About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
  Guidelines for Publication
  Ethics
Articles & Issues
  Search
  Issue
  Online First
  KJChE on
For Authors
  Instructions to Authors
  Ethical Responsibilities of
  Authors in KJChE
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
Issue
Korean Journal of Chemical Engineering,
Vol.38, No.5, 1032-1042, 2021
Fabrication of hydrophobic ZIFs based composite membrane with high CO2 absorption performance
Xu L, Qin Y, Liu L, Xiao J, Ding Z
The membrane contactor has been considered an effective device to capture CO2, but its performance is limited by membrane wetting phenomena. In this work, the ZIF-8/ZIF-L (zeolitic imidazolate framework) based composite membrane with excellent hydrophobic stability and CO2 permeability was successfully fabricated by coating the dense layer on the porous PVDF (polyvinylidene fluoride) substrate. The dense layer was developed by evenly incorporating ZIF-8 nanocrystals and ZIF-L nanosheets into the polydimethylsiloxane (PDMS) polymer. The as-prepared membrane possessed competitive hydrophobicity with a water contact angle (WCA) of 131.8o. And after a ten-day immersion test in CO2 absorbent, the WCA only declined by 9.8%, exhibiting excellent hydrophobic stability. Besides, the CO2 permeability of the composite membrane was 61.8 X10-8ㆍmolㆍm-2ㆍs-1ㆍPa-1 with an ideal CO2/N2 separation factor of ~20, which was effectively improved in comparison with the control membrane. In the CO2 absorption experiment, the prepared membrane achieved the competitive CO2 flux of 3.02X10-3ㆍmolㆍm-2ㆍs-1 when the liquid velocity was 0.25mㆍs-1 and displayed robust long-term operating stability. Finally, the AC impedance technique was applied to continuously monitor the wetting state of composite membranes, which further investigated their anti-wetting ability.
Keywords: Hydrophobic Composite Membrane; Zeolitic Imidazolate Frameworks (ZIFs); CO2 Absorption; Membrane Wetting; Membrane Contactor
[References]
  1. Scholes CA, Kentish SE, Stevens GW, Jin JY, deMontigny D, Sep. Purif. Technol., 156, 841, 2015
  2. Qi Z, Cussler EL, J. Membr. Sci., 23, 321, 1985
  3. Nii S, Takeuchi H, Takahashi K, J. Chem. Eng. Jpn., 25, 67, 1992
  4. Karoor S, Sirkar KK, Ind. Eng. Chem. Res., 32, 674, 1993
  5. NII S, TAKEUCHI H, Gas Sep. Purif., 8(2), 107, 1994
  6. Demontigny D, Tontiwachwuthikul P, Chakma A, J. Membr. Sci., 277(1-2), 99, 2006
  7. Sedghi SM, Brisson J, Rodrigue D, Iliuta MC, Sep. Purif. Technol., 80(2), 338, 2011
  8. Keshavarz R, Fathikalajahi J, Ayatollahi S, J. Hazard. Mater., 152(3), 1237, 2008
  9. Khaisri S, Demontigny D, Tontiwachwuthikul P, Jiraratananon R, Sep. Purif. Technol., 65(3), 290, 2009
  10. Rajabzadeh S, Yoshimoto S, Teramoto M, Al-Marzouqi M, Matsuyama H, Sep. Purif. Technol., 68, 210, 2009
  11. Zhang HY, Wang R, Liang DT, Tay JH, J. Membr. Sci., 308(1-2), 162, 2008
  12. Mosadegh-Sedghi S, Rodrigue D, Brisson J, Iliuta MC, J. Membr. Sci., 452, 332, 2014
  13. Dai ZD, Ansaloni L, Deng LY, Ind. Eng. Chem. Res., 55(20), 5983, 2016
  14. Scholes CA, Kentish SE, Stevens GW, deMontigny D, Int. J. Greenh. Gas Control., 42, 66, 2015
  15. Li K, Zeng X, Li H, Lai X, Ye C, Xie H, Appl. Surf. Sci., 279, 458, 2013
  16. Rosli A, Ahmad AL, Low SC, Sep. Purif. Technol., 221, 275, 2019
  17. Yao J, Wang H, Chem. Soc. Rev., 43, 4470, 2014
  18. Song Q, Nataraj SK, Roussenova MV, Tan JC, Hughes DJ, et al., Energy Environ. Sci., 5, 8359, 2012
  19. Xu YL, Li X, Lin YQ, Malde C, Wang R, J. Membr. Sci., 585, 238, 2019
  20. Fan H, Shi Q, Yan H, Ji S, Dong J, Zhang G, Angew. Chem.-Int. Edit., 53, 5578, 2014
  21. Lee WC, Bondaz L, Huang S, He G, Dakhchoune M, Agrawal KV, J. Membr. Sci., 618, 118745, 2021
  22. Chen R, Yao J, Gu Q, Smeets S, Baerlocher C, Gu H, Zhu D, Morris W, Yaghi OM, Wang H, Chem. Commun., 49, 9500, 2013
  23. Mao H, Zhen HG, Ahmad A, Li SH, Liang Y, Ding JF, Wu Y, Li LZ, Zhao ZP, J. Membr. Sci., 582, 307, 2019
  24. Li H, Han L, Hou JW, Liu JD, Zhang YT, J. Membr. Sci., 572, 82, 2019
  25. Bannwarth S, Darestani M, Coster H, Wessling M, J. Membr. Sci., 473, 318, 2015
  26. Xiao J, Sun Q, Liu L, Ding Z, Chin. J. Chem. Eng., In press (2020).
  27. Cravillon J, Munzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M, Chem. Mater., 21, 1410, 2009
  28. Huang Q, Luo Q, Chen Z, Yao L, Fu P, Lin Z, Environ. Sci.: Water Res. Technol., 4, 1145, 2018
  29. Khan IU, Othman MHD, Ismail AF, Ismail N, Jaafar J, Hashim H, Rahman MA, Jilani A, Mater. Charact., 136, 407, 2018
  30. Low ZX, Yao J, Liu Q, He M, Wang Z, Suresh AK, Bellare J, Wang H, Cryst. Growth Des., 14, 6589, 2014
  31. Liu GH, Jiang ZY, Cao KT, Nair S, Cheng XX, Zhao J, Gomaa H, Wu H, Pan FS, J. Membr. Sci., 523, 185, 2017
  32. Wu XN, Zhao B, Wang L, Zhang ZH, Zhang HW, Zhao XH, Guo XF, J. Membr. Sci., 520, 120, 2016
  33. Pan Y, Hang YT, Zhao XH, Liu GP, Jin WQ, J. Membr. Sci., 579, 210, 2019
  34. Li H, Chen YM, Ma XT, Shi JL, Zhu BK, Zhu LP, J. Membr. Sci., 379(1-2), 397, 2011
  35. Rezakazemi M, Vatani A, Mohammadi T, RSC Adv., 5, 82460, 2015
  36. Low ZX, Razmjou A, Wang K, Gray S, Duke M, Wang HT, J. Membr. Sci., 460, 9, 2014
  37. Vatanpour V, Madaeni SS, Khataee AR, Salehi E, Zinadini S, Monfared HA, Desalination, 292, 19, 2012
  38. Zhang XP, He XZ, Gundersen T, Energy Fuels, 27(8), 4137, 2013
  39. Banerjee R, Furukawa H, Britt D, Knobler C, O'Keeffe M, Yaghi OM, J. Am. Chem. Soc., 131(11), 3875, 2009
  40. Hu Y, Liu ZX, Xu J, Huang YN, Song Y, J. Am. Chem. Soc., 135(25), 9287, 2013
  41. Qiang W, Hu DD, Liu T, Zhao L, J. Supercrit. Fluids, 147, 329, 2019
  42. Barillas MK, Enick RM, O'Brien M, Perry R, Luebke DR, Morreale BD, J. Membr. Sci., 372(1-2), 29, 2011
  43. Lin YQ, Xu YL, Loh CH, Wang R, Appl. Surf. Sci., 436, 670, 2018
  44. Zhang HY, Wang R, Liang DT, Tay JH, J. Membr. Sci., 279(1-2), 301, 2006
  45. Li JL, Chen BH, Sep. Purif. Technol., 41(2), 109, 2005
  46. Xu YL, Lin YQ, Lee M, Malde C, Wang R, J. Membr. Sci., 552, 253, 2018
  47. Hashemifard SA, Ismail AF, Matsuura T, DashtArzhandi MR, RSC Adv., 5, 48442, 2015
  48. Mansourizadeh A, Mousavian S, J. Polym. Res., 20, 99, 2013
[Cited By]
  1. Jia-xi Y, Dan G, You-wei Q, Heng Z, Korean Journal of Chemical Engineering, 39(8), 2010, 2022
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.