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Issue
Korean Journal of Chemical Engineering,
Vol.39, No.1, 216-226, 2022
Kinetics, isothermal and mechanistic insight into the adsorption of eosin yellow and malachite green from water via tri-metallic layered double hydroxide nanosheets
Nazir MA, Najam T, Bashir MS, Javed MS, Bashir MA, Imran M, Azhar U, Shah SSA, Rehman AU
The use of highly efficient, environment-friendly and economically inexpensive materials for the adsorption removal of contaminants from water has always been considered as emerging task. In this study, we synthesized hybrid tri-metallic nickel cobalt layered double hydroxide (NiCoAl-LDH) porous material for the adsorption removal of Eosin yellow (EY) and Malachite green (MG) from water. The characterization results disclosed that tri-metallic LDH has been synthesized with extraordinary purity, identical morphology and high surface area (134.21 m2ㆍg-1). The NiCoAl-LDH performs the best for adsorption of EY (qe=37.30mgㆍg-1 at pH=2) and MG (qe=39.61 mgㆍg-1 at pH= 10). The Langmuir and Freundlich isotherm models were applied to explain the adsorption process of dyes on the surface of LDH. The Langmuir model (R2=0.991 and 0.999 for Eosin Y and Malachite G, respectively) was very appropriate to explain the process of adsorption on NiCoAl-LDH as homogeneous (monolayer). The maximum adsorption capacity of EY and MG calculated with Langmuir model was 78.74 and 110.13mgㆍg-1 at 30 °C, respectively. Also with 240 minutes contact time 94.8% EY and 89.9% MG was adsorbed by as synthesized NiCoAl-LDH nanosheets. The NiCoAl-LDH nanosheets showed excellent performance of reusability of up to five regeneration cycles. The results showed that the adsorption capacity of NiCoAl-LDH nanosheets after five regeneration cycles, to adsorb EY, decreased only from 40.80 to 36.93mgㆍg-1 and that of MG from 79.21 to 75.42mgㆍg-1, which is acceptable. The overall results Suggest that the fabricated NiCoAl-LDH is favorable for the purification of dye contaminated water.
Keywords: LDH; Layered Double Hydroxide; NiCoAl-LDH; Eosin Yellow; Malachite Green; Dye Adsorption; Purification of Water
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