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Issue
Korean Journal of Chemical Engineering,
Vol.38, No.6, 1161-1169, 2021
Cascade conversion of glucose to 5-hydroxymethylfurfuralover Bronsted-Lewis bi-acidic SnAl-beta zeolites
An HJ, Kweon SJ, Kang DC, Shin CH, Kim JF, Park MB, Min HK
The control of acidic properties in a catalyst is one of the key features of technology utilizing biomass for chemical production. In this study, the Bronsted and Lewis bi-acidic SnAl-beta zeolites with controllable acidity were successfully prepared by acid dealumination and isomorphic substitution of Al by Sn, and applied for the cascade conversion of glucose to 5-hydroxymethylfurfural (5-HMF). The Lewis acidity of the catalysts was increased as the higher concentration of nitric acid used for the dealumination process. The optimum portion of Lewis/(Bronsted+Lewis) ratio was investigated to maximize the yield of 5-HMF, which is converted from the glucose via fructose by the cascade reaction. The conversion of glucose was increased until the L/(B+L) ratio reached 0.89 and the selectivity to 5-HMF reached its maximum at the Lewis acid portion of 0.76 among the total acid sites.
Keywords: Beta Zeolite; Glucose Conversion; Cascade Reaction; 5-Hydroxymethylfurfural; Bi-acidic Catalysts
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