Elektrochem. , 65 , 581, 1961
Rempel JY, Bawendi MG, Jensen KF, J. Am. Chem. Soc. , 131 (12), 4479, 2009
Wang F, Richards VN, Shields SP, Buhro WE, Chem. Mater. , 26 , 5, 2014
Viswanatha R, Sarma DD, in Nanomaterials chemistry: Recent developments and new directions, Wiley-VCH Verlag GmbH & Co. KgaA (2007).
Ostwald W, Phys. Chem. , 37 , 385, 1901
Perez M, Scr. Mater. , 52 , 709, 2005
Tyrrell H, J. Chem. Educ. , 41 , 397, 1964
Laudise RA, Chem. Eng. News , 65 , 30, 1987
Rebreanu L, Vanderborght JP, Chou L, Mar. Chem. , 112 , 230, 2008
Chen YF, Johnson E, Peng XG, J. Am. Chem. Soc. , 129 (35), 10937, 2007
Drofenik M, Kristl M, Znidarsic A, Hanzel D, Lisjak D, J. Am. Ceram. Soc. , 90 (7), 2057, 2007
Jana NR, Peng XG, J. Am. Chem. Soc. , 125 (47), 14280, 2003
Ji XH, Song XN, Li J, Bai YB, Yang WS, Peng XG, J. Am. Chem. Soc. , 129 (45), 13939, 2007
Meli L, Green PF, ACS Nano , 2 , 1305, 2008
Morales MP, Gonzalez-Carreno T, Serna CJ, J. Mater. Res. , 7 , 2538, 1992
Murray CB, Norris DJ, Bawendi MG, J. Am. Chem. Soc. , 115 , 8706, 1993
Owen JS, Chan EM, Liu HT, Alivisatos AP, J. Am. Chem. Soc. , 132 (51), 18206, 2010
Qu L, Yu WW, Peng X, Nano Lett , 4 , 465, 2004
Stoeva S, Klabunde KJ, Sorensen CM, Dragieva I, J. Am. Chem. Soc. , 124 (10), 2305, 2002
Thessing J, Qian JH, Chen HY, Pradhan N, Peng XG, J. Am. Chem. Soc. , 129 (10), 2736, 2007
Zheng N, Fan J, Stucky GD, J. Am. Chem. Soc. , 128 (20), 6550, 2006
Seshadri R, Subbanna GN, Vijayakrishnan V, Kulkarni GU, Ananthakrishna G, Rao CN, J. Phys. Chem. , 99 (15), 5639, 1995
Westcott SL, Oldenburg SJ, Lee TR, Halas NJ, Langmuir , 14 (19), 5396, 1998
Xiao JY, Qi LM, Nanoscale , 3 , 1383, 2011
Lin L, Chen M, Qin HY, Peng XG, J. Am. Chem. Soc. , 140 (50), 17734, 2018
Shankar R, Wu BB, Bigioni TP, J. Phys. Chem. C , 114 , 15916, 2010
Ruditskiy A, Zhao M, Gilroy KD, Bara M, Xia Y, Chem. Mater. , 28 , 8800, 2016
Wong EM, Bonevich JE, Searson PC, J. Phys. Chem. B , 102 (40), 7770, 1998
Viswanatha R, Sapra S, Satpati B, Satyam PV, Dev BN, Sarma DD, J. Mater. Chem. , 14 , 661, 2004
Cheong S, Watt J, Ingham B, Toney MF, Tilley RD, J. Am. Chem. Soc. , 131 (40), 14590, 2009
Viswanatha R, Amenitsch H, Sarma DD, J. Am. Chem. Soc. , 129 (14), 4470, 2007
Yao LY, Zhu YX, Liu CQ, Jiao RH, Lu YH, Tan RX, J. Chromatogr. B , 989 , 122, 2015
Woehl TJ, Chem. Mater. , 32 , 7569, 2020
Zhang J, Huang F, Lin Z, Nanoscale , 2 , 18, 2010
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