About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.39, No.1, 146-160, 2022
Date seed activated carbon decorated with CaO and Fe3O4 nanoparticles as a reusable sorbent for removal of formaldehyde
Khaleghi H, Esmaeili H, Jaafarzadeh N, Ramavandi B
Activated carbon (AC) was produced from date seeds by a calcination process at 700 °C. for 2 h and then its surface was improved with CaO and magnetic nanoparticles. AC/CaO/Fe3O4 nanocomposite was then employed to remove formaldehyde ions from aqueous media. The structural characteristics of the materials were completely studied through FT-IR, XRD, SEM, EDX, Map, VSM, BET and TEM analyses. The results showed that the nanocomposite has a mesoporous structure (average pore diameter~13 nm) with great sorption capability. Also, the utmost removal efficiency of formaldehyde using AC, AC/Fe3O4, CaO/Fe3O4 and AC/Fe3O4/CaO nanocomposite was 94.73, 95.67, 95.14 and 98.22%, respectively, indicating that the removal efficiency increases by improving the surface properties of the AC. Moreover, the uptake of formaldehyde using AC/Fe3O4/CaO nanocomposite follows the Freundlich isotherm and pseudo-2nd-order kinetic models. Furthermore, the highest sorption capacity of AC, AC/Fe3O4, CaO/Fe3O4 and AC/ Fe3O4/CaO nanocomposite using the Langmuir model was obtained 19.86, 24.21, 21.28 and 24.01mg/g, respectively. The thermodynamic study showed that formaldehyde sorption using all four adsorbents is exothermic and spontaneous. The reusability of the adsorbents was also evaluated after ten reuse cycles and the outcomes indicated that these four adsorbents have significant reusability. Moreover, the impact of interfering ions (e.g., carbonate, sulfate, phosphate, nitrate and chloride) showed that all of these compounds, except nitrate, had little competition with formaldehyde ions for adsorption on the nanocomposite surface.
Keywords: Date Seed Activated Carbon; Formaldehyde; Magnetic Nanoparticles; Wastewater Treatment
[References]
  1. Chen YZ, He L, Li J, Zhang SY, Comput. Chem. Eng., 109, 216, 2018
  2. He L, Chen Y, Li J, Resour. Conserv. Recycl., 133, 206, 2018
  3. Zvulunov Y, Ben-Barak-Zelas Z, Fishman A, Radian A, Chem. Eng. J., 374, 1275, 2019
  4. Paliulis D, Pol. J. Environ. Stud., 25, 251, 2016
  5. Arsawiset S, Teepoo S, Analytica Chim. Acta, 1118, 63, 2020
  6. Wang H, Song T, Li Z, Qiu J, Zhao Y, Zhang H, Wang J, ACS Appl. Mater. Interfaces, 13, 25918, 2021
  7. Wang X, Fang Z, Xiao B, Zhao J, Ma H, Tian Y, Pang Tan L, Green Chem., 22, 6157, 2020
  8. Bahador F, Foroutan R, Esmaeili H, Ramavandi B, Carbohydr. Polym., 251, 117085, 2021
  9. Zhang T, Wu X, Shaheen SM, Rinklebe J, Bolan NS, Ali EF, Li G, Tsang DC, J. Hazard. Mater., 416, 125738, 2021
  10. Vellingiri K, Vikrant K, Kumar V, Kim KH, Chem. Eng. J., 399, 125759, 2020
  11. Zhu XB, Gao X, Qin R, Zeng YX, Qu RY, Zheng CH, Tu X, Appl. Catal. B: Environ., 170, 293, 2015
  12. Zhang X, Sun X, Lv T, Weng L, Chi M, Shi J, Zhang S, J. Mater. Sci. Mater. Electron., 31, 13344, 2020
  13. Yuan D, Tian L, Gu D, Shen X, Zhu L, Wu H, Wang B, J. Clean Prod., 156, 310, 2017
  14. Soltani RDC, Rezaee A, Safari M, Khataee AR, Karimi B, Desalin. Water Treat., 53, 1613, 2015
  15. Xing B, Yang G, Chen H, Liu X, React. Kinet. Mech. Catal., 126, 547, 2019
  16. Talaiekhozani A, Salari M, Talaei MR, Bagheri M, Eskandari Z, J. Environ. Manage., 184, 204, 2016
  17. Sarabadan M, Bashiri H, Mousavi SM, Korean J. Chem. Eng., 36(10), 1575, 2019
  18. Mahmoodi F, Darvishi P, Vaferi B, J. Iran. Chem. Soc., 15, 2747, 2018
  19. Ma C, Zhang X, Wen K, Wang R, Han R, Korean J. Chem. Eng., 38(1), 135, 2021
  20. Tech JET, J. Environ. Treat. Tech., 2, 12, 2014
  21. Wang K, Zhao J, Li H, Zhan GX, Shi H, J. Taiwan Inst. Chem. Eng., 61, 287, 2016
  22. Khamkeaw A, Phisalaphong M, Jongsomjit B, Lin KYA, Yip AC, J. Hazard. Mater., 384, 121161, 2020
  23. Salman M, Athar M, Shafique U, Rehman R, Ameer S, Ali SZ, Azeem M, Turkish J. Eng. Environ. Sci., 36, 263, 2012
  24. Bellat JP, Weber G, Bezverkhyy I, Lamonier JF, Microporous Mesoporous Mater., 288, 109563, 2019
  25. Bellat JP, Bezverkhyy I, Weber G, Royer S, Averlant R, Giraudon JM, Lamonier JF, J. Hazard. Mater., 300, 711, 2015
  26. Ma C, Zhang X, Wen K, Wang R, Han R, Korean J. Chem. Eng., 38(1), 135, 2021
  27. Syafiqah I, Yussof HW, Water Conserv. Manag., 2, 10, 2018
  28. Seffati K, Esmaeili H, Honarvar B, Esfandiari N, Renew. Energy, 147, 25, 2020
  29. Alsultan A, Mijan A, Taufiq-Yap YH, Mater. Sci. Forum, 840, 348, 2016
  30. Liou TH, Wang PY, Liou YH, BioResources, 11, 6110, 2016
  31. Zhou C, Ding D, Zhu W, Chang X, Zhang T, Wu H, Yang H, Sun L, Appl. Surf. Sci., 520, 146324, 2020
  32. Takada T, Nano Biomedicine, 3, 282, 2011
  33. Wang L, Wu Y, Liu S, Zhang Y, Chen Y, Ma H, Zhu Z, Zhou J, BioResources, 14, 7193, 2019
  34. He L, Chen Y, Zhao H, Tian P, Xue Y, Chen L, Sci. Total Environ., 627, 1585, 2018
  35. Cheng X, He L, Lu H, Chen Y, Ren L, J. Hydrol., 540, 412, 2016
  36. Boushehrian MM, Esmaeili H, Foroutan R, J. Environ. Chem. Eng., 8, 103869, 2020
  37. Bougdah N, Messikh N, Bousba S, Djazi F, Magri P, Rogalski M, Curr. Res. Green Sustain. Chem., 3, 100038, 2020
  38. Takmil F, Esmaeili H, Mousavi SM, Hashemi SA, Adv. Powder Technol., 31(8), 3236, 2020
  39. Esmaeili H, Foroutan R, Jafari D, Rezaei MA, Korean J. Chem. Eng., 37(5), 804, 2020
  40. Yildirim A, Bulut Y, Environ. Technol. Innov., 17, 100560, 2020
  41. Keshtkar Z, Tamjidi S, Vaferi B, Environ. Technol. Innov., 22, 101439, 2021
  42. Ahmadi A, Foroutan R, Esmaeili H, Tamjidi S, Environ. Sci. Pollut. Res., 27, 14044, 2020
  43. Albuquerque MCG, Azevedo DCS, Cavalcante CL, Santamaria-Gonzalez J, Merida-Robles JM, Moreno-Tost R, Rodriguez-Castellon E, Jimenez-Lopez A, Maireles-Torres P, J. Mol. Catal. A-Chem., 300(1-2), 19, 2009
  44. Mousavi AA, Zhang C, Masri SF, Gholipour G, Struct. Health Monit. (2021).
  45. Yao SH, Zhang JJ, Shen DK, Xiao R, Gu S, Zhao M, Liang JY, J. Colloid Interface Sci., 463, 118, 2016
  46. Wang Z, Zhong M, Chen L, Desalin. Water Treat., 57, 13225, 2016
  47. Zhang L, Zhang M, You S, Ma D, Zhao J, Chen Z, Sci. Total Environ., 780, 146505, 2021
  48. Bagheri AR, Ghaedi M, Asfaram A, Bazrafshan AA, Jannesar R, Ultrason. Sonochem., 34, 294, 2017
  49. Ni Z, Cao X, Wang X, Zhou S, Zhang C, Xu B, Ni Y, Coatings, 11, 749, 2021
  50. Taghizadeh F, Ghaedi M, Kamali K, Sharifpour E, Sahraie R, Purkait MK, Powder Technol., 245, 217, 2013
  51. Zhang M, Zhang L, Tian S, Zhang X, Guo J, Guan X, Xu P, Chemosphere, 253, 126638, 2020
  52. Ghanbari S, Vaferi B, Acta Astronaut., 112, 19, 2015
  53. Arivoli S, Hema M, Parthasarathy S, Manju N, J. Chem. Pharm. Res., 2, 262, 2010
  54. Zhang K, Huo Q, Zhou YY, Wang HH, Li GP, Wang YW, Wang YY, ACS Appl. Mater. Interfaces, 11, 17368, 2019
  55. Zhang L, Zheng J, Tian S, Zhang H, Guan X, Zhu S, Zhang X, Bai Y, Xu P, Zhang J, Li Z, J. Environ. Sci., 91, 212, 2020
  56. Vaferi B, Bahmani M, Keshavarz P, Mowla D, J. Environ. Chem. Eng., 2, 1252, 2014
  57. Li B, Wu H, Zhang C, Zheng W, Sun D, Lei S, Desalin. Water Treat., 165, 148, 2019
  58. Prasad R, Yadav KD, Water Conserv. Manag., 4, 83, 2021
  59. Zafisah NS, Ang WL, Mohammad AW, Water Conserv. Manag., 2, 5, 2018
  60. Mohseni-Bandpi A, Al-Musawi TJ, Ghahramani E, Zarrabi M, Mohebi S, Abdollahi Vahed S, J. Mol. Liq., 218, 615, 2016
  61. Esmaeili H, Tamjidi S, Environ. Sci. Pollut. Res., 27, 31652, 2020
  62. Awual MR, Khraisheh M, Alharthi NH, Luqman M, Islam A, Karim MR, Rahman MM, Khaleque MA, Chem. Eng. J., 343, 118, 2018
  63. Banu HT, Meenakshi S, J. Water Process Eng., 16, 81, 2017
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.